0000000001107614

AUTHOR

Roberta Grazia Toro

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Iron and lithium-iron alkyl phosphates as nanostructured material for rechargeable batteries

2018

Abstract Inorganic/organic hybrid materials composed by iron atoms bonded to an alkyl phosphate can be easily synthesized by mixing at 110 °C iron chlorides with tri-alkyl phosphates. Since structural information on these products are lacking and taking into account that lithium/iron organic hybrid materials are important in lithium ion battery technology we report here the physico-chemical characterization of different hybrid lithium/iron butylphosphates. These materials are characterized by the presence of elongated hexagonal crystals stable up to 315 °C. The insertion of lithium does not affect the local structure. Thanks to such structures the material can be electrochemically-cycled an…

Materials scienceHybrid materials; Lithium ion batteries; Tri n-butyl phosphates; Materials Science (all); Condensed Matter Physics; Mechanics of Materials; Mechanical Engineeringchemistry.chemical_element02 engineering and technology010402 general chemistry01 natural sciencesRedoxLithium-ion batteryIonchemistry.chemical_compoundGeneral Materials ScienceTri n-butyl phosphatesAlkylchemistry.chemical_classificationMechanical EngineeringAlkyl phosphate021001 nanoscience & nanotechnologyCondensed Matter Physics0104 chemical sciencesCharacterization (materials science)chemistryChemical engineeringLithium ion batteriesMechanics of MaterialsLithiumMaterials Science (all)Hybrid materials0210 nano-technologyHybrid material
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