0000000001298828

AUTHOR

Yulia G. Gorbunova

showing 48 related works from this author

Electrochemical and spectroscopic studies of poly(diethoxyphosphoryl)porphyrins

2011

Abstract The synthesis and electrochemical characterization of two related series of porphyrins bearing diethoxyphosphoryl groups are reported. One group of compounds is represented as (T( p -R)PP)M where R = phos = P(O)(OEt) 2 and M = Zn(II) or H 2 while the other is represented as (di( p -R)Pdi(phos)P)M where R = P(O)(OEt) 2 , H or CH 3 and M = Zn(II) or H 2 . Each porphyrin was investigated by electrochemistry and thin-layer spectroelectrochemistry in CH 2 Cl 2 , CDCl 3 , CHCl 3 or PhCN containing tetra- n -butylammonium perchlorate (TBAP) as supporting electrolyte. The highly electron-withdrawing P(O)(OEt) 2 groups lead to easier reductions and harder oxidations than the two comparison …

010405 organic chemistryStereochemistryGeneral Chemical Engineeringchemistry.chemical_elementProtonationZinc010402 general chemistryElectrochemistry01 natural sciencesMedicinal chemistryChemical synthesisPorphyrin0104 chemical sciencesAnalytical ChemistryPerchloratechemistry.chemical_compoundchemistryTetraphenylporphyrinElectrochemistry[CHIM]Chemical SciencesTriphenylphosphine oxideComputingMilieux_MISCELLANEOUS
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On the synthesis of functionalized porphyrins and porphyrin conjugates via β-aminoporphyrins

2016

International audience; The synthesis of functionalized porphyrins and their conjugates from meso-tetraarylporphyrins through the acylation and the oxidation of beta-aminoporphyrins was investigated. 2,3-Dioxochlorins were prepared by the oxidation of a variety of beta-aminoporphyrins and subsequently used in a condensation reaction with functionalized aromatic aldehydes and ammonium acetate to form beta-functionalized porphyrins bearing a fused imidazole ring. Under optimized experimental conditions both reactions tolerate various functional groups and afford the products in an appropriate overall yield. The mildness and usefulness of this methodology are illustrated by several examples in…

coordination010402 general chemistryRing (chemistry)01 natural sciences[ CHIM ] Chemical SciencesCatalysisphotoinduced electron-transferAcylationchemistry.chemical_compoundMaterials Chemistrypolycyclic compoundsImidazoleOrganic chemistry[CHIM]Chemical Sciencesalpha-dionesbuilding-blockspyrrolic position010405 organic chemistrysensitized solar-cellsbodipy dyesGeneral Chemistryefficient peripheral functionalizationCondensation reactionCombinatorial chemistryPorphyrin0104 chemical scienceswater-solubilizationchemistryYield (chemistry)systemsAmmonium acetateConjugate
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Post-synthetic methods for functionalization of imidazole-fused porphyrins

2018

Several methods for the post-synthetic modification of imidazo[4,5-[Formula: see text]]porphyrins are reported. First, a synthetic approach to the isomeric difunctionalized porphyrins, containing two [Formula: see text]-fused 2-aryl-1[Formula: see text]-imidazole cycles at adjacent or opposite pyrrole rings of the macrocycle is developed. The core chemistry of this synthetic route is the transformation of 2-aryl-1[Formula: see text]-imidazo[4,5-[Formula: see text]]porphyrins into corresponding imidazodioxochlorins followed by Debus–Radziszewski condensation with aromatic aldehyde. Next, 2-(4-bromophenyl)-1[Formula: see text]-imidazo[4,5-[Formula: see text]]-5,10,15,20-tetramesitylporphyrin…

chemistry.chemical_compound010405 organic chemistryChemistrySurface modificationImidazoleGeneral Chemistry010402 general chemistry01 natural sciencesCombinatorial chemistryCoupling reaction0104 chemical sciencesJournal of Porphyrins and Phthalocyanines
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Platinum( ) and palladium( ) complexes with electron-deficient -diethoxyphosphorylporphyrins: synthesis, structure and tuning of photophysical prope…

2019

The luminescence quenching by O and photodegradation of Pt( ) and Pd( ) phosphorylporphyrins are reported.

