Heterotrimetallic coordination polymers: {Cu(II)Ln(III)Fe(III)} chains and {Ni(II)Ln(III)Fe(III)} layers: synthesis, crystal structures, and magnetic properties.
The use of the [Fe(III) (AA)(CN)4](-) complex anion as metalloligand towards the preformed [Cu(II) (valpn)Ln(III)](3+) or [Ni(II) (valpn)Ln(III) ](3+) heterometallic complex cations (AA=2,2'-bipyridine (bipy) and 1,10-phenathroline (phen); H2 valpn=1,3-propanediyl-bis(2-iminomethylene-6-methoxyphenol)) allowed the preparation of two families of heterotrimetallic complexes: three isostructural 1D coordination polymers of general formula {[Cu(II) (valpn)Ln(III) (H2O)3 (μ-NC)2 Fe(III) (phen)(CN)2 {(μ-NC)Fe(III) (phen)(CN)3}]NO3 ⋅7 H2O}n (Ln=Gd (1), Tb (2), and Dy (3)) and the trinuclear complex [Cu(II) (valpn)La(III) (OH2 )3 (O2 NO)(μ-NC)Fe(III) (phen)(CN)3 ]⋅NO3 ⋅H2O⋅CH3 CN (4) were obtained …
{CoIIIMnIII}ncorrugated chains based on heteroleptic cyanido metalloligands
The use of the cyanide-bearing complexes PPh4[CoIII(4,4′-dmbipy)(CN)4] and PPh4[CoII(dmphen)(CN)3] as metalloligands towards [Mn(salen)(H2O)]ClO4 affords one-dimensional coordination polymers with the formulas {[MnIII(salen)(μ-NC)2CoIII(4,4-dmbipy)(CN)2]·H2O}n (1) and {[MnIII(salen)(μ-NC)2CoIII(dmphen)(CN)2]}n (2) [PPh4+ = tetraphenylphosphonium cation, 4,4′-dmbipy = 4,4′-dimethyl-2,2′-bipyridine, dmphen = 2,9-dimethyl-1,10-phenanthroline and H2salen = N,N′-ethylenebis(salicylideneimine)]. Compounds 1 and 2 were structurally characterized. Their structures consist of neutral chains with regular alternating [Mn(salen)]+ and [CoIII(4,4′-dmbipy)(CN)4]− (1)/[CoIII(dmphen)(CN)4]− (2) moieties, t…
Three different types of bridging ligands in a 3d-3d'-3d'' heterotrimetallic chain.
A one-pot synthesis of a 3d–3d′–3d′′ heterotrimetallic coordination polymer with double diphenoxido, single cyanido and bis-bidentate oxalate as alternating bridges which exhibits an overall antiferromagnetic behaviour has been developed.
Field-induced single ion magnet behaviour of discrete and one-dimensional complexes containing [bis(1-methylimidazol-2-yl)ketone]-cobalt(II) building units.
International audience; We describe herein the first examples of six-coordinate CoII single-ion magnets (SIMs) based on the β-diimine Mebik ligand [Mebik = bis(1-methylimidazol-2-yl)ketone]: two mononuclear [CoII(Rbik)2L2] complexes and one mixed-valence {CoIII2CoII}n chain of formulas [CoII(Mebik)(H2O)(dmso)(μ-NC)2CoIII2(μ-2,5-dpp)(CN)6]n·1.4nH2O (3) [L = NCS (1), NCSe (2) and 2,5-dpp = 2,5-bis(2-pyridyl)pyrazine (3)]. Two bidentate Mebik molecules plus two monodentate N-coordinated pseudohalide groups in cis positions build somewhat distorted octahedral surroundings around the high-spin cobalt(II) ions in 1 and 2. The diamagnetic [CoIII2(μ-2,5-dpp)(CN)8]2− metalloligand coordinates the pa…
Cyanido‐Bearing Cobalt(II/III) Metalloligands – Synthesis, Crystal Structure, and Magnetic Properties
New examples of cyanido-bearing cobalt(III/II) complexes have been obtained by treatment of CoCl2·6H2O with bidentate nitrogen donors and potassium cyanide in a methanol/water mixture. Depending on the chelating ligand, the cobalt(III) complexes PPh4[Co(en)(CN)4] (1, en = ethylenediamine), PPh4[Co(ampy)(CN)4]·1.5H2O [2, ampy = 2-(aminomethyl)pyridine], and PPh4[Co(phen)(CN)4]·CH3OH·0.25H2O (3, phen = 1,10-phenanthroline) and the cobalt(II) complex PPh4[Co(dmphen)(CN)3]·3H2O (4, dmphen = 2,9-dimethyl-1,10-phenanthroline) were obtained. The complexes were characterized by single-crystal X-ray diffraction and variable-temperature magnetic measurements. They are all mononuclear species with six…
Two-Dimensional Coordination Polymers Constructed by [NiIILnIII] Nodes and [WIV(bpy)(CN)6]2– Spacers: A Network of [NiIIDyIII] Single Molecule Magnets
