Resonance quality, radiative/ohmic losses and modal volume of Mie plasmons

International audience; Molecular sytems are efficiently coupled to metal nanoparticles via the excitation of localized surface plasmons-polaritons (SPPs). The coupling strength between SPP and emitters can be estimated from the ratio Q/V where Q and V refer to the mode quality factor and effective volume, respectively. In this letter, we investigate in details the properties of Mie plasmons supported by a metallic nanosphere (Q-factor, radiative and ohmic losses, modal volume). We particularly focus on the difficulty to unambiguously define the modal volumes of localized SPPs. This leads us to propose two definitions; the first one is based on Purcell factor for a dipolar emitter in close …