0000000001083101

AUTHOR

Lukas Glanz

showing 5 related works from this author

Subcomponent self‐assembly of a cyclic tetranuclear Fe(II) helicate in a highly diastereoselective self‐sorting manner

2019

Abstract An enantiomerically pure diamine based on the 4,15‐difunctionalized [2.2]paracyclophane scaffold and 2‐formylpyridine self‐assemble into an optically pure cyclic metallosupramolecular Fe4L6 helicate upon mixing with iron(II) ions in a diastereoselective subcomponent self‐assembly process. The cyclic assembly results from steric strain that prevents the formation of a smaller linear dinuclear triple‐stranded helicate, and hence, leads to the larger strain‐free assembly that fulfils the maximum occupancy rule. Interestingly, use of the racemic diamine also leads to a racemic mixture of the homochiral cyclic helicates as the major product in a highly diastereoselective narcissistic ch…

Circular dichroismSupramolecular chemistry010402 general chemistrychiral self-sorting01 natural sciencesCatalysisSupramolecular ChemistryStereocenterchemistry.chemical_compoundDiaminesupramolekulaarinen kemiacyclic helicates010405 organic chemistryCommunicationOrganic Chemistrymetallo-supramolecular chemistryDiastereomersubcomponent self-assemblyGeneral Chemistryself-assemblyparacyclophanesCommunications3. Good health0104 chemical sciencesCrystallographySelf sortingchemistryRacemic mixtureSelf-assembly[2.2]paracyclophane
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CCDC 1919439: Experimental Crystal Structure Determination

2019

Related Article: Jana Anhäuser, Rakesh Puttreddy, Lukas Glanz, Andreas Schneider, Marianne Engeser, Kari Rissanen, Arne Lützen|2019|Chem.-Eur.J.|25|12294|doi:10.1002/chem.201903164

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(SP)-44'-[tricyclo[8.2.2.247]hexadeca-1(12)46101315-hexaene-512-diyl]dianiline methanol solvateExperimental 3D Coordinates
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CCDC 1919442: Experimental Crystal Structure Determination

2019

Related Article: Jana Anhäuser, Rakesh Puttreddy, Lukas Glanz, Andreas Schneider, Marianne Engeser, Kari Rissanen, Arne Lützen|2019|Chem.-Eur.J.|25|12294|doi:10.1002/chem.201903164

(rac)-hexakis(mu-NN'-[tricyclo[8.2.2.247]hexadeca-1(12)46101315-hexaene-512-diylbis(41-phenylene)]bis[1-(pyridin-2-yl)methanimine])-tetra-iron(ii) octakis(trifluoromethanesulfonate) unknown solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1919441: Experimental Crystal Structure Determination

2019

Related Article: Jana Anhäuser, Rakesh Puttreddy, Lukas Glanz, Andreas Schneider, Marianne Engeser, Kari Rissanen, Arne Lützen|2019|Chem.-Eur.J.|25|12294|doi:10.1002/chem.201903164

Space GroupCrystallography(ΛΛΛΛ)-hexakis(mu-(SP)-NN'-[tricyclo[8.2.2.247]hexadeca-1(12)46101315-hexaene-512-diylbis(41-phenylene)]bis[1-(pyridin-2-yl)methanimine])-tetra-iron(ii) octakis(trifluoromethanesulfonate) acetonitrile unknown solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1919440: Experimental Crystal Structure Determination

2019

Related Article: Jana Anhäuser, Rakesh Puttreddy, Lukas Glanz, Andreas Schneider, Marianne Engeser, Kari Rissanen, Arne Lützen|2019|Chem.-Eur.J.|25|12294|doi:10.1002/chem.201903164

(ΔΔΔΔ)-hexakis(mu-(RP)-NN'-[tricyclo[8.2.2.247]hexadeca-1(12)46101315-hexaene-512-diylbis(41-phenylene)]bis[1-(pyridin-2-yl)methanimine])-tetra-iron(ii) octakis(trifluoromethanesulfonate) acetonitrile unknown solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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