Glassy PEEK‐WC vs Rubbery Pebax®1657 Polymers: Effect on the Gas Transport in CuNi‐MOF Based Mixed Matrix Membranes

Mixed matrix membranes (MMMs) are seen as promising candidates to overcome the fundamental limit of polymeric membranes, known as the so-called Robeson upper bound, which defines the best compromise between permeability and selectivity of neat polymeric membranes. To overcome this limit, the permeability of the filler particles in the MMM must be carefully matched with that of the polymer matrix. The present work shows that it is not sufficient to match only the permeability of the polymer and the dispersed phase, but that one should consider also the individual contributions of the diffusivity and the solubility of the gas in both components. Here we compare the gas transport performance o…

Cytosine Nucleobase Ligand: A Suitable Choice for Modulating Magnetic Anisotropy in Tetrahedrally Coordinated Mononuclear CoII Compounds

A family of tetrahedral mononuclear CoII complexes with the cytosine nucleobase ligand is used as the playground for an in-depth study of the effects that the nature of the ligand, as well as their noninnocent distortions on the Co(II) environment, may have on the slow magnetic relaxation effects. Hence, those compounds with greater distortion from the ideal tetrahedral geometry showed a larger-magnitude axial magnetic anisotropy (D) together with a high rhombicity factor (E/D), and thus, slow magnetic relaxation effects also appear. In turn, the more symmetric compound possesses a much smaller value of the D parameter and, consequently, lacks single-ion magnet behavior.

Efficient Gas Separation and Transport Mechanism in Rare Hemilabile Metal–Organic Framework

Understanding/visualizing the established interactions between gases and adsorbents is mandatory to implement better performance materials in adsorption/separation processes. Here we report the unique behavior of a rare example of a hemilabile chiral three-dimensional metal–organic framework (MOF) with an unprecedented qtz-e-type topology, with formula CuII2(S,S)-hismox·5H2O (1) (hismox = bis[(S)-histidine]oxalyl diamide). 1 exhibits a continuous and reversible breathing behavior, based on the hemilability of carboxylate groups from l-histidine. In situ powder (PXRD) and single crystal X-ray diffraction (SCXRD) using synchrotron radiation allowed us to unveil the crystal structures of four …

Multivariate Metal-Organic Framework/Single-Walled Carbon Nanotube Buckypaper for Selective Lead Decontamination.

The search for efficient technologies empowering the selective capture of environmentally harmful heavy metals from wastewater treatment plants, at affordable prices, attracts wide interest but constitutes an important technological challenge. We report here an eco-friendly single-walled carbon nanotube buckypaper (SWCNT-BP) enriched with a multivariate amino acid-based metal-organic framework (MTV-MOF) for the efficient and selective removal of Pb

Synthesis and Enhanced Capture Properties of a New BioMOF@SWCNT‐BP: Recovery of the Endangered Rare‐Earth Elements from Aqueous Systems (Adv. Mater. Interfaces 16/2021)

Multivariate Metal-Organic Frameworks for the Simultaneous Capture of Organic and Inorganic Contaminants from Water

We report a new water-stable multivariate (MTV) Metal-Organic Framework (MOF) prepared by combining two different oxamide-based metalloligands derived from the natural amino acids L-serine and L-methionine. This unique material features hexagonal channels decorated with two types of flexible and functional 'arms' (-CH2OH and -CH2CH2SCH3) capable to act, synergistically, for the simultaneous and efficient removal of both inorganic (heavy metals like Hg2+, Pb2+ and Tl+) and organic (dyes such as Pyronin Y, Auramine O, Brilliant Green and Methylene Blue) contaminants and, in addition, this MTV-MOF is completely reusable. Single-crystal X-ray diffraction (SCXRD) measurements allowed to solve th…

Magneto-structural correlations in Ni(ii) [2 × 2] metallogrids featuring a variable number of μ-aquo or μ-hydroxo extra bridges

Four new [2 × 2] grid-type metallosupramolecular species have been obtained by using the ditopic 3,6-bis(2′-pyridyl)pyridazine ligand (dppn) and nickel(II) salts containing poorly coordinating anions. Three of them have the formula [Ni4(μ-dppn)4(μ-OH)2(μ-H2O)2]X6·nH2O [with X = ClO4− (1), NO3− (2) and CF3SO3− (3), and n = 6.5 (1), 14 (2) and 4 (3)]. Their crystal structure shows the same tetranuclear core, constituted by four six-coordinate metal ions and four dppn molecules. Two hydroxo groups and two water molecules efficiently interact forming two hydrated hydroxide (H3O2−) supramolecular bridging anions, further stabilizing the grid. The other compound, [Ni4(μ-dppn)4(μ-OH)3(μ-H2O)](ClO4…