Three isomorphous two-dimensional (2D) coordination polymers of general formula {[Ni(II)(valpn)Ln(III)(NO3)(H2O)(μ-NC)4W(IV)(bipy)(CN)2]·xH2O·yCH3CN}n have been synthesized by reacting Ph4P[W(V)(CN)6(bipy)] with the heterodinuclear [Ni(II)Ln(III)(valpn)(O2NO)3] complexes [H2valpn = 1,3-propanediyl-bis(2-iminomethylene-6-methoxyphenol), bipy = 2,2'-bipyridine, and Ln = Gd (1), Dy (2), and Tb (3) with x = 2 (1), 3.9 (2), and 3.35 (3) and y = 2.50 (1), 2 (2), and 1.8 (3)]. Their crystal structures consist of [Ni(II)Ln(III)] 3d-4f nodes which are connected by [W(IV)(bipy)(CN)6](2-) diamagnetic linkers resulting from the reduction of W(V) to W(IV) during the reaction process. The Ni(II) and Ln(I…
Cyanido-bridged {FeIIILnIII} heterobimetallic chains assembled through the [FeIII{HB(pz)3}(CN)3]−complex as metalloligand: synthesis, crystal structure and magnetic properties
A new series of cyanido-bridged {FeIIILnIII} heterobimetallic chains of general formula {[(NC)FeIII{HB(pz)3}(μ-CN)2LnIII(bpdo)(NO3)2(H2O)]·CH3CN}n [HB(pz)3− = hydrotris(pyrazol-1-yl)borate, bpdo = 2,2′-bipyridine-N,N′-dioxide and Ln = Gd (1), Tb (2), Dy (3) and Ho (4)], were obtained by using the low-spin [Fe{HB(pz)3}(CN)3]− complex as a metalloligand towards the preformed [Ln(bdpo)(NO3)2(H2O)]+ species. Single-crystal X-ray diffraction shows that 1–4 are isostructural compounds that crystallize in the monoclinic P21/c space group. Their crystal structure consists of neutral 1D coordination polymers where the [Fe{HB(pz)3}(CN)3]− fragment adopts a bis-monodentate coordination mode, through t…
Cyanido-Bridged {LnIIIWV} Heterobinuclear Complexes: Synthesis and Magneto-Structural Study
A new series of cyanido-bridged {LnIIIWV} heterobinuclear complexes of formula [LnIII(pyim)2(i-PrOH)(H2O)2(μ-CN)WV(CN)7]·2H2O [Ln = Gd (1), Tb (2), Dy (3), Ho (4), and Er (5); pyim = 2-(1H-imidazol-2-yl)-pyridine) and i-PrOH = isopropyl alcohol] were synthesized by one-pot reaction between (NH3Bu)3[W(CN)8] and [Ln(pyim)2]2+ complexes (generated in situ by mixing the corresponding LnIII ions and the pyim ligand). Compounds 1–5 are isomorphous and crystallize in the monoclinic system P21/n space group. Their crystal structure consists of binuclear units in which the octacyanotungstate(V) anion coordinates to the corresponding LnIII ion through a single cyanide ligand. The tungsten(V) and lant…
A novel octacyanido dicobalt(iii) building block for the construction of heterometallic compounds
The first bimetallic octacyanido complex of CoIII, (PPh4)2[Co2(μ-2,5-dpp)(CN)8] (1), was synthesized and used as a metalloligand with [Mn(MAC)(H2O)2]Cl2·4H2O to give a new {CoIIIMnII} heterometallic chain of formula [MnII(MAC)(μ-NC)2Co2III(μ-2,5-dpp)(CN)6]n·7nH2O (2) (PPh4+ = tetraphenylphosphonium cation; 2,5-dpp = 2,5-bis(2-pyridyl)pyrazine and MAC = 2,13-dimethyl-3,6,9,12,18-pentaazabicyclo-[12.3.1]octadeca-1(18),2,12,14,16-pentaene). Both compounds were characterized by single-crystal X-ray diffraction. Compound 1 contains a diamagnetic 2,5-dpp-bridged dicobalt(III) unit with four peripheral cyanide ligands at each cobalt center achieving a six-coordinate surrounding, the electroneutral…
Magnetism in Heterobimetallic and Heterotrimetallic Chains Based on the Use of [W V (bipy)(CN) 6 ] – as a Metalloligand
Synthesis, crystal structure and magnetic properties of a cyanide-bridged heterometallic {CoIIMnIII} chain
The assembly reaction between the low-spin [CoII(dmphen)(CN)3]- metalloligand and the [MnIII(salen)(H2O)]+ complex cation yielded the one-dimensional compound {[MnIII(salen)(μ-NC)2CoII(dmphen)(CN)]·2H2O}n (1), which behaves as a ferrimagnetic chain, the intrachain magnetic coupling being J = -1.71(1) cm-1.
