6533b86dfe1ef96bd12caa2e
RESEARCH PRODUCT
Two-Dimensional Coordination Polymers Constructed Using, Simultaneously, Linear and Angular Spacers and Cobalt(II) Nodes. New Examples of Networks of Single-Ion Magnets
Simona NicaFrancesc LloretAdrian E. IonJulia VallejoSergiu ShovaMarius AndruhAugustin M. MadalanMiguel Julvesubject
chemistry.chemical_classificationEthyleneSingle ionchemistry.chemical_elementPolymerAzuleneIonInorganic Chemistrychemistry.chemical_compoundchemistryMagnetOrganic chemistryPhysical chemistryPhysical and Theoretical ChemistryCobaltdescription
Two novel bidimensional coordination polymers, [Co(azbbpy)(4,4'-bipy)0.5(DMF)(NCS)2]·MeOH (1) and [Co(azbbpy)(bpe)0.5(DMF)(NCS)2]·0.25H2O (2), resulted from the assembling of cobalt(II) ions by 1,3-bis(4-pyridyl)azulene, using either 4,4'-bipyridyl or 1,2-bis(4-pyridyl)ethylene as neutral spacers. The cobalt(II) nodes in 1 and 2 act as single-ion magnets (SIMs).
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2014-12-19 | Inorganic Chemistry |