From Mononuclear Compounds to [2 × 2] Metallogrids: Ferromagnetically Coupled Systems Built by Nickel(II) and 3,6-Bis(2′-pyridyl)pyridazine (dppn)

Mono-, di-, tri-, and tetranuclear compounds of nickel(II) of formula [Ni(dppn)3](NCS)2·0.5dppn (1), [{Ni(dppn)(NCS)}2(μ-dppn)(μ-NCS)]NCS (2), [Ni3(dppn)2(N3)2(μ-dppn)2(μ-N3)2](ClO4)2·CH3CH2OH·2H2O...

Gas Transport in Mixed Matrix Membranes: Two Methods for Time Lag Determination

The most widely used method to measure the transport properties of dense polymeric membranes is the time lag method in a constant volume/pressure increase instrument. Although simple and quick, this method provides only relatively superficial, averaged data of the permeability, diffusivity, and solubility of gas or vapor species in the membrane. The present manuscript discusses a more sophisticated computational method to determine the transport properties on the basis of a fit of the entire permeation curve, including the transient period. The traditional tangent method and the fitting procedure were compared for the transport of six light gases (H2, He, O2, N2, CH4, and CO2) and ethane an…

Supramolecular arrangements of novel clickable 4-substituted 3,6-bis(2′-pyridyl)pyridazine molecules

Abstract The clickable reaction between the starting 3,6-bis(2′-pyridyl)-1,2,4,5-tetrazine (bptz) with a series of terminal alkynes-containing functional biomolecules [prop-2-yn-1-ol, 4-(prop-2′-yn-1′-yl)morpholine and D-galactose] by means of an inverse electron demand Diels-Alder pathway has been studied and four new 4-substituted 3,6-bis(2′-pyridyl)pyridazine derivatives (4-Rdppn) were isolated, namely 4-(hydroxymethyl)-3,6-di(pyridin-2-yl)pyridazine (1), 4-((prop-2-yn-1-yloxy)methyl)-3,6-di(pyridin-2-yl)pyridazine (2) obtained by post-etherification reaction of 1, 4-(morpholinemethyl)-(3,6-dipyridin-2-yl)pyridazine monohydrate (3) and 3,6-di(pyridin-2-yl)-4-((2,2,7,7-tetramethyltetrahyd…

Reverse osmosis and nanofiltration membranes for highly efficient PFASs removal: overview, challenges and future perspectives

Today, it is extremely urgent to face the increasing shortage of clean and safe water resources, determined by the exponential growth of both world population and its consumerism, climate change and pollution. Water remediation from traditional chemicals and contaminants of emerging concerns (CECs) is supposed to be among the major methods to solve water scarcity issues. Reverse osmosis (RO) and nanofiltration (NF) membrane separation technologies have proven to be feasible, sustainable and highly effective methods for the removal of contaminants, comprising the extremely persistent and recalcitrant perfluoroalkyl substances (PFASs), which failed to be treated through the traditional water …

Highly Efficient Removal of Neonicotinoid Insecticides by Thioether-Based (Multivariate) Metal–Organic Frameworks

Circumventing the impact of agrochemicals on aquatic environments has become a necessity for health and ecological reasons. Herein, we report the use of a family of five eco-friendly water-stable isoreticular metal-organic frameworks (MOFs), prepared from amino acids, as adsorbents for the removal of neonicotinoid insecticides (thiamethoxam, clothianidin, imidacloprid, acetamiprid, and thiacloprid) from water. Among them, the three MOFs containing thioether-based residues show remarkable removal efficiency. In particular, the novel multivariate MOF {SrIICuII6[(S,S)-methox]1.5[(S,S)-Mecysmox]1.50(OH)2(H2O)}·36H2O (5), featuring narrow functional channels decorated with both -CH2SCH3 and -CH2…

A Metalloligand Approach for the Self-Assembly of a Magnetic Two-Dimensional Grid-of-Grids

The efficient organization of discrete functional molecules into extended frameworks, while retaining their physical properties, is a mandatory requisite to move toward applications. Here we descri...