In situ generation of Ph3PO in cyanido-bridged heterometallic {FeIIILnIII}2 molecular squares (Ln = Eu, Sm)
Two new examples of cyanido-bridged {FeIIILnIII}2 molecular squares, with pyim and PPh3O as capping ligands at the LnIII sites, exhibit weak antiferromagnetic interactions [Ln = Eu (1), Sm (2), pyim = 2-(1H-imidazol-2-yl)pyridine, PPh3PO = triphenylphosphine oxide].
Slow relaxation of the magnetization in a {CoIIIMnIII} heterometallic brick-wall network
Abstract The use of the cyanide-bearing dicobalt(III) complex (PPh4)2[Co2III(μ−2,5-dpp)(CN)8] as a metalloligand towards [Mn(salen)(H2O)]ClO4 afforded the heterobimetallic two-dimensional compound of formula [{MnIII(salen)}2{(μ-NC)4Co2III(μ−2,5-dpp)(CN)4}]n (1) [PPh4+ = teraphenylphosphonium cation, 2,5-dpp = 2,5-bis(2-pyridyl)pyrazine and H2salen = N,N’-ethylenebis(salicylideneimine)] whose structure has been determined by single crystal X-ray diffraction. Compound 1 exhibits a neutral brick-wall structure, where each [Co2III(μ−2,5-dpp)(CN)8]2− unit adopts a tetrakis-monodentate bridging mode towards four {MnIII(salen)}+ fragments through four of its eight cyanide ligands. Each cobalt(III)…
Synthesis, Crystal Structures, and Magnetic Properties of Two Novel Cyanido-Bridged Heterotrimetallic {CuIIMnIICrIII} Complexes
The self-assembly process between the heteroleptic [CrIII(phen)(CN)4]− and [CrIII(ampy)(CN)4]− metalloligands and the heterobimetallic {CuII(valpn)MnII}2+ tecton afforded two heterotrimetallic complexes of formula [{CuII(valpn)MnII(μ-NC)2CrIII(phen)(CN)2}2{(μ-NC)CrIII(phen)(CN)3}2]·2CH3CN (1) and {[CuII(valpn)MnII(μ-NC)2CrIII(ampy)(CN)2]2·2CH3CN}n (2) [phen = 1,10-phenanthroline, ampy = 2-aminomethylpyridine, and H2valpn = 1,3-propanedyilbis(2-iminomethylene-6-methoxyphenol)]. The crystal structure of 1 consists of neutral CuII2MnII2CrIII4 octanuclear units, where two [Cr(phen)(CN)4]− anions act as bis-monodentate ligands through cyanide groups toward two manganese(II) ions from two [CuII(v…
Design of 3d–4f molecular squares through the [Fe{(HB(pz)3)}(CN)3]− metalloligand
