0000000001101252

AUTHOR

Giuseppe Ciccarella

0000-0003-4467-0922

showing 2 related works from this author

Cyclocarbonylation reactions of allylphenols and allylnaphthols catalyzed by Pd/C- 1,4-bis(diphenylphosphine)butane

2002

Palladium/activated carbon (Pd/C) in the presence of 1,4-bis(diphenylphosphino)butane is an efficient heterogeneous catalyst for cyclocarbonylation reactions of 2-allyl phenols affording five-, six-, and seven-membered ring lactones. Various examples of cyclocarbonylation are reported and the regioselectivity is compared with the homogeneous system. Both commercial Pd/C and Pd/C prepared from activated carbons obtained from vegetable and polymeric wastes are investigated.

Diphenylphosphinechemistry.chemical_elementRegioselectivityButaneGeneral ChemistryHeterogeneous catalysisChemical synthesisCatalysisInorganic Chemistrychemistry.chemical_compoundchemistryOrganic chemistryCarbonylationPalladiumApplied Organometallic Chemistry
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Photocatalytic Degradation of 4-nitrophenol in aqueous suspension by using polycristalline TiO2 samples impregnated with a Cu(II)-phthalocyanine

2002

In this paper, the preparation of polycrystalline TiO2 samples impregnated with a modified Cu(II)-phthalocyanine (TiO2–CuPc) is reported along with an investigation on the photocatalytic behavior of this system compared with bare TiO2 (both in the anatase and rutile form) and with TiO2 samples impregnated with not functionalized commercial phthalocyanine (TiO2–CuPc) or with metal free phthalocyanine (TiO2–Pc). The photocatalytic degradation of 4-nitrophenol (4-NP) was studied as a probe reaction. The presence of modified CuPc showed to be beneficial only for TiO2 (anatase) while the commercial not functionalized CuPc also slightly for both TiO2 (anatase) and TiO2 (rutile). The metal free Pc…

AnataseMaterials scienceTITANIUM-DIOXIDEPHTHALOCYANINE COMPLEXESProcess Chemistry and TechnologyInorganic chemistry4-NitrophenolOXIDATIONMineralization (biology)CatalysisReaction ratechemistry.chemical_compoundchemistryRutilePhthalocyaninePhotocatalysisCrystalliteGeneral Environmental Science
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