Efficient Capture of Organic Dyes and Crystallographic Snapshots by a Highly Crystalline Amino-Acid-Derived Metal-Organic Framework

The presence of residual organic dyes in water resources or wastewater treatment systems, derived mainly from effluents of different industries, is a major environmental problem with no easy solution. Herein, an ecofriendly, water-stable metal-organic framework was prepared from a derivative of the natural amino acid l-serine. Its functional channels are densely decorated with highly flexible l-serine residues bearing hydroxyl groups. The presence of such a flexible and functional environment within the confined environment of the MOF leads to efficient removal of different organic dyes from water: Pyronin Y, Auramine O, Methylene Blue and Brilliant Green, as unveiled by unprecedented snaps…

Synthesis of a rod-based porous coordination polymer from a nucleotide as a sequential chiral inductor

We report the two-step synthesis of a novel chiral rod-based porous coordination polymer (PCP). The chemical approach consists of the use of a previously prepared bis(ethylenediamine) copper monomer [Cu(en)]2(NO3)2 [where en = ethylenediamine] reacting with the cytidine 5′-monophosphate (CMP) nucleotide. The bis(ethylenediamine) copper compound—stabilized by axial coordination of nitrate counter-anions—reacts in the presence of sodium salt of CMP to yield right-handed copper(II) chains of P helicity with formula [Cu2(en)2(CMP)2]·5H2O (1). The axial coordination of the CMP2- ligands through the N3 and O2 sites (free nitrogen and carbonyl groups) of the cytosine nucleobase and oxygen atoms of…

Highly efficient temperature-dependent chiral separation with a nucleotide-based coordination polymer.

We report a new chiral coordination polymer, prepared from the cytidine 5′-monophosphate (CMP) nucleotide, capable of separating efficiently (enantiomeric excess of ca. 100%) racemic mixtures of L- and D-Asp in a temperature-dependent manner. The crystal structure of the host–guest adsorbate, with the D-Asp guest molecules loaded within its channels, could be solved allowing a direct visualization of the chiral recognition process.

Metal–organic framework technologies for water remediation: towards a sustainable ecosystem

Having access to clean water is a mandatory requirement for the proper development of living beings. So, addressing the removal of contaminants from aquatic systems should be a priority research topic in order to restore ecosystem balance and secure a more sustainable future. The fascinating structures and striking physical properties of metal–organic frameworks (MOFs) have revealed them as excellent platforms for the removal of harmful species from water. In this review, we have focused our attention on critically highlighting the latest developments achieved in the adsorptive removal of inorganic – metal cations, inorganic acids, oxyanions/cations, nuclear wastes and other inorganic anion…

Bioinspired Metal-Organic Frameworks in Mixed Matrix Membranes for Efficient Static/Dynamic Removal of Mercury from Water

The mercury removal efficiency of a novel metal-organic framework (MOF) derived from the amino acid S-methyl-L-cysteine is presented and the process is characterized by single-crystal X-ray crystallography. A feasibility study is further presented on the performance of this MOF and also that of another MOF derived from the amino acid L-methionine when used as the sorbent in mixed matrix membranes (MMMs). These MOF-based MMMs exhibit high efficiency and selectivity in both static and dynamic regimes in the removal of Hg2+ from aqueous environments, due to the high density of thioalkyl groups decorating MOF channels. Both MMMs are capable to reduce different concentration of the pollutant to …

A Biocompatible Aspartic-Decorated Metal–Organic Framework with Tubular Motif Degradable under Physiological Conditions

Achieving a precise control of the final structure of metal–organic frameworks (MOFs) is necessary to obtain desired physical properties. Here, we describe how the use of a metalloligand design strategy and a judicious choice of ligands inspired from nature is a versatile approach to succeed in this challenging task. We report a new porous chiral MOF, with the formula Ca5II{CuII10[(S,S)-aspartamox]5}·160H2O (1), constructed from Cu2+ and Ca2+ ions and aspartic acid-decorated ligands, where biometal Cu2+ ions are bridged by the carboxylate groups of aspartic acid moieties. The structure of MOF 1 reveals an infinite network of basket-like cages, built by 10 crystallographically distinct Cu(II…

Postsynthetic Approach for the Rational Design of Chiral Ferroelectric Metal–Organic Frameworks

