Author: Chandan Dey

0000000001162671

AUTHOR

Chandan Dey

Effect of Nonconstituent Additive Ions on the Controlled Crystallization of Lanthanide-Based Preyssler Polyoxometalates

Preyssler-type polyoxometalates (POMs) encapsulating lanthanide ions have been shown to provide ideal examples of single-molecule magnets and spin-qubits. However, the advances in this area are limited by the quality and size of the crystals. In this work, the role of additives ions in the crystallization of these POMs from aqueous solutions has been investigated. More specifically, we have studied the influence of Al3+, Y3+, and In3+ on the crystallization process of K12[MP5W30O110] (where M = Gd and Y). The results show that the concentration of these ions in the solution plays an important role in controlling the crystallization rate of the grown POM crystals leading to a significant inc…

research product

CSD 2024846: Experimental Crystal Structure Determination

Related Article: Iván Gómez-Muñoz, Chandan Dey, Eugenio Coronado|2023|Cryst.Growth Des.|23|3544|doi:10.1021/acs.cgd.3c00046

research product

CSD 2024847: Experimental Crystal Structure Determination

Related Article: Iván Gómez-Muñoz, Chandan Dey, Eugenio Coronado|2023|Cryst.Growth Des.|23|3544|doi:10.1021/acs.cgd.3c00046

research product

CSD 2235856: Experimental Crystal Structure Determination

Related Article: Iván Gómez-Muñoz, Chandan Dey, Eugenio Coronado|2023|Cryst.Growth Des.|23|3544|doi:10.1021/acs.cgd.3c00046

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PEPhysical Sciences and Engineering
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LSLife Sciences
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