Generalized effective stress concept for saturated active clays

Experimental evidence shows that changes in pore-water chemistry can significantly affect the mechanical behavior of saturated active clays. Despite this evidence, how the chemical composition of the pore water can be considered in effective stress definition is questionable. This paper develops the concept of generalized effective stress for active clays. To this end, physicochemical studies on water–clay mineral interactions are used to clearly define the different types of ions and water present in an active clay. In particular, the presence of both movable and non-movable ions within the liquid water is highlighted. Taking this into account, thermodynamic and geochemistry principles ar…