Electron Accumulative Molecules.
With the goal to produce molecules with high electron accepting capacity and low reorganization energy upon gaining one or more electrons, a synthesis procedure leading to the formation of a B–N(aromatic) bond in a cluster has been developed. The research was focused on the development of a molecular structure able to accept and release a specific number of electrons without decomposing or change in its structural arrangement. The synthetic procedure consists of a parallel decomposition reaction to generate a reactive electrophile and a synthesis reaction to generate the B–N(aromatic) bond. This procedure has paved the way to produce the metallacarboranylviologen [M(C2B9H11)(C2B9H10)-NC5H4-…
CCDC 1581998: Experimental Crystal Structure Determination
Related Article: Ana B. Buades, Víctor Sanchez Arderiu, David Olid-Britos, Clara Viñas, Reijo Sillanpää, Matti Haukka, Xavier Fontrodona, Markos Paradinas, Carmen Ocal, Francesc Teixidor|2018|J.Am.Chem.Soc.|140|2957|doi:10.1021/jacs.7b12815
CCDC 1582429: Experimental Crystal Structure Determination
Related Article: Ana B. Buades, Víctor Sanchez Arderiu, David Olid-Britos, Clara Viñas, Reijo Sillanpää, Matti Haukka, Xavier Fontrodona, Markos Paradinas, Carmen Ocal, Francesc Teixidor|2018|J.Am.Chem.Soc.|140|2957|doi:10.1021/jacs.7b12815
CCDC 1582000: Experimental Crystal Structure Determination
Related Article: Ana B. Buades, Víctor Sanchez Arderiu, David Olid-Britos, Clara Viñas, Reijo Sillanpää, Matti Haukka, Xavier Fontrodona, Markos Paradinas, Carmen Ocal, Francesc Teixidor|2018|J.Am.Chem.Soc.|140|2957|doi:10.1021/jacs.7b12815
CCDC 1582430: Experimental Crystal Structure Determination
Related Article: Ana B. Buades, Víctor Sanchez Arderiu, David Olid-Britos, Clara Viñas, Reijo Sillanpää, Matti Haukka, Xavier Fontrodona, Markos Paradinas, Carmen Ocal, Francesc Teixidor|2018|J.Am.Chem.Soc.|140|2957|doi:10.1021/jacs.7b12815
CCDC 1582431: Experimental Crystal Structure Determination
Related Article: Ana B. Buades, Víctor Sanchez Arderiu, David Olid-Britos, Clara Viñas, Reijo Sillanpää, Matti Haukka, Xavier Fontrodona, Markos Paradinas, Carmen Ocal, Francesc Teixidor|2018|J.Am.Chem.Soc.|140|2957|doi:10.1021/jacs.7b12815