6533b871fe1ef96bd12d23c0

RESEARCH PRODUCT

[W(bipy)(CN)6]−: A Suitable Metalloligand in the Design of Heterotrimetallic Complexes. The First CuIILnIIIWV Trinuclear Complexes

Miguel JulveDiana VisinescuFrancesc LloretMarius AndruhMaria-gabriela AlexandruMaria-gabriela AlexandruAugustin M. Madalan

subject

Inorganic ChemistryCrystallographyChemistryPhysical and Theoretical Chemistry

description

The first 3d-4f-5d heterotrimetallic complexes using [W(V)(bipy)(CN)(6)](-) as a metalloligand were synthesized (bipy = 2,2'-bipyridine). The structural and magnetic properties of three [Cu(II)Ln(III)W(V)] complexes (Ln = Gd, Ho, Tb) are discussed.

https://doi.org/10.1021/ic300544m