A new series of {FeIII2LnIII2} heterobimetallic squares of general formula [FeIII{HB(pz)3}(CN)(μ-CN)2Ln(pyim)x(NO3)2(H2O)y]2·zH2O [Ln = La (1), Gd (2), Tb (3) and Dy (4); {HB(pz)3}− = hydrotris(pyrazolyl)borate and pyim = 2-(1H-imidazol-2-yl)pyridine; x = 2, y = 0 (1), x = y = 1 (2–4) and z = 10 (1), 6 (2), 2.76 (3), 4 (4)] were synthesized by reacting the low-spin [FeIII{HB(pz)3}(CN)3]− complex anion with the preformed [LnIII(pyim)x(NO3)2(H2O)y]+ complex cation [formed in situ by mixing the lanthanide(III) salt and the pyim ligand]. Single-crystal X-ray diffraction shows that 1–4 crystallize in the P triclinic space group, 2–4 being isomorphous. In all cases, the structure comprises neutra…
Slow Relaxation of the Magnetization in a {Co <sup>III</sup>Mn <sup>III</sup>} Heterometallic Brick-Wall Network
The use of the cyanide-bearing dicobalt(III) complex (PPh 4 ) 2 [Co 2 III (m-2,5-dpp)(CN) 8 ] as a metalloligand towards [Mn(salen)(H 2 O)]ClO 4 afforded the heterobimetallic two-dimensional compound of formula [{Mn III (salen)} 2 {(m-NC) 4 Co 2 III (m-2,5-dpp)(CN) 4 }] n (1) [PPh 4 + = teraphenylphosphonium cation, 2,5-dpp = 2,5-bis(2-pyridyl)pyrazine and H 2 salen = N,N’ -ethylenebis(salicylideneimine)] whose structure has been determined by single crystal X-ray diffraction. Compound 1 exhibits a neutral brick-wall structure, where each [Co 2 III (m-2,5-dpp)(CN) 8 ] 2- unit adopts a tetrakis-monodentate bridging mode towards four {Mn III (salen)} + fragments through four of its eight cyan…
Synthesis, Crystal Structure and Magnetic Properties of Three {Cr III Mn II } Heterodimetallic Complexes Based on Heteroleptic Cyanido‐Bearing Cr III Building Blocks
The use of the heteroleptic [CrIII(AA)(CN)4]- complex as a ligand towards the preformed [MnII(tptz)]2+ and [MnII(pyim)2]2+ species afforded the heterometallic compounds: [MnII(tptz)(H2O)(NO3)(-NC)CrIII(ampy)(CN)3]CH3CN (1), [MnII(tptz)(H2O)(NO3)(-NC)CrIII(phen)(CN)3]H2O (2) and {[MnII(pyim)2][(-NC)Cr(phen)(CN)3]2}3H2O (3) [AA = 2-aminomethylpyridine (ampy) and 1,10-phenanthroline (phen), tptz = 2,4,6-tris(2-pyridyl)-1,3,5-triazine and pyim = 2-(1H-imidazol-2-yl)pyridine]. 1 and 2 are neutral heterodinuclear complexes where a [CrIII(AA)(CN)4]- building block acts as a monodentate ligand through one cyanide group towards a seven coordinate MnII ion. Compound 3 is a neutral heterotrinuclear co…
[W(bipy)(CN)6]−: A Suitable Metalloligand in the Design of Heterotrimetallic Complexes. The First CuIILnIIIWV Trinuclear Complexes
The first 3d-4f-5d heterotrimetallic complexes using [W(V)(bipy)(CN)(6)](-) as a metalloligand were synthesized (bipy = 2,2'-bipyridine). The structural and magnetic properties of three [Cu(II)Ln(III)W(V)] complexes (Ln = Gd, Ho, Tb) are discussed.