International audience; Ferroelectrics (FEs) are materials of paramount importance with a wide diversity of applications. Herein, we propose a postsynthetic methodology for the smart implementation of ferroelectricity in chiral metal−organic frameworks (MOFs): following a single-crystal to single-crystal cation metathesis, the Ca2+ counterions of a preformed chiral MOF of formula Ca6II{CuII24[(S,S)-hismox]12(OH2)3}·212H2O (1), where hismox is a chiral ligand derived from the natural amino acid l-histidine, are replaced by CH3NH3+. The resulting compound, (CH3NH3)12{CuII24[(S,S)-hismox]12(OH2)3}·178H2O (2), retains the polar space group of 1 and is ferroelectric below 260 K. These results op…

Front Cover: Efficient Capture of Organic Dyes and Crystallographic Snapshots by a Highly Crystalline Amino-Acid-Derived Metal-Organic Framework (Chem. Eur. J. 67/2018)

Synthesis and Enhanced Capture Properties of a New BioMOF@SWCNT‐BP: Recovery of the Endangered Rare‐Earth Elements from Aqueous Systems

Photodegradation of Brilliant Green Dye by a Zinc bioMOF and Crystallographic Visualization of Resulting CO2

We present a novel bio-friendly water-stable Zn-based MOF (1), derived from the natural amino acid L-serine, which was able to efficiently photodegrade water solutions of brilliant green dye in only 120 min. The total degradation was followed by UV-Vis spectroscopy and further confirmed by single-crystal X-ray crystallography, revealing the presence of CO2 within its channels. Reusability studies further demonstrate the structural and performance robustness of 1.

Metal–Organic Frameworks as Playgrounds for Reticulate Single-Molecule Magnets

Achieving an accurate control on the final structure of Metal-Organic Frameworks (MOFs) is mandatory to obtain target physical properties. Here we describe how the combination of a metalloligand design strategy and a post-synthetic method is a versatile and powerful approach to success on this extremely difficult task. In a first stage, a novel oxamato-based tetranuclear cobalt(III) complex with a tetrahedron-shape geometry is used, for the first time, as metalloligand toward cal-cium(II) cations to lead a diamagnetic Ca(II)-Co(III) three-dimensional (3D) MOF (1). In a second stage, in a single-crystal to single-crystal manner the calcium(II) ions are replaced by terbium (III), dysprosium(I…

Lanthanide Discrimination with Hydroxyl-Decorated Flexible Metal–Organic Frameworks

We report two new highly crystalline metal-organic frameworks (MOFs), derived from the natural amino acids serine (1) and threonine (2), featuring hexagonal channels densely decorated with hydroxyl groups belonging to the amino acid residues. Both 1 and 2 are capable of discriminating, via solid-phase extraction, a mixture of selected chloride salts of lanthanides on the basis of their size, chemical affinity, and/or the flexibility of the network. In addition, this discrimination follows a completely different trend for 1 and 2 because of the different locations of the hydroxyl groups in each compound, which is evocative of steric complementarity between the substrate and receptor. Last bu…

Crystallographic snapshots of host–guest interactions in drugs@metal–organic frameworks: towards mimicking molecular recognition processes

We report a novel metal–organic framework (MOF) featuring functional pores decorated with hydroxyl groups derived from the natural amino acid L-serine, which is able to establish specific interactions of different natures, strengths and directionalities with organic molecules of technological interest, i.e. ascorbic acid, pyridoxine, bupropion and 17-β-estradiol, based on their different sizes and chemical natures. The ability of 1 to distinctly organize guest molecules within its channels, through the concomitant effect of different directing supramolecular host–guest interactions, enables gaining unique insights, by means of single-crystal X-ray crystallography, into the host–guest intera…

Metal-Organic Frameworks as Unique Platforms to Gain Insight of σ-Hole Interactions for the Removal of Organic Dyes from Aquatic Ecosystems.

The combination of high crystallinity and rich host-guest chemistry in metal-organic frameworks (MOFs), have situated them in an advantageous position, with respect to traditional porous materials, to gain insight on specific weak noncovalent supramolecular interactions. In particular, sulfur σ-hole interactions are known to play a key role in the biological activity of living beings as well as on relevant molecular recognitions processes. However, so far, they have been barely explored. Here, we describe both how the combination of the intrinsic features of MOFs, especially the possibility of using single-crystal X-ray crystallography (SCXRD), can be an extremely valuable tool to gain insi…

Hydrolase–like catalysis and structural resolution of natural products by a metal–organic framework

