0000000001164109

AUTHOR

Sergio Andrés

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CO2fixation and activation by metal complexes of small polyazacyclophanes

2001

The interaction of the cyclophanes 2,6,9,13-tetraaza[14]paracyclophane (L1) and 2,6,9,13-tetraaza[14]metacyclophane (L2) and of their Zn2+ and Cu2+ complexes with CO32− and its protonated forms is described. The actuation of the Cu2+–L2 system as an electrocatalyst for the reduction of CO2 to CO in water is advanced. Copyright © 2001 John Wiley & Sons, Ltd.

Metalchemistry.chemical_compoundchemistryvisual_artOrganic ChemistryCarbon fixationCarbon dioxideInorganic chemistryvisual_art.visual_art_mediumProtonationPhysical and Theoretical ChemistryElectrocatalystJournal of Physical Organic Chemistry
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