Elettrodeposizione di leghe nanostrutturate a base di stagno

Nanostructures of different oxides/hydroxides grown in nanoporous templates by electrochemical methods.

Elettrodo al piombo, metodo per la sua realizzazione ed accumulatore comprendente l’elettrodo

Toward Tin-Based High-Capacity Anode for Lithium-Ion Battery

Electrochemical deposition of SnCo alloys inside the nanometric pores of commercial membranes is described. Composition, morphology and crystallographic structure of the synthesized nanostructured alloys are reported as well as the results of electrochemical tests carried out both in half-cell and in full battery configuration to investigate the performance of these SnCo alloys as anodes for lithium-ion batteries. Optimized depositions yielded nanostructured alloys that performed 200 deep galvanostatic cycles at C/2 and 30 °C with 80 % capacity retention and coulombic efficiency higher than 97 % after 40 cycles Moreover, charge-discharge rate capability tests showed the high performance of …

Nanostructured Material Fabrication for Energy Conversion

Nanostructured Material Fabrication for Energy Conversion

The electrochemical deposition is a suitable via to fabricate nanostructured materials for energy conversion, and for other purposes. This paper deals with the electrochemical synthesis of nanostructured alloys and ruthenium oxide, which can be used in Li-ion batteries and polymer electrolyte membrane electrolyzers.

Metodo di realizzazione di un elettrodo ad elevata densità energetica ed elettrodo ottenibile con tale metodo

A viable path toward a high energy density anode for lithium-ion batteries

Effect of temperature on the growth of alfa-PbO2 nanostructures

Abstract Ordered arrays of α-PbO 2 nanostructures were grown by galvanostatic anodic deposition into the channels of alumina templates. Electrodepositions were performed in an aqueous solution containing lead acetate and sodium acetate at pH 5.4. Bath temperature and electrodeposition time were varied to check their effect on the growth of nanostructures. It has been found that filling of alumina pores is independent of the time and electrodeposition temperature, whilst height and growth kinetics of nanostructures vary with both parameters. Temperature greatly influences morphology: wires grown at room temperature consisted of clusters of particles, leading to poorly compact structures, whi…

Fabbricazione elettrochimica e caratterizzazione di materiali nanostrutturati

High-performing Sn-Co nanowire electrodes as anodes for lithium-ion batteries

Abstract The preparation of Sn 2 Co 3 nanowire arrays (NWs) electrogrown inside the channels of polycarbonate membranes and their characterization as anodes for Li-ion batteries both in half-cell vs. Li and in battery configuration are reported. The Sn 2 Co 3 NW electrodes tested by deep galvanostatic charge/discharge cycles in ethylene carbonate-dimethylcarbonate (1:1) – LiPF 6 1 M displayed 80% capacity retention after 200 cycles at C/2 and 30 °C, and a high charge and discharge rate capability at C-rate from C/3 (0.33 A/g) to 10C (10 A/g) at 30° and 10 °C. Electrodes with the highest alloy loading delivered up to 0.6 mAh cm −2 at C/2. The performance of these electrodes in battery config…

Studio del processo di recupero di membrane di policarbonato