Oxidation of pentan-2-ol -Part II: Experimental and modeling study

International audience; The oxidation of pentan-2-ol was investigated at high-pressure in a jet-stirred reactor and in a shock tube. Experiments in the JSR were carried out at 10 atm, between 500-1180 K, for five different equivalence ratios of = 0.35, 0.5, 1, 2, 4 and 1000 ppm of fuel, at a constant residence time of 0.7 s. Reactant, product and intermediate species mole fractions were quantified using Fourier transform infrared spectrometry (FTIR) and gas chromatography (GC). Ignition delay times were measured for pentan-2-ol/O 2 mixtures in argon in a shock tube at 20 and 40 bar, in a temperature range of 1070-1460 K and for equivalence ratios of = 0.5, 1 and 2. Ignition delay times of a…

An experimental and kinetic modeling study on the oxidation of 1,3-dioxolane

International audience; The modern catalytic or enzymatic advances allow the production of novel biofuel. Among them, 1,3dioxolane can be produced from formaldehyde and ethylene glycol, both can be obtained from biomass. In this study, the oxidation of 1,3-dioxolane is studied at stoichiometric conditions. The ignition delay times of 1,3-dioxolane/O 2 /inert mixtures were measured in a shock tube and in a rapid compression machine at pressures of 20 to 40 bar and temperatures ranging from 630 to 1300 K. The pressure profiles recorded in the rapid compression machine show a first stage of ignition enlightening the influence of the low temperature chemistry of combustion. Furthermore, mole fr…

Methyl-3-Hexenoate Combustion Chemistry: Experimental Study and Numerical Kinetic Simulation

International audience; This work represents a detailed investigation of combustion and oxidation of methyl-3-hexenoate (CAS Number 2396-78-3), including experimental studies of combustion and oxidation characteristics, quantum chemistry calculations and kinetic model refinement. Following experiments have been carried out: Speciation measurements during oxidation in a jet-stirred reactor at 1 atm; chemical speciation measurements in a stoichiometric premixed flame at 1 atm using molecular-beam mass-spectrometry; ignition delay times measurements in a shock tube at 20 and 40 bar; and laminar burning velocity measurements at 1 atm using a heat-flux burner over a range of equivalence ratios. …

An experimental and modeling study of the oxidation of 3-pentanol at high pressure

International audience; High pressure oxidation of 3-pentanol is investigated in a jet-stirred reactor and in a shock tube. Experiments in the reactor were carried out at 10 atm, between 730 and 1180 K, for equivalence ratios of 0.35, 0.5, 1, 2, 4 and 1000 ppm fuel, at a constant residence time of 0.7 s. Reactant, product and intermediate species mole fractions were recorded using Fourier transform infrared spectroscopy (FTIR) and gas chromatography (GC). Ignition delay times were measured for 3-pentanol/O2 mixtures in argon in a shock tube at 20 and 40 bar, in a temperature range of 1000–1470 K and for equivalence ratios of 0.5, 1 and 2. The fuel did not show any low-temperature reactivity…

Vaporization characteristics of 1-propanol droplets at high temperatures

International audience; The gasification of a droplet via vaporization is one of the main processes in combustion systems, namely diesel and propulsion engines. In these combustion systems, always the liquid fuel is atomized as a cloud of droplets in the chamber, which then vaporizes, and mixes with the oxidant and burns to release heat. Therefore, to afford a better knowledge especially in modelling complex spray flows and mixture formation issues, the study of the droplet vaporization which involves mass, heat and momentum transfer processes is really vital. Alcohol has been chosen for this particular study due to its potential as an alternative fuel to the current conventional hydrocarbo…

An Experimental and Kinetic Modeling Study of Ethanol / Dme Mixtures Auto-Ignition

Solving the riddle of the high-temperature chemistry of 1,3-dioxolane

Probing the low-temperature chemistry of ethanol via the addition of dimethyl ether

Considering the importance of ethanol (EtOH) as an engine fuel and a key component of surrogate fuels, the further understanding of its auto-ignition and oxidation characteristics at engine-relevant conditions (high pressures and low temperatures) is still necessary. However, it remains difficult to measure ignition delay times for ethanol at temperatures below 850 K with currently available facilities including shock tube and rapid compression machine due to its low reactivity. Considering the success of our recent study of toluene oxidation under similar conditions [38], dimethyl ether (DME) has been selected as a radical initiator to explore the low-temperature reactivity of ethanol. In …

VAPORIZATION CHARACTERISTICS OF ETHANOL AND 1-PROPANOL DROPLETS AT HIGH TEMPERATURES

International audience; A detailed description of the vaporization of an isolated droplet has been carried out in this experimental study aimed at investigating ethanol and another aliphatic alcohol, 1-propanol. The characterization of the vaporization phenomenon is necessary for this liquid fuel to develop efficient design of injection systems for propulsion and power generation. Particularly, the vaporization rates and their dependency on temperature, important features for modeling and design, are explored for both ethanol and 1-propanol at intermediate to high temperatures. The experimental setup consists of a pressure chamber in which the furnace, the droplet formation, the droplet sup…