Materials scienceQuenching (fluorescence)010405 organic chemistrychemistry.chemical_element010402 general chemistry01 natural sciencesToluene3. Good health0104 chemical sciencesInorganic Chemistrychemistry.chemical_compoundchemistryCovalent bondPhysical chemistryLuminescencePhosphorescencePlatinumSingle crystalPalladium
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Synthesis of (trans-A2)BC-Type Porphyrins with Acceptor Diethoxyphosphoryl and Various Donor Groups and their Assembling in the Solid State and at In…

2019

ChemistryOrganic ChemistryPolymer chemistrySolid-statePhysical and Theoretical ChemistryLuminescenceAcceptorAminationCatalysisEuropean Journal of Organic Chemistry
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Imidazoporphyrins as supramolecular tectons: synthesis and self-assembly of zinc 2-(4-pyridyl)-1H-imidazo[4,5-b]porphyrinate

2019

International audience; 5,10,15,20-Tetramesityl-2-(4-pyridyl)-1H-imidazo[4,5-b]porphyrin (PyPor) bearing a pyridine donor site connected to the tetrapyrrolic macrocycle by a rigid imidazole linker was prepared in high yield by the condensation of the corresponding 2,3-dioxochlorin and 4-formylpyridine in the presence of ammonium acetate. After the insertion of a metal ion capable of metal–ligand axial coordination, namely Zn(II), this compound afforded self-complementary porphyrin PyPorZn which was suitable for self-assembly. In the crystals, this complex exists as a zigzag coordination polymer formed through the axial coordination of the pyridine nitrogen atom to the zinc ion of the neighb…

ChemistryLigandCoordination polymer[CHIM.ORGA]Chemical Sciences/Organic chemistrySupramolecular chemistrychemistry.chemical_element02 engineering and technologyGeneral ChemistryZinc010402 general chemistry021001 nanoscience & nanotechnologyCondensed Matter Physics01 natural sciencesPorphyrin0104 chemical scienceschemistry.chemical_compoundCrystallographyMonomerPyridineImidazoleGeneral Materials Science[CHIM.COOR]Chemical Sciences/Coordination chemistry0210 nano-technology
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Coordination self-assembly through weak interactions in meso-dialkoxyphosphoryl-substituted zinc porphyrinates.

2019

International audience; The self-assembly of seven zinc 10-(dialkoxyphosphoryl)-5,15-diarylporphyrinates Zn5-Zn11 containing different substituents at the phosphonate and aryl groups was investigated. Single crystals of Zn5-Zn9 complexes were grown under the same conditions and analyzed by X-ray structural analysis. A supramolecular self-assembly is observed in all crystals through weak coordinative bonding of the phosphoryl group of one porphyrin molecule to the zinc(II) ion of a second porphyrin molecule. The geometry of the porphyrin macrocycle is similar in all of the studied crystals and the central zinc atom in each case adopts a distorted tetragonal pyramidal environment. However, th…

Chloroform010405 organic chemistry[CHIM.ORGA]Chemical Sciences/Organic chemistryArylSupramolecular chemistrychemistry.chemical_elementZinc010402 general chemistry01 natural sciencesPorphyrinToluene0104 chemical sciencesInorganic Chemistrychemistry.chemical_compoundCrystallographychemistryMolecule[CHIM.COOR]Chemical Sciences/Coordination chemistrySelf-assemblyDalton transactions (Cambridge, England : 2003)
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Heterocycle-appended porphyrins: synthesis and challenges

