6533b857fe1ef96bd12b39dc
RESEARCH PRODUCT
An original 3D coordination polymer constructed from trinuclear nodes and tetracarboxylato spacers
Miguel JulveAlina S. DincaSimona NicaMarius AndruhSergiu ShovaAdrian E. IonAdrian E. IonDan DumitrescuFrancesc LloretAndreea Dogarusubject
Materials scienceLigandCoordination polymerIcosahedral symmetryCationic polymerizationchemistry.chemical_elementGeneral ChemistryCondensed Matter PhysicsCondensation reactionCopperIonCrystallographychemistry.chemical_compoundchemistryAntiferromagnetismGeneral Materials Sciencedescription
A novel 3D coordination polymer, ∞3[{Cu3(felden)}4(btec)3]·17H2O, has been assembled using cationic trigonal nodes, [CuII3(felden)]3+, generated by a tricompartmental ligand, H3felden, which results from the Schiff condensation reaction between 2,4,6-triformylphloroglucinol and N,N-dimethylethylenediamine. The tetraanion of the 1,2,4,5-benzenetetracaboxylic acid (H4btec) was employed as a spacer. The structure of 1 shows large icosahedral cavities and channels and the magnetic interaction between the copper(II) ions within the triangles is weak and antiferromagnetic.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2021-01-01 | CrystEngComm |