0000000001116113

AUTHOR

Axel Gerdes

Bunker Cave stalagmites: an archive for central European Holocene climate variability

Holocene climate was characterised by variability on multi-centennial to multi-decadal time scales. In central Europe, these fluctuations were most pronounced during winter. Here we present a record of past winter climate variability for the last 10.8 ka based on four speleothems from Bunker Cave, western Germany. Due to its central European location, the cave site is particularly well suited to record changes in precipitation and temperature in response to changes in the North Atlantic realm. We present high-resolution records of δ<sup>18</sup>O, δ<sup>13</sup>C values and Mg/Ca ratios. Changes in the Mg/Ca ratio are attributed to past meteoric p…

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Age and mineralogy of supergene uranium minerals — Tools to unravel geomorphological and palaeohydrological processes in granitic terrains (Bohemian Massif, SE Germany)

Abstract Uranyl phosphates (torbernite, autunite, uranocircite, saleeite) and hydrated uranyl silicates (normal and beta-uranophane) found in various erosion levels and structures in the Late Variscan granites at the western edge of the Bohemian Massif, Germany, were the target of mineralogical investigations and age dating, using conventional and more advanced techniques such as Laser-Ablation-Inductive-Coupled-Plasma Mass Spectrometry (LA-ICP-MS). Supergene U minerals have an edge over other rock-forming minerals for such studies, because of their inherent ‘clock’ and their swift response to chemical and physical environmental changes on different scales. Uraniferous phoscretes and silcre…

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Preservation of successive diagenetic stages in Middle Triassic bonebeds: Evidence from in situ trace element and strontium isotope analysis of vertebrate fossils

Abstract Bonebeds comprise reworked and time averaged constituents of different phosphatic vertebrate remains and, hence, provide an ideal substrate for the study of long and short term diagenetic processes. To test whether trace elements (U, Sr, REE) and 87 Sr/ 86 Sr ratios can be used for distinguishing between successive diagenetic signals, we performed geochemical analyses on vertebrate remains (bones, teeth, scales and coprolites) from two Triassic bonebeds located near Palzem (Germany). Trace element analysis was done on 170 vertebrate remains by LA-ICP-MS while 87 Sr/ 86 Sr ratios were determined for 39 bioclasts using LA-MC-ICP-MS. Although a low inter- and intra-bioclast REE variab…

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Reconstruction of late Holocene autumn/winter precipitation variability in SW Romania from a high-resolution speleothem trace element record

We present the first high-resolution trace element (Mg/Ca, Sr/Ca, Ba/Ca) record from a stalagmite in southwestern Romania covering the last 3.6 ka, which provides the potential for quantitative climate reconstruction. Precise age control is based on three independent dating methods, in particular for the last 250 yr, where chemical lamina counting is combined with the identification of the 20th century radiocarbon bomb peak and Th-230/U dating. Long-term cave monitoring and model simulations of drip water and speleothem elemental variability indicate that precipitation-related processes are the main drivers of speleothem Mg/Ca ratios. Calibration against instrumental climate data shows a si…

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Zircon Dates Long-Lived Plume Dynamics in Oceanic Islands

In this contribution we report the first systematic study of zircon U-Pb geochronology and δ 18O-εHf(t) isotope geochemistry from 10 islands of the hot-spot related Galapagos Archipelago. The data extracted from the zircons allow them to be grouped into three types: (a) young zircons (0–∼4 Ma) with εHf(t) (∼5–13) and δ 18O (∼4–7) isotopic mantle signature with crystallization ages dating the islands, (b) zircons with εHf(t) (∼5–13) and δ 18O (∼5–7) isotopic mantle signature (∼4–164 Ma) which are interpreted to date the time of plume activity below the islands (∼164 Ma is the minimum time of impingement of the plume below the lithosphere), and (c) very old zircons (∼213–3,000 Ma) with mostly…

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