A rare isostructural series of 3d–4f cyanido-bridged heterometallic squares obtained by assembling [FeIII{HB(pz)3}(CN)3]− and LnIII ions: synthesis, X-ray structure and cryomagnetic study
A new series of cyanido-bridged {FeIIILnIII}2 neutral molecular squares of general formula [Fe{HB(pz)3}(CN)(μ-CN)2Ln(NO3)2(pyim)(Ph3PO)]2·2CH3CN [Ln = Ce (1), Pr (2), Nd (3), Gd (4), Tb (5), Dy (6) and Er (7); {HB(pz)3}− = hydrotris(pyrazolyl)borate, pyim = 2-(1H-imidazol-2-yl)pyridine and Ph3PO = triphenylphosphine oxide] were obtained by reacting the low-spin [Fe{HB(pz)3}(CN)3]− species with the preformed [LnIII(pyim)(NO3)2(pyim)(Ph3PO)]+ complex anions (generated in situ by mixing the nitrate salt of each Ln(III) ion with pyim and Ph3PO molecules). Single-crystal X-ray diffraction studies show that 1–7 are isostructural compounds that crystallize in the triclinic P space group. Their cry…
CCDC 995944: Experimental Crystal Structure Determination
Related Article: Maria-Gabriela Alexandru, Diana Visinescu, Marius Andruh, Nadia Marino, Donatella Armentano, Joan Cano, Francesc Lloret, Miguel Julve|2015|Chem.-Eur.J.|21|5429|doi:10.1002/chem.201406088
CCDC 995946: Experimental Crystal Structure Determination
Related Article: Maria-Gabriela Alexandru, Diana Visinescu, Marius Andruh, Nadia Marino, Donatella Armentano, Joan Cano, Francesc Lloret, Miguel Julve|2015|Chem.-Eur.J.|21|5429|doi:10.1002/chem.201406088
CCDC 1582396: Experimental Crystal Structure Determination
Related Article: Maria-Gabriela Alexandru, Diana Visinescu, Sergiu Shova, Willian X. C. Oliveira, Francesc Lloret, Miguel Julve|2018|Dalton Trans.|47|6005|doi:10.1039/C8DT00895G
CCDC 1520091: Experimental Crystal Structure Determination
Related Article: Maria-Gabriela Alexandru, Diana Visinescu, Sergiu Shova, Marius Andruh, Francesc Lloret, Miguel Julve|2017|Inorg.Chem.|56|2258|doi:10.1021/acs.inorgchem.6b02966
CCDC 995943: Experimental Crystal Structure Determination
Related Article: Maria-Gabriela Alexandru, Diana Visinescu, Marius Andruh, Nadia Marino, Donatella Armentano, Joan Cano, Francesc Lloret, Miguel Julve|2015|Chem.-Eur.J.|21|5429|doi:10.1002/chem.201406088
CCDC 1969476: Experimental Crystal Structure Determination
Related Article: Maria-Gabriela Alexandru, Diana Visinescu, Beatrice Cula, Sergiu Shova, Renato Rabelo, Nicolás Moliner, Francesc Lloret, Joan Cano, Miguel Julve|2021|Dalton Trans.|50|14640|doi:10.1039/D1DT02512K
CCDC 1520092: Experimental Crystal Structure Determination
Related Article: Maria-Gabriela Alexandru, Diana Visinescu, Sergiu Shova, Marius Andruh, Francesc Lloret, Miguel Julve|2017|Inorg.Chem.|56|2258|doi:10.1021/acs.inorgchem.6b02966
CCDC 2096753: Experimental Crystal Structure Determination
Related Article: Juan-Ram��n Jim��nez, Buqing Xu, Hasnaa El Said, Yanling Li, Jurgen von Bardeleben, Lise-Marie Chamoreau, Rodrigue Lescou��zec, Sergiu Shova, Diana Visinescu, Maria-Gabriela Alexandru, Joan Cano, Miguel Julve|2021|Dalton Trans.|50|16353|doi:10.1039/D1DT02441H
CCDC 995947: Experimental Crystal Structure Determination
Related Article: Maria-Gabriela Alexandru, Diana Visinescu, Marius Andruh, Nadia Marino, Donatella Armentano, Joan Cano, Francesc Lloret, Miguel Julve|2015|Chem.-Eur.J.|21|5429|doi:10.1002/chem.201406088
CCDC 1969477: Experimental Crystal Structure Determination
Related Article: Maria-Gabriela Alexandru, Diana Visinescu, Beatrice Cula, Sergiu Shova, Renato Rabelo, Nicolás Moliner, Francesc Lloret, Joan Cano, Miguel Julve|2021|Dalton Trans.|50|14640|doi:10.1039/D1DT02512K
