6533b833fe1ef96bd129c043

RESEARCH PRODUCT

Synthesis, crystal structure and magnetic properties of a new [ZnII6DyIII6] dodecanuclear motif

Sergiu ShovaAlina S. DincaMiguel JulveMarius AndruhFrancesc LloretJulia Vallejo

subject

ChemistryStereochemistryLigandSupramolecular chemistrychemistry.chemical_elementCrystal structureZincCondensation reactionIonInorganic Chemistrychemistry.chemical_compoundCrystallographyHydroxylamineOctahedronMaterials ChemistryPhysical and Theoretical Chemistry

description

Abstract A new dodecanuclear complex, [{(HL)(L)(dmf)ZnIIDyIII(dmf)(H2O)}6]·3dmf·4.2H2O has been assembled using a supramolecular compartmental ligand (H3L results from the condensation reaction of 3-formylsalicylic acid and hydroxylamine). The six DyIII ions describe an octahedron that is inscribed into the octahedron generated by the zinc(II) ions each DyIII ion from this motif behaving as a single ion magnet.

yearjournalcountryeditionlanguage
2013-11-01Polyhedron
https://doi.org/10.1016/j.poly.2013.08.049