Molecular alignment echoes probe collision-induced rotational-speed changes

2020

International audience; We show that the decays with pressure of the rotational alignment echoes induced in N 2 O-He gas mixtures by two ultrashort laser pulses with various delays show detailed information about collision-induced changes of the rotational speed of the molecules. Measurements and classical calculations consistently demonstrate that collisions reduce the echo amplitude all the more efficiently when the echo appears late. We quantitatively explain this behavior by the filamentation of the classical rotational phase space induced by the first pulse and the narrowing of the filaments with time. The above mentioned variation of the echo decay then reflects the ability of collisi…