CCDC 2073773: Experimental Crystal Structure Determination
Related Article: Diana Visinescu, Maria-Gabriela Alexandru, Dan G. Dumitrescu, Sergiu Shova, Nicolás Moliner, Francesc Lloret, Miguel Julve|2021|CrystEngComm|23|4615|doi:10.1039/D1CE00626F
CCDC 995948: Experimental Crystal Structure Determination
Related Article: Maria-Gabriela Alexandru, Diana Visinescu, Marius Andruh, Nadia Marino, Donatella Armentano, Joan Cano, Francesc Lloret, Miguel Julve|2015|Chem.-Eur.J.|21|5429|doi:10.1002/chem.201406088
CCDC 1907945: Experimental Crystal Structure Determination
Related Article: Maria-Gabriela Alexandru, Diana Visinescu, Beatrice Braun-Cula, Sergiu Shova, Francesc Lloret, Miguel Julve|2019|Dalton Trans.|48|7532|doi:10.1039/C9DT01445D
CCDC 989258: Experimental Crystal Structure Determination
Related Article: Maria-Gabriela Alexandru, Diana Visinescu, Nadia Marino, Giovanni De Munno, Julia Vallejo, Francesc Lloret, Miguel Julve|2014|Eur.J.Inorg.Chem.||4564|doi:10.1002/ejic.201402190
CCDC 1969470: Experimental Crystal Structure Determination
Related Article: Maria-Gabriela Alexandru, Diana Visinescu, Beatrice Cula, Sergiu Shova, Renato Rabelo, Nicolás Moliner, Francesc Lloret, Joan Cano, Miguel Julve|2021|Dalton Trans.|50|14640|doi:10.1039/D1DT02512K
CCDC 1582395: Experimental Crystal Structure Determination
Related Article: Maria-Gabriela Alexandru, Diana Visinescu, Sergiu Shova, Willian X. C. Oliveira, Francesc Lloret, Miguel Julve|2018|Dalton Trans.|47|6005|doi:10.1039/C8DT00895G
CCDC 2073771: Experimental Crystal Structure Determination
Related Article: Diana Visinescu, Maria-Gabriela Alexandru, Dan G. Dumitrescu, Sergiu Shova, Nicolás Moliner, Francesc Lloret, Miguel Julve|2021|CrystEngComm|23|4615|doi:10.1039/D1CE00626F
CCDC 2096752: Experimental Crystal Structure Determination
Related Article: Juan-Ram��n Jim��nez, Buqing Xu, Hasnaa El Said, Yanling Li, Jurgen von Bardeleben, Lise-Marie Chamoreau, Rodrigue Lescou��zec, Sergiu Shova, Diana Visinescu, Maria-Gabriela Alexandru, Joan Cano, Miguel Julve|2021|Dalton Trans.|50|16353|doi:10.1039/D1DT02441H
CCDC 989260: Experimental Crystal Structure Determination
Related Article: Maria-Gabriela Alexandru, Diana Visinescu, Nadia Marino, Giovanni De Munno, Julia Vallejo, Francesc Lloret, Miguel Julve|2014|Eur.J.Inorg.Chem.||4564|doi:10.1002/ejic.201402190
CCDC 1892383: Experimental Crystal Structure Determination
Related Article: Maria-Gabriela Alexandru, Nadia Marino, Diana Visinescu, Giovanni De Munno, Marius Andruh, Abdeslem Bentama, Francesc Lloret, Miguel Julve|2019|New J.Chem.|43|6675|doi:10.1039/C9NJ00420C
CCDC 1567349: Experimental Crystal Structure Determination
Related Article: Maria-Gabriela Alexandru, Diana Visinescu, Sergiu Shova, Francesc Lloret, and Miguel Julve|2017|Inorg.Chem.|56|12594|doi:10.1021/acs.inorgchem.7b02050
CCDC 1969471: Experimental Crystal Structure Determination
Related Article: Maria-Gabriela Alexandru, Diana Visinescu, Beatrice Cula, Sergiu Shova, Renato Rabelo, Nicolás Moliner, Francesc Lloret, Joan Cano, Miguel Julve|2021|Dalton Trans.|50|14640|doi:10.1039/D1DT02512K
CCDC 995949: Experimental Crystal Structure Determination
Related Article: Maria-Gabriela Alexandru, Diana Visinescu, Marius Andruh, Nadia Marino, Donatella Armentano, Joan Cano, Francesc Lloret, Miguel Julve|2015|Chem.-Eur.J.|21|5429|doi:10.1002/chem.201406088
CCDC 1524159: Experimental Crystal Structure Determination
Related Article: Maria-Gabriela Alexandru, Diana Visinescu, Beatrice Braun-Cula, Francesc Lloret, Miguel Julve|2018|Eur.J.Inorg.Chem.||349|doi:10.1002/ejic.201700313
