0000000001154878
AUTHOR
Tony Khoury
Three-Metal Coordination by Novel Bisporphyrin Architectures
The synthesis and characterization of a new type of bisporphyrin system is reported where the two macrocycles are linked in a cofacial arrangement by a substituted carbazole bridge. The three nitrogen atoms of the carbazole bridge in the compounds may complex a metal ion and thus provide a new parameter for varying the physical properties and flexibility of the dyad after formation of a three-metal system. In the present study, four bis-metalloporphyrin complexes were synthesized and examined by electrochemistry and thin-layer spectroelectrochemistry in CH(2)Cl(2) and PhCN. Two of the examined compounds contain Cu(II) or Zn(II) porphyrins and a carbazole linker with a bound Cu(II) ion, givi…
CCDC 1502145: Experimental Crystal Structure Determination
Related Article: Jean-Michel Barbe, Benoit Habermeyer, Tony Khoury, Claude P. Gros, Philippe Richard, Ping Chen, and Karl M. Kadish|2010|Inorg.Chem.|49|8929|doi:10.1021/ic101170k