2020

Abstract Porphyrin and their versatile metal complexes represent a special class of coordination compounds possessing unique physical-chemical properties. The achievements in the development of the synthetic approaches for the modification of the porphyrin macrocycle allowed the preparation of a variety of functional derivatives for diverse applications. Among a broad diversity of synthetically available metalloporphyrins meso-substituted tetrapyrroles are comprehensively investigated. However, β-substituted porphyrins could be considered as the most suitable models for mimicking the key roles of naturally occurring dyes in vital processes. The introduction of various substituents to the β-…

chemistry.chemical_classificationAnnulation010405 organic chemistry010402 general chemistrySpecial class01 natural sciencesPorphyrinCombinatorial chemistry0104 chemical sciencesCoordination complexInorganic Chemistrychemistry.chemical_compoundchemistryMaterials ChemistryPhysical and Theoretical ChemistryCoordination Chemistry Reviews
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Synthesis of porphyrin-bis(polyazamacrocycle) triads via Suzuki coupling reaction

2014

Suzuki–Miyaura cross-coupling reaction has been used for the synthesis of tricyclic architectures based on trans-A2B2-porphyrins and bisaminal-protected polyazamacrocycles which are linked directly or by a p-phenylene spacer. This modular approach allowed the synthesis of ligands with various substituted porphyrin macrocycles and bisaminal-protected tetraazamacrocycles possessing different cavity sizes. These molecules can be assembled into dimers using a DABCO linker. Deprotection of these compounds afforded porphyrin-bis(polyazamacrocycle) triads.

chemistry.chemical_compoundSuzuki reactionChemistryStereochemistry[CHIM]Chemical SciencesMoleculeGeneral ChemistryDABCOLinkerCombinatorial chemistryPorphyrinComputingMilieux_MISCELLANEOUSJournal of Porphyrins and Phthalocyanines
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Insights into the Synthesis and the Solution Behavior ofmeso-Aryloxy- and Alkoxy-Substituted Porphyrins

2015

meso-RO-appended (R = alkyl, aryl) porphyrins bearing one or two OR substituents at the tetrapyrrolic macrocycle were synthesized in good yields from 5,15-dibromo-10,20-diphenylporphyrins 2H(Br2DPP), Ni(Br2DPP) and Zn(Br2DPP) using an SNAr reaction. By varying the solvent, the base, the temperature, and the time of the reaction, the optimum conditions were established, and the selective introduction of one or two meso-RO substituents at the periphery of the macrocycle was achieved. Moreover, monofunctionalization of Ni(Br2DPP) according to an SNAr reaction was used as a key step for the synthesis of rarely explored unsymmetrical porphyrinyl alkyl ethers. 1H NMR studies of these ethers in CD…

chemistry.chemical_classification010405 organic chemistryStereochemistryArylOrganic ChemistryHomogeneous catalysis010402 general chemistry01 natural sciencesMedicinal chemistry0104 chemical scienceschemistry.chemical_compoundchemistryNucleophilic aromatic substitutionNucleophilic substitutionAlkoxy groupMoleculePhysical and Theoretical ChemistryAlkylDerivative (chemistry)European Journal of Organic Chemistry
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Insights into the crystal packing of phosphorylporphyrins based on the topology of their intermolecular interaction energies

2014

Four metal complexes of 5,15-bis(diethoxyphosphoryl)-10,20-diphenylporphyrin 1M (M = Cd(II), Ni(II), Pd(II), and Pt(II)) were synthesized and crystallographically characterized. The crystal organization patterns were analyzed using DFT (B97-D3/def2-SVP) calculations of the intermolecular interaction energies between complexes in the crystals. For the systematic analysis of crystal packing, the calculations were extended to previously reported compounds 1M (M = H2, Cu(II), and Zn(II)). Quantitative analysis of the interaction energies shows the essential role of weak intermolecular interactions, such as C-H⋯O, C-H⋯π and M⋯π, in the formation of basic structural motifs and their organization …

010405 organic chemistryIntermolecular forceGeneral Chemistry010402 general chemistryCondensed Matter Physics01 natural sciencesPorphyrin0104 chemical sciencesCrystalMetalchemistry.chemical_compoundCrystallographychemistryPolymorphism (materials science)Intermolecular interactionvisual_artvisual_art.visual_art_medium[CHIM]Chemical SciencesGeneral Materials ScienceComputingMilieux_MISCELLANEOUS
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Synthesis and Self-Organization of Zinc β-(Dialkoxyphosphoryl)porphyrins in the Solid State and in Solution