[EN] The exact chemical structure of non-crystallising natural products is still one of the main challenges in Natural Sciences. Despite tremendous advances in total synthesis, the absolute structural determination of a myriad of natural products with very sensitive chemical functionalities remains undone. Here, we show that a metal-organic framework (MOF) with alcohol-containing arms and adsorbed water, enables selective hydrolysis of glycosyl bonds, supramolecular order with the so-formed chiral fragments and absolute determination of the organic structure by single-crystal X-ray crystallography in a single operation. This combined strategy based on a biomimetic, cheap, robust and multigr…

CCDC 1891588: Experimental Crystal Structure Determination

Related Article: Marta Mon, Rosaria Bruno, Estefanía Tiburcio, Aida Grau-Atienza, Antonio Sepúlveda-Escribano, Enrique V. Ramos-Fernandez, Alessio Fuoco, Elisa Esposito, Marcello Monteleone, Johannes C. Jansen, Joan Cano, Jesús Ferrando-Soria, Donatella Armentano, Emilio Pardo|2019|Chem.Mater.|31|5856|doi:10.1021/acs.chemmater.9b01995

CCDC 1823995: Experimental Crystal Structure Determination

Related Article: Marta Mon, Rosaria Bruno, Jesús Ferrando-Soria, Lucia Bartella, Leonardo Di Donna, Marianna Talia, Rosamaria Lappano, Marcello Maggiolini, Donatella Armentano, Emilio Pardo|2018|Materials Horizons|5|683|doi:10.1039/C8MH00302E

CCDC 2072809: Experimental Crystal Structure Determination

Related Article: Cristina Negro, Héctor Martinez Pérez-Cejuela, Ernesto Francisco Ph.D. Simo-Alfonso, Jose Manuel Herrero-Martinez, Rosaria Bruno, Donatella Armentano, Jesus Ferrando-Soria, Emilio Pardo|2021|ACS Applied Materials and Interfaces|13|28424|doi:10.1021/acsami.1c08833

CCDC 1938637: Experimental Crystal Structure Determination

Related Article: Lucas H. G. Kalinke, Danielle Cangussu, Marta Mon, Rosaria Bruno, Estefania Tiburcio, Francesc Lloret, Donatella Armentano, Emilio Pardo, Jesus Ferrando-Soria|2019|Inorg.Chem.|58|14498|doi:10.1021/acs.inorgchem.9b02086

CCDC 1938635: Experimental Crystal Structure Determination

Related Article: Lucas H. G. Kalinke, Danielle Cangussu, Marta Mon, Rosaria Bruno, Estefania Tiburcio, Francesc Lloret, Donatella Armentano, Emilio Pardo, Jesus Ferrando-Soria|2019|Inorg.Chem.|58|14498|doi:10.1021/acs.inorgchem.9b02086

CCDC 2128259: Experimental Crystal Structure Determination

Related Article: Mariafrancesca Baratta, Teresa Fina Mastropietro, Rosaria Bruno, Antonio Tursi, Cristina Negro, Jesús Ferrando-Soria, Alexander I. Mashin, Aleksey Nezhdanov, Fiore P. Nicoletta, Giovanni De Filpo, Emilio Pardo, Donatella Armentano|2022|ACS Appl. Nano Mater.|5|5223|doi:10.1021/acsanm.2c00280

CCDC 2007971: Experimental Crystal Structure Determination

Related Article: Rosaria Bruno, Marta Mon, Paula Escamilla, Jesus Ferrando‐Soria, Elisa Esposito, Alessio Fuoco, Marcello Monteleone, Johannes C. Jansen, Rosangela Elliani, Antonio Tagarelli, Donatella Armentano, Emilio Pardo|2021|Adv.Funct.Mater.|31|2008499|doi:10.1002/adfm.202008499

CCDC 1826456: Experimental Crystal Structure Determination

Related Article: Marta Mon, Rosaria Bruno, Rosangela Elliani, Antonio Tagarelli, Xiaoni Qu, Sanping Chen, Jesús Ferrando-Soria, Donatella Armentano, Emilio Pardo|2018|Inorg.Chem.|57|13895|doi:10.1021/acs.inorgchem.8b02409

CCDC 1826450: Experimental Crystal Structure Determination

Related Article: Marta Mon, Rosaria Bruno, Rosangela Elliani, Antonio Tagarelli, Xiaoni Qu, Sanping Chen, Jesús Ferrando-Soria, Donatella Armentano, Emilio Pardo|2018|Inorg.Chem.|57|13895|doi:10.1021/acs.inorgchem.8b02409

