0000000001137608
AUTHOR
Ben Kennedy
Advances in Fourier transform infrared spectroscopy of natural glasses: From sample preparation to data analysis
Fourier transform infrared spectroscopy (FTIR) is an analytical technique utilized to measure the concentrations of H and C species in volcanic glasses. Water and CO2 are the most abundant volatile species in volcanic systems. Water is present in magmas in higher concentrations than CO2 and is also more soluble at lower pressures, and, therefore it is the dominant volatile forming bubbles during volcanic eruptions. Dissolved water affects both phase equilibria and melt physical properties such as density and viscosity, therefore, water is important for understanding magmatic processes. Additionally, quantitative measurements of different volatile species using FTIR can be achieved at high s…
Halogen (Cl, F) release during explosive, effusive, and intrusive phases of the 2011 rhyolitic eruption at Cordón Caulle volcano (Chile)
We investigate sulphur, chlorine and fluorine release during explosive, effusive and intrusive phases of the 2011 Cordon Caulle eruption, with a focus on halogen devolatilization. Petrological analysis shows halogen release to have been promoted by isobaric crystallization in slowly-cooled magma that was emplaced in a lava flow and sub-vent intrusion. Fluorine in particular mobilized only after extensive groundmass crystallization and incipient devitrification. By 2017, the gas emitted from vent-proximal fumaroles had hydrothermal compositions, with HCl/HF ratios decreasing with decreasing temperature. We estimate that the eruption could eventually emit up to 0.84 Mt of SO2, 6.3 Mt of HCl, …