2012

The first synthesis and self-organization of zinc β-phosphorylporphyrins in the solid state and in solution are reported. β-Dialkoxyphosphoryl-5,10,15,20-tetraphenylporphyrins and their Zn(II) complexes have been synthesized in good yields by using Pd- and Cu-mediated carbon-phosphorous bond-forming reactions. The Cu-mediated reaction allowed to prepare the mono-β-(dialkoxyphosphoryl)porphyrins 1 Zn-3 Zn starting from the β-bromo-substituted zinc porphyrinate ZnTPPBr (TPP = tetraphenylporphyrin) and dialkyl phosphites HP(O)(OR)(2) (R = Et, iPr, nBu). The derivatives 1 Zn-3 Zn were obtained in good yields by using one to three equivalents of CuI. When the reaction was carried out in the pres…

Models MolecularMetalloporphyrinschemistry.chemical_elementZincCrystallography X-Ray010402 general chemistryPhotochemistry01 natural sciencesCatalysisCatalysischemistry.chemical_compoundPolymer chemistryTetraphenylporphyrin[CHIM]Chemical SciencesComputingMilieux_MISCELLANEOUSMolecular Structure010405 organic chemistryOrganic ChemistryGeneral ChemistryNuclear magnetic resonance spectroscopyToluene0104 chemical sciencesSolutionsZincchemistryYield (chemistry)MethanolPalladiumChemistry - A European Journal
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Gallium(III) and Indium(III) Complexes with meso-Monophosphorylated Porphyrins: Synthesis and Structure. A First Example of Dimers Formed by the Self…

2017

International audience; The synthesis and structural characterization, both in solution by means of H-1 and P-31 NMR and UV-vis spectroscopies and in the solid state by X-ray diffraction on single crystal, of a series of gallium(III) and indium(III) meso-mono(diethoxyphosphoryl)porphyrins bearing different peripheral substituents as well as the corresponding monoesters and phosphonic acids are reported. This work describes the first example of the X-ray structure of a self-assembled dimer formed via strong binding between the oxygen atom of the phosphonate substituent and the gallium(III) cations of adjacent porphyrin molecules [Ga-O = 1.9708(13) angstrom].

coordinationchlorideDimerSubstituentchemistry.chemical_elementmalaria pigment[CHIM.INOR]Chemical Sciences/Inorganic chemistry010402 general chemistryPhotochemistry01 natural sciencessupramolecular chemistryInorganic Chemistrychemistry.chemical_compoundoctaethylporphyrinMoleculecleavagePhysical and Theoretical ChemistryGalliumsoluble diamagnetic modelmolecular-structure010405 organic chemistrycrystal-structure[ CHIM.INOR ] Chemical Sciences/Inorganic chemistryPhosphonatePorphyrin0104 chemical sciencesCrystallographychemistryoxidesSingle crystalIndium
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Supramolecular Architectures Based on Phosphonic Acid Diesters

2014

The interest of phosphonic acid dialkyl esters for generation of metal-organic materials is discussed using derivatives of porphyrin and 1,10-phenanthroline series as representative examples.

010405 organic chemistryCoordination polymerOrganic ChemistrySupramolecular chemistry010402 general chemistry01 natural sciencesBiochemistryCombinatorial chemistryPorphyrin0104 chemical sciencesSupramolecular assemblyInorganic Chemistrychemistry.chemical_compoundchemistry[CHIM]Chemical SciencesOrganic chemistryComputingMilieux_MISCELLANEOUSPhosphorus, Sulfur, and Silicon and the Related Elements
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Electrochemical, Spectroelectrochemical, and Structural Studies of Mono- and Diphosphorylated Zinc Porphyrins and Their Self-Assemblies

