6533b856fe1ef96bd12b1e9c
RESEARCH PRODUCT
An {Fe60} tetrahedral cage: building nanoscopic molecular assemblies through cyanometallate and alkoxo linkers
Azzedine BousseksouLaurent LisnardLaurent LisnardRodrigue LescouëzecRodrigue LescouëzecAbhishake MondalAbhishake MondalLise-marie ChamoreauLise-marie ChamoreauMiguel JulveFloriana TunaJuan-ramón JiménezJuan-ramón JiménezP. Ferteysubject
Materials science010405 organic chemistry010402 general chemistry01 natural sciences0104 chemical sciencesInorganic ChemistryCrystallographyCoordination cageComputational chemistryTetrahedron[CHIM]Chemical Sciences[CHIM.COOR]Chemical Sciences/Coordination chemistryCageNanoscopic scaledescription
International audience; A nanoscopic {Fe60} coordination cage (approximately 3 nm) was prepared by the self assembly of a partially blocked tricyanidoferrate(III) complex and tris(alkoxo)-based iron(III) coordination motifs. This cage is a rare example of a mixed cyanido/alkoxo-bridged high nuclearity complex and it exemplifies the great potential of this new synthetic route to generate uncommon molecular architectures using cyanometallates as metalloligands versus alkoxo-based polynuclear entities.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2016-01-01 |