0000000001130994

AUTHOR

Marcel Mayor

showing 2 related works from this author

Photomodulation of Two-Dimensional Self-Assembly of Azobenzene-Hexa-peri-hexabenzocoronene-Azobenzene Triads

2019

International audience; Achieving exquisite control over self-assembly of functional polycyclic aromatic hydrocarbons (PAH) and nanographene (NG) is essential for their exploitation as active elements in (nano)technological applications. In the framework of our effort to leverage their functional complexity, we designed and synthesized two hexa-peri-hexabenzocoronene (HBC) triads, pAHA and oAHA, decorated with two light-responsive azobenzene moieties at the pseudo-para and ortho positions, respectively. Their photoisomerization in solution is demonstrated by UV–vis absorption. 1H NMR measurements of oAHA suggested 23% of Z-form can be obtained at a photostationary state with UV irradiation …

Technology[CHIM.MATE] Chemical Sciences/Material chemistryGeneral Chemical EngineeringHexa-peri-hexabenzocoronene[CHIM.MATE]Chemical Sciences/Material chemistry02 engineering and technologyGeneral Chemistry010402 general chemistry021001 nanoscience & nanotechnologyPhotochemistry01 natural sciences0104 chemical scienceschemistry.chemical_compoundAzobenzenechemistryMaterials ChemistrySelf-assembly0210 nano-technologyddc:600
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A Kapitza-Dirac-Talbot-Lau interferometer for highly polarizable molecules

2007

Research on matter waves is a thriving field of quantum physics and has recently stimulated many investigations with electrons, neutrons, atoms, Bose-condensed ensembles, cold clusters and hot molecules. Coherence experiments with complex objects are of interest for exploring the transition to classical physics, for measuring molecular properties and they have even been proposed for testing new models of space-time. For matter-wave experiments with complex molecules, the strongly dispersive effect of the interaction between the diffracted molecule and the grating wall is a major challenge because it imposes enormous constraints on the velocity selection of the molecular beam. We here descri…

PhysicsDiffractionQuantum PhysicsGeneral Physics and AstronomyFOS: Physical sciencesGratingInterferometryPolarizabilityPhase gratingQuantum mechanicsMoleculeMatter waveQuantum Physics (quant-ph)Coherence (physics)
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