CCDC 2073772: Experimental Crystal Structure Determination
Related Article: Diana Visinescu, Maria-Gabriela Alexandru, Dan G. Dumitrescu, Sergiu Shova, Nicolás Moliner, Francesc Lloret, Miguel Julve|2021|CrystEngComm|23|4615|doi:10.1039/D1CE00626F
CCDC 953096: Experimental Crystal Structure Determination
Related Article: Maria-Gabriela Alexandru, Diana Visinescu, Sergiu Shova, Francesc Lloret, Miguel Julve, and Marius Andruh|2013|Inorg.Chem.|52|11627|doi:10.1021/ic4019794
CCDC 1574907: Experimental Crystal Structure Determination
Related Article: Maria-Gabriela Alexandru, Diana Visinescu, Sergiu Shova, Marius Andruh, Francesc Lloret, Miguel Julve|2018|Eur.J.Inorg.Chem.||360|doi:10.1002/ejic.201701245
CCDC 2073774: Experimental Crystal Structure Determination
Related Article: Diana Visinescu, Maria-Gabriela Alexandru, Dan G. Dumitrescu, Sergiu Shova, Nicolás Moliner, Francesc Lloret, Miguel Julve|2021|CrystEngComm|23|4615|doi:10.1039/D1CE00626F
CCDC 1582397: Experimental Crystal Structure Determination
Related Article: Maria-Gabriela Alexandru, Diana Visinescu, Sergiu Shova, Willian X. C. Oliveira, Francesc Lloret, Miguel Julve|2018|Dalton Trans.|47|6005|doi:10.1039/C8DT00895G
CCDC 989261: Experimental Crystal Structure Determination
Related Article: Maria-Gabriela Alexandru, Diana Visinescu, Nadia Marino, Giovanni De Munno, Julia Vallejo, Francesc Lloret, Miguel Julve|2014|Eur.J.Inorg.Chem.||4564|doi:10.1002/ejic.201402190
CCDC 953097: Experimental Crystal Structure Determination
Related Article: Maria-Gabriela Alexandru, Diana Visinescu, Sergiu Shova, Francesc Lloret, Miguel Julve, and Marius Andruh|2013|Inorg.Chem.|52|11627|doi:10.1021/ic4019794
CCDC 2072597: Experimental Crystal Structure Determination
Related Article: Juan-Ram��n Jim��nez, Buqing Xu, Hasnaa El Said, Yanling Li, Jurgen von Bardeleben, Lise-Marie Chamoreau, Rodrigue Lescou��zec, Sergiu Shova, Diana Visinescu, Maria-Gabriela Alexandru, Joan Cano, Miguel Julve|2021|Dalton Trans.|50|16353|doi:10.1039/D1DT02441H
CCDC 1567346: Experimental Crystal Structure Determination
Related Article: Maria-Gabriela Alexandru, Diana Visinescu, Sergiu Shova, Francesc Lloret, and Miguel Julve|2017|Inorg.Chem.|56|12594|doi:10.1021/acs.inorgchem.7b02050
CCDC 1582340: Experimental Crystal Structure Determination
Related Article: Maria-Gabriela Alexandru, Diana Visinescu, Sergiu Shova, Marius Andruh, Francesc Lloret, Joan Cano, Miguel Julve|2018|Dalton Trans.|47|1010|doi:10.1039/C7DT04586G
CCDC 1585318: Experimental Crystal Structure Determination
Related Article: Maria-Gabriela Alexandru, Diana Visinescu, Sergiu Shova, Willian X. C. Oliveira, Francesc Lloret, Miguel Julve|2018|Dalton Trans.|47|6005|doi:10.1039/C8DT00895G
CCDC 1567347: Experimental Crystal Structure Determination
Related Article: Maria-Gabriela Alexandru, Diana Visinescu, Sergiu Shova, Francesc Lloret, and Miguel Julve|2017|Inorg.Chem.|56|12594|doi:10.1021/acs.inorgchem.7b02050
CCDC 989259: Experimental Crystal Structure Determination
Related Article: Maria-Gabriela Alexandru, Diana Visinescu, Nadia Marino, Giovanni De Munno, Julia Vallejo, Francesc Lloret, Miguel Julve|2014|Eur.J.Inorg.Chem.||4564|doi:10.1002/ejic.201402190
CCDC 1567348: Experimental Crystal Structure Determination
Related Article: Maria-Gabriela Alexandru, Diana Visinescu, Sergiu Shova, Francesc Lloret, and Miguel Julve|2017|Inorg.Chem.|56|12594|doi:10.1021/acs.inorgchem.7b02050
CCDC 1969473: Experimental Crystal Structure Determination
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