6533b834fe1ef96bd129e2bb
RESEARCH PRODUCT
Synthesis of porphyrin-bis(polyazamacrocycle) triads via Suzuki coupling reaction
Yulia G. GorbunovaSankar MuniappanAlla Bessmertnykh-lemeuneElena R. RanyukKirill P. BirinKiril P. BirinChristine SternJulien MichalakYulia Yu. EnakievaYulia Yu. EnakievaRoger Guilardsubject
chemistry.chemical_compoundSuzuki reactionChemistryStereochemistry[CHIM]Chemical SciencesMoleculeGeneral ChemistryDABCOLinkerCombinatorial chemistryPorphyrinComputingMilieux_MISCELLANEOUSdescription
Suzuki–Miyaura cross-coupling reaction has been used for the synthesis of tricyclic architectures based on trans-A2B2-porphyrins and bisaminal-protected polyazamacrocycles which are linked directly or by a p-phenylene spacer. This modular approach allowed the synthesis of ligands with various substituted porphyrin macrocycles and bisaminal-protected tetraazamacrocycles possessing different cavity sizes. These molecules can be assembled into dimers using a DABCO linker. Deprotection of these compounds afforded porphyrin-bis(polyazamacrocycle) triads.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2014-03-12 | Journal of Porphyrins and Phthalocyanines |