6533b7dafe1ef96bd126edb9

RESEARCH PRODUCT

An unusual magnetic response in a π-stacked 66-dia net structure of [4 + 2] copper(II) cubane

Biswa Nath GhoshKari RissanenShouvik ChattopadhyayBikash Kumar ShawShyamal K. SahaMithun Das

subject

General Chemical Engineeringchemistry.chemical_elementGeneral ChemistryMagnetic responseCoercivityCoppercopper(II) cubaneCrystallographychemistry.chemical_compoundmagnetic responsechemistryFerromagnetismCubaneNet (polyhedron)Antiferromagnetismta116

description

A phenoxo bridged antiferromagnetic copper(II) cubane features a π-stacked 66-dia net framework and creates long range ferromagnetic ordering, as evidenced from a coercivity maximum (∼2000 Oe) at 20 K with very unusual saturation magnetization.

10.1039/c5ra07548chttps://doi.org/10.1039/c5ra07548c