2019

International audience; Three series of porphyrins containing a Zn(II) central metal ion and zero, one or two phosphoryl groups at the meso-positions of the macrocycle were characterized as to their electrochemical, spectroscopic and structural properties in non-aqueous media. The investigated compounds are represented as 5,15-bis(4'-R-phenyl)porphyrinatozinc, 10-(diethoxyphosphoryl)-5,15-bis(4'-R-phenyl)porphyrinatozinc and 5,15-bis(diethoxyphosphoryl)-10,20-bis(4'-R-phenyl)porphyrinatozinc, where R = OMe, Me, H or CN. Linear-free energy relationships are observed between the measured redox potentials at room temperature and the electronic nature of the substituents at the 5 and 15 meso-ph…

010405 organic chemistryChemistryInorganic chemistrychemistry.chemical_elementZinc010402 general chemistryElectrochemistry01 natural sciences0104 chemical sciencesInorganic ChemistryMetal[CHIM.THEO]Chemical Sciences/Theoretical and/or physical chemistryvisual_artvisual_art.visual_art_medium[CHIM.COOR]Chemical Sciences/Coordination chemistryPhysical and Theoretical Chemistry
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Electrochemical and Spectroelectrochemical Studies of Diphosphorylated Metalloporphyrins. Generation of a Phlorin Anion Product

2015

Two series of diphosphoryl-substituted porphyrins were synthesized and characterized by electrochemistry and spectroelectrochemistry in nonaqueous media containing 0.1 M tetra-n-butylammonium perchlorate (TBAP). The investigated compounds are 5,15-bis(diethoxyphosphoryl)-10,20-diphenylporphyrins (Ph)2(P(O)(OEt)2)2PorM and 5,15-bis(diethoxyphosphoryl)-10,20-di(para-carbomethoxyphenyl)porphyrins (PhCOOMe)2(P(O)(OEt)2)2PorM where M = 2H, Co(II), Ni(II), Cu(II), Zn(II), Cd(II), or Pd(II). The free-base and five metalated porphyrins with nonredox active centers undergo two ring-centered oxidations and two ring-centered reductions, the latter of which is followed by a chemical reaction of the por…

PhotochemistryElectrochemistryMedicinal chemistryPorphyrinChemical reactionIonInorganic ChemistryPerchloratechemistry.chemical_compoundchemistryChemical conversion[CHIM]Chemical SciencesPhysical and Theoretical ChemistryComputingMilieux_MISCELLANEOUS
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Unusual Formation of a Stable 2D Copper Porphyrin Network

2013

Copper(II) 5,15-bis(diethoxyphosphoryl)-10,20-diphenylporphyrin was obtained and characterized by means of cyclic voltammetry, electron paramagnetic resonance, Fourier transform infrared, and UV-visible spectroscopy. Three crystalline forms were grown and studied by means of X-ray diffraction methods (single crystal and powder). The highly electron-withdrawing effect of phosphoryl groups attached directly to the porphyrin macrocycle results in a self-assembling process, with formation of a stable 2D coordination network, which is unusual for copper(II) porphyrins. The resulting 2D structure is a rare example of an assembly based on copper(II) porphyrins where the copper(II) central metal io…

Models MolecularPorphyrinschemistry.chemical_element010402 general chemistryPhotochemistry01 natural scienceslaw.inventionInorganic ChemistryMetalchemistry.chemical_compoundlawMolecule[CHIM]Chemical SciencesPhysical and Theoretical ChemistryPhosphorylationElectron paramagnetic resonanceSpectroscopyComputingMilieux_MISCELLANEOUS010405 organic chemistryElectron Spin Resonance SpectroscopyPorphyrinCopper0104 chemical sciencesCrystallographychemistryvisual_artvisual_art.visual_art_mediumCyclic voltammetrySingle crystalCopper
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Electrochemical and spectroelectrochemical studies of β-phosphorylated Zn porphyrins