CCDC 1826452: Experimental Crystal Structure Determination

Related Article: Marta Mon, Rosaria Bruno, Rosangela Elliani, Antonio Tagarelli, Xiaoni Qu, Sanping Chen, Jesús Ferrando-Soria, Donatella Armentano, Emilio Pardo|2018|Inorg.Chem.|57|13895|doi:10.1021/acs.inorgchem.8b02409

CCDC 1843114: Experimental Crystal Structure Determination

Related Article: Marta Mon, Rosaria Bruno, Estefanía Tiburcio, Pierre‐Edouard Casteran, Jesús Ferrando‐Soria, Donatella Armentano, Emilio Pardo|2018|Chem.-Eur.J.|24|17712|doi:10.1002/chem.201803547

CCDC 1938638: Experimental Crystal Structure Determination

Related Article: Lucas H. G. Kalinke, Danielle Cangussu, Marta Mon, Rosaria Bruno, Estefania Tiburcio, Francesc Lloret, Donatella Armentano, Emilio Pardo, Jesus Ferrando-Soria|2019|Inorg.Chem.|58|14498|doi:10.1021/acs.inorgchem.9b02086

CCDC 1891577: Experimental Crystal Structure Determination

Related Article: Marta Mon, Rosaria Bruno, Estefanía Tiburcio, Aida Grau-Atienza, Antonio Sepúlveda-Escribano, Enrique V. Ramos-Fernandez, Alessio Fuoco, Elisa Esposito, Marcello Monteleone, Johannes C. Jansen, Joan Cano, Jesús Ferrando-Soria, Donatella Armentano, Emilio Pardo|2019|Chem.Mater.|31|5856|doi:10.1021/acs.chemmater.9b01995

CCDC 1843112: Experimental Crystal Structure Determination

Related Article: Marta Mon, Rosaria Bruno, Estefanía Tiburcio, Pierre‐Edouard Casteran, Jesús Ferrando‐Soria, Donatella Armentano, Emilio Pardo|2018|Chem.-Eur.J.|24|17712|doi:10.1002/chem.201803547

CCDC 2072807: Experimental Crystal Structure Determination

Related Article: Cristina Negro, Héctor Martinez Pérez-Cejuela, Ernesto Francisco Ph.D. Simo-Alfonso, Jose Manuel Herrero-Martinez, Rosaria Bruno, Donatella Armentano, Jesus Ferrando-Soria, Emilio Pardo|2021|ACS Applied Materials and Interfaces|13|28424|doi:10.1021/acsami.1c08833

CCDC 1874222: Experimental Crystal Structure Determination

Related Article: Nadia Marino, Rosaria Bruno, Abdeslem Bentama, Alejandro Pascual-Álvarez, Francesc Lloret, Miguel Julve, Giovanni De Munno|2019|CrystEngComm|21|917|doi:10.1039/C8CE01894D

CCDC 1826453: Experimental Crystal Structure Determination

Related Article: Marta Mon, Rosaria Bruno, Rosangela Elliani, Antonio Tagarelli, Xiaoni Qu, Sanping Chen, Jesús Ferrando-Soria, Donatella Armentano, Emilio Pardo|2018|Inorg.Chem.|57|13895|doi:10.1021/acs.inorgchem.8b02409

CCDC 1541852: Experimental Crystal Structure Determination

Related Article: Marta Mon, Jesús Ferrando-Soria, Michel Verdaguer, Cyrille Train, Charles Paillard, Brahim Dkhil, Carlo Versace, Rosaria Bruno, Donatella Armentano, Emilio Pardo|2017|J.Am.Chem.Soc.|139|8098|doi:10.1021/jacs.7b03633

CCDC 1891583: Experimental Crystal Structure Determination

Related Article: Marta Mon, Rosaria Bruno, Estefanía Tiburcio, Aida Grau-Atienza, Antonio Sepúlveda-Escribano, Enrique V. Ramos-Fernandez, Alessio Fuoco, Elisa Esposito, Marcello Monteleone, Johannes C. Jansen, Joan Cano, Jesús Ferrando-Soria, Donatella Armentano, Emilio Pardo|2019|Chem.Mater.|31|5856|doi:10.1021/acs.chemmater.9b01995

CCDC 2051219: Experimental Crystal Structure Determination

Related Article: Rosaria Bruno, Teresa F. Mastropietro, Giovanni De Munno, Emilio Pardo, Donatella Armentano|2021|J.Coord.Chem.||1|doi:10.1080/00958972.2021.1872785

