0000000001299100

AUTHOR

Bikash Kumar Shaw

showing 10 related works from this author

An unusual magnetic response in a π-stacked 66-dia net structure of [4 + 2] copper(II) cubane

2015

A phenoxo bridged antiferromagnetic copper(II) cubane, features a π-stacked 66 -dia net framework, which creates long range ferromagnetic ordering, as evidenced from a coercivity maximum (~2000 Oe) at 20K with very unusual saturation magnetization. peerReviewed

magnetic responsecopper(II) cubane
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An unusual magnetic response in a π-stacked 66-dia net structure of [4 + 2] copper(II) cubane

2015

A phenoxo bridged antiferromagnetic copper(II) cubane features a π-stacked 66-dia net framework and creates long range ferromagnetic ordering, as evidenced from a coercivity maximum (∼2000 Oe) at 20 K with very unusual saturation magnetization.

General Chemical Engineeringchemistry.chemical_elementGeneral ChemistryMagnetic responseCoercivityCoppercopper(II) cubaneCrystallographychemistry.chemical_compoundmagnetic responsechemistryFerromagnetismCubaneNet (polyhedron)Antiferromagnetismta116RSC Advances
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Field-induced ferromagnetism due to magneto-striction in 1-D helical chains

2016

Two homochiral copper(II) helices, [Cu(μ1,3-N3)(L1)]n (1) and [Cu(μ1,3-NCO)(L2)]n (2), with end-to-end pseudohalide bridges, were synthesized using two N2O donor achiral Schiff bases via spontaneous chiral resolution. Field-induced ferromagnetic ordering due to magneto-striction in homochiral 1-D helix [Cu(μ1,3-N3)(L1)]n (1) is reported for the first time. At temperatures below 5.5 K, under a magnetic field of 1 T, orthogonality between the magnetic orbitals of copper centres increases significantly due to the contraction of lattice parameters, giving rise to long-range ferromagnetic ordering in the helical chain. The magneto-dielectric results are also indicative of the observed magneto-st…

Quantitative Biology::BiomoleculesCondensed matter physicsChemistryGeneral Chemical Engineeringchemistry.chemical_element02 engineering and technologyGeneral Chemistry010402 general chemistry021001 nanoscience & nanotechnology01 natural sciencesCopperChiral resolutionHelical chain0104 chemical sciencesMagnetic fieldfield-induced ferromagnetismCrystallographyFerromagnetismAtomic orbitalLattice (order)Helix0210 nano-technologyta116RSC Advances
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Asymmetric bis-(μ1,1-azido) bridged dinuclear copper(II) complex with N2O donor Schiff base: synthesis, structure and magnetic study

2015

A copper(II) complex, [Cu2(L)2(N3)2] [where HL = 2-((3-(methylamino)propylimino)methyl)-6-methoxyphenol] has been synthesized and characterized by elemental analysis, IR, UV–vis and fluorescence spectroscopy, and single-crystal X-ray diffraction studies. The complex crystallizes in the trigonal space group R. The deprotonated tridentate Schiff base occupies three coordination sites of copper(II). The fourth coordination site is occupied by an azide. A symmetry-related azide from a different molecule coordinates with the fifth site of copper(II), thereby forming a double end-on azide-bridged centrosymmetric dimer. Variable temperature solid–state magnetic studies between 2 and 300 K were car…

Schiff baseStereochemistryDimerchemistry.chemical_elementschiff baseCopperchemistry.chemical_compoundCrystallographyMagnetizationCopper(II)Deprotonationchemistryfield-dependent magnetization studyantiferromagneticMaterials ChemistryMoleculeAntiferromagnetismAzidePhysical and Theoretical Chemistrydinuclearta116Journal of Coordination Chemistry
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CCDC 1053244: Experimental Crystal Structure Determination

2016

Related Article: Bikash Kumar Shaw, Mithun Das, Anik Bhattacharyya, Biswa Nath Ghosh, Susmita Roy, Prabhat Mandal, Kari Rissanen, Shouvik Chattopadhyay, Shyamal Kumar Saha|2016|RSC Advances|6|22980|doi:10.1039/C5RA27040E

Space GroupCrystallographyCrystal Systemcatena-[(2-(1-((2-(dimethylamino)ethyl)imino)ethyl)-1-naphtholato)-(mu-azido)-copper(ii)]Crystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 991416: Experimental Crystal Structure Determination

2015

Related Article: Mithun Das, Bikash Kumar Shaw, Biswa Nath Ghosh, Kari Rissanen, Shyamal Kumar Saha, Shouvik Chattopadhyay|2015|RSC Advances|5|46869|doi:10.1039/C5RA07548C

tetrakis(mu3-2-(2-Oxido-3-methoxybenzylidene)hydrazinecarboxamide)-tetra-copper tetraperchlorate tetrahydrateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1053245: Experimental Crystal Structure Determination

2016

Related Article: Bikash Kumar Shaw, Mithun Das, Anik Bhattacharyya, Biswa Nath Ghosh, Susmita Roy, Prabhat Mandal, Kari Rissanen, Shouvik Chattopadhyay, Shyamal Kumar Saha|2016|RSC Advances|6|22980|doi:10.1039/C5RA27040E

Space GroupCrystallographyCrystal Systemcatena-[(2-(1-((2-(dimethylamino)ethyl)imino)ethyl)-1-naphtholato)-(mu-azido)-copper(ii)]Crystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1053247: Experimental Crystal Structure Determination

2016

Related Article: Bikash Kumar Shaw, Mithun Das, Anik Bhattacharyya, Biswa Nath Ghosh, Susmita Roy, Prabhat Mandal, Kari Rissanen, Shouvik Chattopadhyay, Shyamal Kumar Saha|2016|RSC Advances|6|22980|doi:10.1039/C5RA27040E

Space GroupCrystallographycatena-[(1-(((2-(dimethylamino)ethyl)imino)methyl)-2-naphtholato)-(mu-cyanato)-copper(ii)]Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1007150: Experimental Crystal Structure Determination

2016

Related Article: MITHUN DAS, BIKASH KUMAR SHAW, BISWA NATH GHOSH, KARI RISSANEN, SHYAMAL KUMAR SAHA and SHOUVIK CHATTOPADHYAY|2015|J.Coord.Chem.|68|1361|doi:10.1080/00958972.2015.1014350

Space GroupCrystallographyCrystal SystemCrystal Structurebis(mu-azido)-bis(2-methoxy-6-(((3-(methylamino)propyl)imino)methyl)phenolato)-di-copper(ii)Cell ParametersExperimental 3D Coordinates
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CCDC 1053243: Experimental Crystal Structure Determination

2016

Related Article: Bikash Kumar Shaw, Mithun Das, Anik Bhattacharyya, Biswa Nath Ghosh, Susmita Roy, Prabhat Mandal, Kari Rissanen, Shouvik Chattopadhyay, Shyamal Kumar Saha|2016|RSC Advances|6|22980|doi:10.1039/C5RA27040E

Space GroupCrystallographyCrystal Systemcatena-[(2-(1-((2-(dimethylamino)ethyl)imino)ethyl)-1-naphtholato)-(mu-azido)-copper(ii)]Crystal StructureCell ParametersExperimental 3D Coordinates
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