2013

The electrochemical and spectroelectrochemical properties of two β-phosphorylated Zn porphyrins, [2-diethoxyphosphoryl-5,10,15,20-tetraphenylporphyrinato]zinc (1) and [2-diisopropoxyphosphoryl-5,10,15,20-tetraphenylporphyrinato]zinc (2), are reported in CH 2 Cl 2 and PhCN containing tetrabutylammonium perchlorate (TBAP) or tetrabutylammonium hexafluorophosphate (TBAPF6) as supporting electrolyte. Under certain solution conditions, three one-electron reductions are observed, with the last process being attributed to the product of a chemical reaction following formation of the porphyrin dianion. Two or three oxidations are observed for the same compounds, again depending upon the solution c…

010405 organic chemistrySupporting electrolyteDimerSubstituentchemistry.chemical_elementGeneral ChemistryZinc010402 general chemistryPhotochemistry01 natural sciencesPorphyrinRedox0104 chemical scienceschemistry.chemical_compoundRadical ionchemistryPolymer chemistryTetrabutylammonium hexafluorophosphate[CHIM]Chemical SciencesComputingMilieux_MISCELLANEOUSJournal of Porphyrins and Phthalocyanines
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Supramolecular Assembly of Organophosphonate Diesters Using Paddle-Wheel Complexes: First Examples in Porphyrin Series

2014

The reactions of dicopper tetrapivalate complex Cu2(μ-OOC-t-Bu)4(NCMe)2 (1) with triphenylphosphine oxide and diethyl phosphite allow paddle-wheel (PW) copper(II) complexes with phosphorus-containing axial ligands (2, 3) to be obtained. When meso-bis(diethoxyphosphoryl)porphyrins 4M were employed in this ligand exchange reaction, a series of one-dimensional (1D) homo- and heterometallic coordination polymers 5M composed of PW subunits and organophosphonate diesters were prepared and characterized by means of single crystal X-ray analysis. Planar porphyrinate 4Pd and nonplanar metalloporphyrinates 4Cu and 4Ni proved to be appropriate molecular structural blocks for assembly of coordination p…

010405 organic chemistryStereochemistryChemistryLigandchemistry.chemical_elementGeneral Chemistry010402 general chemistryCondensed Matter Physics01 natural sciencesPorphyrin0104 chemical sciencesSupramolecular assemblychemistry.chemical_compoundNickelPaddle wheelPolymer chemistry[CHIM]Chemical SciencesMoietyGeneral Materials ScienceComputingMilieux_MISCELLANEOUSTriphenylphosphine oxidePalladiumCrystal Growth & Design
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CCDC 902786: Experimental Crystal Structure Determination

2013

Related Article: Anna A. Sinelshchikova, Sergey E. Nefedov, Yulia Yu. Enakieva, Yulia G. Gorbunova, Aslan Yu. Tsivadze, Karl M. Kadish, Ping Chen, Alla Bessmertnykh-Lemeune, Christine Stern, and Roger Guilard|2013|Inorg.Chem.|52|999|doi:10.1021/ic302257g

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(Tetraethyl (1020-diphenylporphyrin-515-diyl)bis(phosphonate))-copper(ii)Experimental 3D Coordinates
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CCDC 1017124: Experimental Crystal Structure Determination

2015

Related Article: Marina A. Uvarova, Anna A. Sinelshchikova, Margarita A. Golubnichaya, Sergey E. Nefedov, Yulia Yu. Enakieva, Yulia G. Gorbunova, Aslan Yu. Tsivadze, Christine Stern, Alla Bessmertnykh-Lemeune, Roger Guilard|2014|Cryst.Growth Des.|14|5976|doi:10.1021/cg501157e

tetrakis(mu2-Pivalato-OO')-bis(acetonitrile)-di-copper(ii) benzene solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1519796: Experimental Crystal Structure Determination

2017

Related Article: Yulia Yu. Enakieva, Marina V. Volostnykh, Sergey E. Nefedov, Gayane A. Kirakosyan, Yulia G. Gorbunova, Aslan Yu. Tsivadze, Alla G. Bessmertnykh-Lemeune, Christine Stern, Roger Guilard|2017|Inorg.Chem.|56|3055|doi:10.1021/acs.inorgchem.6b03160

