0000000001166766
AUTHOR
Germain Bayon
Rare earth element and neodymium isotope tracing of sedimentary rock weathering
Chemical weathering plays an important role in sequestering atmospheric CO2, but its potential influence on global climate over geological timescales remains debated. To some extent, this uncertainty arises from the difficulty in separating the respective contribution of sedimentary and crystalline silicate rocks to past weathering rates in the geological record; two types of rocks having presumably different impact on the long-term carbon cycle. In this study, we investigate the use of rare earth element (REE) and neodymium isotopes (εNd) in leached iron oxide fractions of river sediments for tracing the origin of weathered rocks on continents. A new index, called ‘concavity index’ (CI), i…
Evolution of the neodymium isotopic signature of neritic seawater on a northwestern Pacific margin: new constrains on possible end-members for the composition of deep-water masses in the Late Cretaceous ocean.
11 pages; International audience; The Neodymium(Nd) isotope composition of fish remains has beenwidely used to track past changes in oceanic circulation. Although the number of published Nd isotope data for the Cretaceous has markedly increased in the last years, no consensus has been reached on the structure of the oceanic circulation and its evolution during the Late Cretaceous. Yet this period is characterised bymajor geodynamical and climatic changes andmarked by the disappearance of global oceanic anoxic events inwhich changes in oceanic circulation modesmay have played a significant role. In this study we present the first record of Nd isotopic composition of fish remains from contine…
Deep basin record evolution of chemical weathering and physical erosion as response to the tectonic uplift of the South African Plateau during the upper Cretaceous
<p>During the upper Cretaceous the South African Plateau underwent an uneven uplift period that coincided with the onset of a long-term climate cooling. This uplift recorded two pulses, an early pulse during the Turonian that affected the eastern margin and a later pulse occurred during the Campanian affecting the western margin (van der Beek et al., 2002; Braun et al., 2014; Baby et al., 2020). We aim here to determine the response of physical erosion and chemical weathering to this tectonic event, that may have played a role in the long-term climate cooling by promoting silicate weathering and associated atmospheric CO<sub>2</sub> drawdown. In thi…
Hafnium-neodymium isotope evidence for enhanced weathering and tectonic-climate interactions during the Late Cretaceous
<p>Over million-year timescale the carbon cycle evolution is driven by mantle CO<sub>2</sub> degassing (source) and by continental weathering that drawdowns atmospheric CO<sub>2</sub> through silicate weathering reactions (sink). Based on a novel geochemical proxy of chemical weathering intensity (i.e. using measurements of Hf and Nd isotope ratios in clay-size fractions of sediments) and clay mineralogy, we discuss the links between tectonic, continental weathering and climate evolution during the late Cretaceous. That period records the very first step of the last greenhouse to icehouse transition and is concomitant to …
Goldschmidt Abstracts 2010 – F
We report on two novel procedures for the determination of several trace elements in seawater, including elements characterized by very low abundance (sub-0.1 to 1 ng l-1) in the ocean, such as REEs, Hf, and Th. Our methods are based on the procedure developed recently by Bayon et al. [1], and applied successfully to a wide range of geological samples. It involves addition of a Tm spike and pre-concentration using co-precipitation, prior to analysis by inductively coupled plasma-sector field mass spectrometry (ICP-SFMS). The addition of a small amount of Tm to the sample produces a positive Tm anomaly in the resulting REE pattern, which allows calculation of precise trace element concentrat…
Seep-carbonate lamination controlled by cyclic particle flux.
Authigenic carbonate build-ups develop at seafloor methane-seeps, where microbially mediated sulphate-dependent anaerobic oxidation of methane facilitates carbonate precipitation. Despite being valuable recorders of past methane seepage events, their role as archives of atmospheric processes has not been examined. Here we show that cyclic sedimentation pulses related to the Indian monsoon in concert with authigenic precipitation of methane-derived aragonite gave rise to a well-laminated carbonate build-up within the oxygen minimum zone off Pakistan (northern Arabian Sea). U–Th dating indicates that the build-up grew during past ~1,130 years, creating an exceptional high-resolution archive o…
The large-scale evolution of neodymium isotopic composition in the global modern and Holocene ocean revealed from seawater data and other records
International audience; The large-scale evolution of neodymium isotopic composition in the global modern and Holocene ocean revealed from seawater data and other records. Kazuyo Tachikawa and project members Neodymium isotopic compositions (143 Nd/ 144 Nd or ε Nd) have been used as a tracer of water masses and lithogenic inputs to the ocean. To further evaluate the faithfulness of this tracer, we have updated a global seawater ε Nd database and combined it with hydrography parameters (temperature, salinity, nutrients and oxygen concentrations), carbon isotopic ratio and radiocarbon of dissolved inorganic carbon. Archive ε Nd data are compiled for leachates, foraminiferal tests, deep-sea cor…
Evolution of neodymium isotopic signature of seawater during the Late Cretaceous: implications for intermediate and deep circulation.
20 pages; International audience; Neodymium isotopic compositions (εNd) have been largely used for the last fifty years as a tracer of past ocean circulation, and more intensively during the last decade to investigate ocean circulation during the Cretaceous period. Despite a growing set of data, circulation patterns still remain unclear during this period. In particular, the identification of the deep-water masses and their spatial extension within the different oceanic basins are poorly constrained. In this study we present new deep-water εNd data inferred from the Nd isotope composition of fish remains and Fe–Mn oxyhydroxide coatings on foraminifera tests, along with new εNd data of resid…
Limestone petrography and geochemical composition at ROV station GeoB12353-11
Authigenic carbonate build-ups develop at seafloor methane-seeps, where microbially mediated sulphate-dependent anaerobic oxidation of methane facilitates carbonate precipitation. Despite being valuable recorders of past methane seepage events, their role as archives of atmospheric processes has not been examined. Here we show that cyclic sedimentation pulses related to the Indian monsoon in concert with authigenic precipitation of methane-derived aragonite gave rise to a well-laminated carbonate build-up within the oxygen minimum zone off Pakistan (northern Arabian Sea). U?Th dating indicates that the build-up grew during past ~1,130 years, creating an exceptional high-resolution archive o…