Author: Miguel A. Rodríguez

0000000001225955

AUTHOR

Miguel A. Rodríguez

A new electrophilic addition to acetylenes. Synthesis of 1,2-iodofunctionalized olefins

Abstract Acetylenes react with bis(pyridine)iodo(I) tetrafluoroborate ( 1 ) in the presence of a wide variety of nucleophiles (F, Cl, Br, I, SCN, pyridine, OAc, anisole, H) to give 1,2-iodofunctionalized olefins ( 4 ).

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