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterschloro-(diethyl (1020-bis(4-methylphenyl)porphyrin-5-yl)phosphonate)-indiumExperimental 3D Coordinates
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CCDC 1871295: Experimental Crystal Structure Determination

2019

Related Article: Inna A. Abdulaeva, Kirill P. Birin, Anna A. Sinelshchikova, Mikhail S. Grigoriev, Konstantin A. Lyssenko, Yulia G. Gorbunova, Aslan Yu. Tsivadze, Alla Bessmertnykh-Lemeune|2019|CrystEngComm|21|1488|doi:10.1039/C8CE01992D

Space GroupCrystallographycatena-[(5101520-Tetramesityl-2-(4-pyridyl)-1H-imidazo[45-b]porphyrinato)-zinc(ii) toluene solvate]Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 902785: Experimental Crystal Structure Determination

2013

Related Article: Anna A. Sinelshchikova, Sergey E. Nefedov, Yulia Yu. Enakieva, Yulia G. Gorbunova, Aslan Yu. Tsivadze, Karl M. Kadish, Ping Chen, Alla Bessmertnykh-Lemeune, Christine Stern, and Roger Guilard|2013|Inorg.Chem.|52|999|doi:10.1021/ic302257g

(Tetraethyl (1020-diphenylporphyrin-515-diyl)bis(phosphonato))-copper(ii)Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1844989: Experimental Crystal Structure Determination

2019

Related Article: Sergey E. Nefedov, Kirill P. Birin, Alla Bessmertnykh-Lemeune, Yulia Y. Enakieva, Anna A. Sinelshchikova, Yulia G. Gorbunova, Aslan Y. Tsivadze, Christine Stern, Yuanyuan Fang, Karl M. Kadish|2019|Dalton Trans.|48|5372|doi:10.1039/C9DT00706G

Space GroupCrystallographyCrystal SystemCrystal Structurecatena-[(mu-10-(diethoxyphosphoryl)-515-diphenylporphyrin-2123-diyl)-zinc(ii)]Cell ParametersExperimental 3D Coordinates
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CCDC 1904438: Experimental Crystal Structure Determination

2019

Related Article: Marina V. Volostnykh, Sergey M. Borisov, Mikhail A. Konovalov, Anna A. Sinelshchikova, Yulia G. Gorbunova, Aslan Yu. Tsivadze, Michel Meyer, Christine Stern, Alla Bessmertnykh-Lemeune|2019|Dalton Trans.|48|8882|doi:10.1039/C9DT01577A

Space GroupCrystallographyCrystal SystemCrystal Structure(10-(Diethoxyphosphoryl)-515-bis(4-methylphenyl)porphyrinato)-palladium(ii) dichloromethane solvateCell ParametersExperimental 3D Coordinates
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CCDC 1017131: Experimental Crystal Structure Determination

2015

Related Article: Marina A. Uvarova, Anna A. Sinelshchikova, Margarita A. Golubnichaya, Sergey E. Nefedov, Yulia Yu. Enakieva, Yulia G. Gorbunova, Aslan Yu. Tsivadze, Christine Stern, Alla Bessmertnykh-Lemeune, Roger Guilard|2014|Cryst.Growth Des.|14|5976|doi:10.1021/cg501157e

Space GroupCrystallographyCrystal Systemcatena-[(mu3-tetraethyl (1020-diphenylporphyrin-2123diyl-515-diyl)bis(phosphonate))-tetrakis(mu2-pivalato)-di-copper-nickel chloroform solvate]Crystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1844993: Experimental Crystal Structure Determination

2019

Related Article: Sergey E. Nefedov, Kirill P. Birin, Alla Bessmertnykh-Lemeune, Yulia Y. Enakieva, Anna A. Sinelshchikova, Yulia G. Gorbunova, Aslan Y. Tsivadze, Christine Stern, Yuanyuan Fang, Karl M. Kadish|2019|Dalton Trans.|48|5372|doi:10.1039/C9DT00706G