CCDC 1474778: Experimental Crystal Structure Determination

Related Article: Rosaria Bruno, Julia Vallejo, Nadia Marino, Giovanni De Munno, J. Krzystek, Joan Cano, Emilio Pardo, and Donatella Armentano|2017|Inorg.Chem.|56|1857|doi:10.1021/acs.inorgchem.6b02448

CCDC 2062290: Experimental Crystal Structure Determination

Related Article: Paula Escamilla, Marta Viciano-Chumillas, Rosaria Bruno, Donatella Armentano, Emilio Pardo, Jesús Ferrando-Soria|2021|Molecules|26|4098|doi:10.3390/molecules26134098

CCDC 2132444: Experimental Crystal Structure Determination

Related Article: Cristina Negro, Paula Escamilla, Rosaria Bruno, Jesus Ferrando-Soria, Donatella Armentano, Emilio Pardo|2022|Chem.-Eur.J.|28||doi:10.1002/chem.202200034

CCDC 1826458: Experimental Crystal Structure Determination

Related Article: Marta Mon, Rosaria Bruno, Rosangela Elliani, Antonio Tagarelli, Xiaoni Qu, Sanping Chen, Jesús Ferrando-Soria, Donatella Armentano, Emilio Pardo|2018|Inorg.Chem.|57|13895|doi:10.1021/acs.inorgchem.8b02409

CCDC 1823991: Experimental Crystal Structure Determination

Related Article: Marta Mon, Rosaria Bruno, Jesús Ferrando-Soria, Lucia Bartella, Leonardo Di Donna, Marianna Talia, Rosamaria Lappano, Marcello Maggiolini, Donatella Armentano, Emilio Pardo|2018|Materials Horizons|5|683|doi:10.1039/C8MH00302E

CCDC 1826454: Experimental Crystal Structure Determination

Related Article: Marta Mon, Rosaria Bruno, Rosangela Elliani, Antonio Tagarelli, Xiaoni Qu, Sanping Chen, Jesús Ferrando-Soria, Donatella Armentano, Emilio Pardo|2018|Inorg.Chem.|57|13895|doi:10.1021/acs.inorgchem.8b02409

CCDC 1826455: Experimental Crystal Structure Determination

Related Article: Marta Mon, Rosaria Bruno, Rosangela Elliani, Antonio Tagarelli, Xiaoni Qu, Sanping Chen, Jesús Ferrando-Soria, Donatella Armentano, Emilio Pardo|2018|Inorg.Chem.|57|13895|doi:10.1021/acs.inorgchem.8b02409

CCDC 1891594: Experimental Crystal Structure Determination

Related Article: Marta Mon, Rosaria Bruno, Estefanía Tiburcio, Aida Grau-Atienza, Antonio Sepúlveda-Escribano, Enrique V. Ramos-Fernandez, Alessio Fuoco, Elisa Esposito, Marcello Monteleone, Johannes C. Jansen, Joan Cano, Jesús Ferrando-Soria, Donatella Armentano, Emilio Pardo|2019|Chem.Mater.|31|5856|doi:10.1021/acs.chemmater.9b01995

CCDC 1823993: Experimental Crystal Structure Determination

Related Article: Marta Mon, Rosaria Bruno, Jesús Ferrando-Soria, Lucia Bartella, Leonardo Di Donna, Marianna Talia, Rosamaria Lappano, Marcello Maggiolini, Donatella Armentano, Emilio Pardo|2018|Materials Horizons|5|683|doi:10.1039/C8MH00302E

CCDC 1891591: Experimental Crystal Structure Determination

Related Article: Marta Mon, Rosaria Bruno, Estefanía Tiburcio, Aida Grau-Atienza, Antonio Sepúlveda-Escribano, Enrique V. Ramos-Fernandez, Alessio Fuoco, Elisa Esposito, Marcello Monteleone, Johannes C. Jansen, Joan Cano, Jesús Ferrando-Soria, Donatella Armentano, Emilio Pardo|2019|Chem.Mater.|31|5856|doi:10.1021/acs.chemmater.9b01995

CCDC 1868872: Experimental Crystal Structure Determination

Related Article: Nadia Marino, Rosaria Bruno, Abdeslem Bentama, Alejandro Pascual-Álvarez, Francesc Lloret, Miguel Julve, Giovanni De Munno|2019|CrystEngComm|21|917|doi:10.1039/C8CE01894D

