Author: Billy Phillips

0000000001284660

AUTHOR

Billy Phillips

Jahn–Teller effects in Au25(SR)18

The relationship between oxidation state, structure, and magnetism in many molecules is well described by first-order Jahn–Teller distortions. This relationship is not yet well defined for ligated nanoclusters and nanoparticles, especially the nano-technologically relevant gold-thiolate protected metal clusters. Here we interrogate the relationships between structure, magnetism, and oxidation state for the three stable oxidation states, 1, 0 and +1 of the thiolate protected nanocluster Au25(SR)18. We present the single crystal X-ray structures of the previously undetermined charge state Au25(SR)18+1, as well as a higher quality single crystal structure of the neutral compound Au25(SR)180 . …

research product

CCDC 1055143: Experimental Crystal Structure Determination

Related Article: Marcus A. Tofanelli, Kirsi Salorinne, Thomas W. Ni, Sami Malola, Brian Newell, Billy Phillips, Hannu Häkkinen, Christopher J. Ackerson|2016|Chemical Science|7|1882|doi:10.1039/C5SC02134K

research product

CCDC 1055144: Experimental Crystal Structure Determination

Related Article: Marcus A. Tofanelli, Kirsi Salorinne, Thomas W. Ni, Sami Malola, Brian Newell, Billy Phillips, Hannu Häkkinen, Christopher J. Ackerson|2016|Chemical Science|7|1882|doi:10.1039/C5SC02134K

research product

PEPhysical Sciences and Engineering
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LSLife Sciences
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