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinatestetrakis(mu-10-(diethoxyphosphoryl)-515-bis(4-methoxyphenyl)porphyrin-2123-diyl)-tetra-zinc(ii)
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CCDC 1017125: Experimental Crystal Structure Determination

2015

Related Article: Marina A. Uvarova, Anna A. Sinelshchikova, Margarita A. Golubnichaya, Sergey E. Nefedov, Yulia Yu. Enakieva, Yulia G. Gorbunova, Aslan Yu. Tsivadze, Christine Stern, Alla Bessmertnykh-Lemeune, Roger Guilard|2014|Cryst.Growth Des.|14|5976|doi:10.1021/cg501157e

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterstetrakis(mu2-Pivalato-OO')-bis(acetonitrile)-di-copper(ii) chloroform solvateExperimental 3D Coordinates
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CCDC 998788: Experimental Crystal Structure Determination

2014

Related Article: Roman I. Zubatyuk, Anna A. Sinelshchikova, Yulia Y. Enakieva, Yulia G. Gorbunova, Aslan Y. Tsivadze, Sergey E. Nefedov, Alla Bessmertnykh-Lemeune, Roger Guilard, Oleg V. Shishkin|2014|CrystEngComm|16|10428|doi:10.1039/C4CE01623H

Space GroupCrystallography(tetraethyl (1020-diphenylporphyrin-515-diyl)bis(phosphonatato))-nickel(ii) hexane solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1519795: Experimental Crystal Structure Determination

2017

Related Article: Yulia Yu. Enakieva, Marina V. Volostnykh, Sergey E. Nefedov, Gayane A. Kirakosyan, Yulia G. Gorbunova, Aslan Yu. Tsivadze, Alla G. Bessmertnykh-Lemeune, Christine Stern, Roger Guilard|2017|Inorg.Chem.|56|3055|doi:10.1021/acs.inorgchem.6b03160

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbromo-(515-di-p-tolylporphyrinato)-galliumExperimental 3D Coordinates
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CCDC 1890813: Experimental Crystal Structure Determination

2019

Related Article: Yuanyuan Fang, Xiaoqin Jiang, Karl M. Kadish, Sergey E. Nefedov, Gayane A. Kirakosyan, Yulia Y. Enakieva, Yulia G. Gorbunova, Aslan Y. Tsivadze, Christine Stern, Alla Bessmertnykh-Lemeune, Roger Guilard|2019|Inorg.Chem.|58|4665|doi:10.1021/acs.inorgchem.9b00268

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-((mu-tetraethyl [1020-bis(4-cyanophenyl)porphyrin-515-diyl]bis(phosphonate))-zinc(ii) chloroform solvate)Experimental 3D Coordinates
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CCDC 1017126: Experimental Crystal Structure Determination

2015

Related Article: Marina A. Uvarova, Anna A. Sinelshchikova, Margarita A. Golubnichaya, Sergey E. Nefedov, Yulia Yu. Enakieva, Yulia G. Gorbunova, Aslan Yu. Tsivadze, Christine Stern, Alla Bessmertnykh-Lemeune, Roger Guilard|2014|Cryst.Growth Des.|14|5976|doi:10.1021/cg501157e

Space GroupCrystallographytetrakis(mu2-Pivalato-OO')-bis(triphenylphosphine oxide)-di-copper(ii) dichloromethane solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1893716: Experimental Crystal Structure Determination

2019

Related Article: Elizaveta V. Ermakova, Yulia Y. Enakieva, Sergey E. Nefedov, Vladimir V. Arslanov, Yulia G. Gorbunova, Aslan Y. Tsivadze, Christine Stern, Alla Lemeune|2019|Eur.J.Org.Chem.|2019|3146|doi:10.1002/ejoc.201900448

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-((mu-diethyl [15-(morpholin-4-yl)-1020-diphenylporphyrin-5-yl]phosphonate)-zinc)Experimental 3D Coordinates
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CCDC 1017127: Experimental Crystal Structure Determination

2015

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