0000000001154878

AUTHOR

Tony Khoury

showing 2 related works from this author

Three-Metal Coordination by Novel Bisporphyrin Architectures

2010

The synthesis and characterization of a new type of bisporphyrin system is reported where the two macrocycles are linked in a cofacial arrangement by a substituted carbazole bridge. The three nitrogen atoms of the carbazole bridge in the compounds may complex a metal ion and thus provide a new parameter for varying the physical properties and flexibility of the dyad after formation of a three-metal system. In the present study, four bis-metalloporphyrin complexes were synthesized and examined by electrochemistry and thin-layer spectroelectrochemistry in CH(2)Cl(2) and PhCN. Two of the examined compounds contain Cu(II) or Zn(II) porphyrins and a carbazole linker with a bound Cu(II) ion, givi…

PorphyrinsMolecular StructureMetalloporphyrinsChemistryCarbazoleStereoisomerismPhotochemistryElectrochemistryRedoxIonInorganic ChemistryMetalZincchemistry.chemical_compoundvisual_artPolymer chemistryvisual_art.visual_art_mediumPhysical and Theoretical ChemistryLinkerCopperInorganic Chemistry
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CCDC 1502145: Experimental Crystal Structure Determination

2016

Related Article: Jean-Michel Barbe, Benoit Habermeyer, Tony Khoury, Claude P. Gros, Philippe Richard, Ping Chen, and Karl M. Kadish|2010|Inorg.Chem.|49|8929|doi:10.1021/ic101170k

Space GroupCrystallographyCrystal System(mu-36-di-t-butyl-18-bis(((4-(1317-diethyl-23781218-hexamethylporphyrinato-5-yl)phenyl)imino)methyl)carbazol-9-ido)-chloro-tri-copper(ii)Crystal StructureCell ParametersExperimental 3D Coordinates
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