CO2fixation and activation by metal complexes of small polyazacyclophanes

6533b862fe1ef96bd12c74eb

RESEARCH PRODUCT

CO2fixation and activation by metal complexes of small polyazacyclophanes

Victor Marcelino Jose Antonio Ramirez Antonio Doménech José M. Llinares Beatriu Escuder Santiago V. Luis Sergio Andrés Enrique García-españa Conxa Soriano

subject

Metal chemistry.chemical_compound chemistry visual_art Organic Chemistry Carbon fixation Carbon dioxide Inorganic chemistry visual_art.visual_art_medium Protonation Physical and Theoretical Chemistry Electrocatalyst

description

The interaction of the cyclophanes 2,6,9,13-tetraaza[14]paracyclophane (L1) and 2,6,9,13-tetraaza[14]metacyclophane (L2) and of their Zn2+ and Cu2+ complexes with CO32− and its protonated forms is described. The actuation of the Cu2+–L2 system as an electrocatalyst for the reduction of CO2 to CO in water is advanced. Copyright © 2001 John Wiley & Sons, Ltd.

year	journal	country	edition	language
2001-07-01	Journal of Physical Organic Chemistry

https://doi.org/10.1002/poc.400

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