0000000000991937

AUTHOR

P. Fertey

showing 2 related works from this author

An {Fe60} tetrahedral cage: building nanoscopic molecular assemblies through cyanometallate and alkoxo linkers

2016

International audience; A nanoscopic {Fe60} coordination cage (approximately 3 nm) was prepared by the self assembly of a partially blocked tricyanidoferrate(III) complex and tris(alkoxo)-based iron(III) coordination motifs. This cage is a rare example of a mixed cyanido/alkoxo-bridged high nuclearity complex and it exemplifies the great potential of this new synthetic route to generate uncommon molecular architectures using cyanometallates as metalloligands versus alkoxo-based polynuclear entities.

Materials science010405 organic chemistry010402 general chemistry01 natural sciences0104 chemical sciencesInorganic ChemistryCrystallographyCoordination cageComputational chemistryTetrahedron[CHIM]Chemical Sciences[CHIM.COOR]Chemical Sciences/Coordination chemistryCageNanoscopic scale
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CCDC 1409712: Experimental Crystal Structure Determination

2016

Related Article: J.-R. Jiménez, A. Mondal, L.-M. Chamoreau, P. Fertey, F. Tuna, M. Julve, A. Bousseksou, R. Lescouëzec, L. Lisnard|2016|Dalton Trans.|45|17610|doi:10.1039/C6DT03151J

Space GroupCrystallographyCrystal SystemCrystal Structureundeca-iron(ii) nonatetraconta-iron(iii) nonacosachloride hexatriacontacyanide dodecakis(hydrogen tris(pyrazolyl)borate) octacosakis(2-methyl-2-(oxidomethyl)propane-13-bis(olate)) tetraoxide methanol solvate nonapentacontahydrateCell ParametersExperimental 3D Coordinates
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