0000000001217880

AUTHOR

X. Thomas

showing 2 related works from this author

Methane line parameters in the HITRAN2012 database

2013

International audience; The compilation of methane molecular line parameters was updated to include new global analyses and measurements for 12CH4, 13CH4 and 12CH3D. Over 70% of the methane parameters in HITRAN2008 were replaced; existing parameters retained were the microwave lines and the Dyad of 13CH4 near 7 μm and ν6 of 13CH3D near 8.7 μm, 12CH3D (7-4076 cm-1), hot bands of 12CH4 (1887-3370 cm-1) and normal sample CH4 (4800-5550 cm-1 and 8000-9200 cm-1). With a minimum intensity at 296 K in units of cm-1/(molecule cm-2) set to 10-37 for the far-IR and 10-29 for the mid- and near-IR, the methane database increased from 290,091 lines in HITRAN2008 to 468,013 lines, and three-fourths of th…

Materials science010504 meteorology & atmospheric sciencesPlanetscomputer.software_genre01 natural sciencesSpectral lineMethaneCavity ring-down spectroscopy010309 opticschemistry.chemical_compoundLine parameters0103 physical sciencesIsotopologueSpectroscopy0105 earth and related environmental sciencesLine (formation)[PHYS.PHYS.PHYS-OPTICS]Physics [physics]/Physics [physics]/Optics [physics.optics][ PHYS.PHYS.PHYS-OPTICS ] Physics [physics]/Physics [physics]/Optics [physics.optics]RadiationDatabaseDifferential optical absorption spectroscopyExoplanetsRemote sensingAtomic and Molecular Physics and OpticschemistryHITRAN databaseAtomic physicsGround statecomputerMethaneMicrowaveJournal of Quantitative Spectroscopy and Radiative Transfer
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New assignments in the 2μm transparency window of the 12CH4 Octad band system

2013

Abstract This paper reports new assignments of rovibrational transitions of 12 CH 4 bands in the range 4600–4887  cm −1 which is usually referred to as a part of the 2 μm methane transparency window. Several experimental data sources for methane line positions and intensities were combined for this analysis. Three long path Fourier transform spectra newly recorded in Reims with 1603 m absorption path length and pressures of 1, 7 and 34 hPa for samples of natural abundance CH 4 provided new measurements of 12 CH 4 lines. Older spectra for 13 CH 4 (90% purity) from JPL with 73 m absorption path length were used to identify the corresponding lines. Most of the lines in this region belong to th…

PhysicsRadiationbusiness.industryFourier transform spectraRotational–vibrational spectroscopyAtomic and Molecular Physics and OpticsSpectral lineMethaneDipolechemistry.chemical_compoundsymbols.namesakeOpticschemistryPath lengthsymbolsAtomic physicsGround stateHamiltonian (quantum mechanics)businessSpectroscopyJournal of Quantitative Spectroscopy and Radiative Transfer
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