CCDC 2062289: Experimental Crystal Structure Determination

Related Article: Paula Escamilla, Marta Viciano-Chumillas, Rosaria Bruno, Donatella Armentano, Emilio Pardo, Jesús Ferrando-Soria|2021|Molecules|26|4098|doi:10.3390/molecules26134098

CCDC 1891582: Experimental Crystal Structure Determination

Related Article: Marta Mon, Rosaria Bruno, Estefanía Tiburcio, Aida Grau-Atienza, Antonio Sepúlveda-Escribano, Enrique V. Ramos-Fernandez, Alessio Fuoco, Elisa Esposito, Marcello Monteleone, Johannes C. Jansen, Joan Cano, Jesús Ferrando-Soria, Donatella Armentano, Emilio Pardo|2019|Chem.Mater.|31|5856|doi:10.1021/acs.chemmater.9b01995

CCDC 1891587: Experimental Crystal Structure Determination

Related Article: Marta Mon, Rosaria Bruno, Estefanía Tiburcio, Aida Grau-Atienza, Antonio Sepúlveda-Escribano, Enrique V. Ramos-Fernandez, Alessio Fuoco, Elisa Esposito, Marcello Monteleone, Johannes C. Jansen, Joan Cano, Jesús Ferrando-Soria, Donatella Armentano, Emilio Pardo|2019|Chem.Mater.|31|5856|doi:10.1021/acs.chemmater.9b01995

CCDC 1828624: Experimental Crystal Structure Determination

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CCDC 1964202: Experimental Crystal Structure Determination

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CCDC 1891590: Experimental Crystal Structure Determination

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CCDC 1985884: Experimental Crystal Structure Determination

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CCDC 1891593: Experimental Crystal Structure Determination

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CCDC 1823992: Experimental Crystal Structure Determination

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CCDC 1891579: Experimental Crystal Structure Determination

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CCDC 1868871: Experimental Crystal Structure Determination

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CCDC 1891584: Experimental Crystal Structure Determination

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CCDC 1891576: Experimental Crystal Structure Determination

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CCDC 2072808: Experimental Crystal Structure Determination

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CCDC 2132443: Experimental Crystal Structure Determination

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CCDC 2132442: Experimental Crystal Structure Determination

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CCDC 1891580: Experimental Crystal Structure Determination

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CCDC 1826457: Experimental Crystal Structure Determination

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CCDC 1977986: Experimental Crystal Structure Determination

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CCDC 1474777: Experimental Crystal Structure Determination

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CCDC 1891586: Experimental Crystal Structure Determination

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CCDC 1826449: Experimental Crystal Structure Determination

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CCDC 2075709: Experimental Crystal Structure Determination

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CCDC 1964204: Experimental Crystal Structure Determination

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CCDC 1891581: Experimental Crystal Structure Determination

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CCDC 1964203: Experimental Crystal Structure Determination

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CCDC 1921930: Experimental Crystal Structure Determination

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CCDC 2132445: Experimental Crystal Structure Determination

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CCDC 1891592: Experimental Crystal Structure Determination

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CCDC 1843113: Experimental Crystal Structure Determination

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CCDC 1541853: Experimental Crystal Structure Determination

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CCDC 2128260: Experimental Crystal Structure Determination

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CCDC 2007972: Experimental Crystal Structure Determination

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CCDC 1826451: Experimental Crystal Structure Determination

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CCDC 1868873: Experimental Crystal Structure Determination

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CCDC 1891585: Experimental Crystal Structure Determination

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CCDC 1843115: Experimental Crystal Structure Determination

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CCDC 1823994: Experimental Crystal Structure Determination

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CCDC 1828625: Experimental Crystal Structure Determination

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CCDC 1921928: Experimental Crystal Structure Determination

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CCDC 1891578: Experimental Crystal Structure Determination

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CCDC 1985885: Experimental Crystal Structure Determination

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CCDC 1964201: Experimental Crystal Structure Determination

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CCDC 1868874: Experimental Crystal Structure Determination

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CCDC 1891589: Experimental Crystal Structure Determination

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CCDC 2132446: Experimental Crystal Structure Determination

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CCDC 1977987: Experimental Crystal Structure Determination

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CCDC 1891595: Experimental Crystal Structure Determination

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CCDC 1891596: Experimental Crystal Structure Determination

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CCDC 1921929: Experimental Crystal Structure Determination

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CCDC 1938636: Experimental Crystal Structure Determination

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CCDC 1977985: Experimental Crystal Structure Determination

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