0000000001242087

AUTHOR

Marc Morant Giner

Hybrid heterostructures and materials based on transition metal dichalcogenides

La irrupción de los nanomateriales en la vida moderna es un claro indicador del avance científico. El diseño de materiales a la carta permite establecer un control preciso sobre las propiedades finales de estos. El objetivo principal que ha motivado la presente Tesis es la combinación y funcionalización de láminas de MoS2 ultrafinas químicamente exfoliadas (ce-MoS2) con diferentes sistemas de base molecular. La Tesis se divide en los siguientes Capítulos: Capítulo I: En primer lugar, se introducen brevemente los nanomateriales. En segundo lugar, se describen los materiales bidimensionales (2D). A continuación, se detallan algunos aspectos generales de los dicalcogenuros de metales de transi…

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WS2/MoS2 Heterostructures through Thermal Treatment of MoS2 Layers Electrostatically Functionalized with W3S4 Molecular Clusters

The preparation of 2D stacked layers that combine flakes of different nature, gives rise to countless number of heterostructures where new band alignments, defined at the interfaces, control the electronic properties of the system. Among the large family of 2D/2D heterostructures, the one formed by the combination of the most common semiconducting transition metal dichalcogenides WS2/MoS2, has awaken great interest due to its photovoltaic and photoelectrochemical properties. Solution as well as dry physical methods have been developed to optimize the synthesis of these heterostructures. Here a suspension of negatively charged MoS2 flakes is mixed with a methanolic solution of a cationic W3S…

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