0000000001299116

AUTHOR

Song Gao

Magnetization Relaxation in a Three‐Dimensional Ligated Cobalt Phosphonate Containing Ferrimagnetic Chains

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Does the thermal evolution of molecular structures critically affect the magnetic anisotropy?

A dysprosium based single-ion magnet is synthesized and characterized by the angular dependence of the single-crystal magnetic susceptibility. Ab initio and effective electrostatic analyses are performed using the molecular structures determined from single crystal X-ray diffraction at 20 K, 100 K and 300 K. Contrary to the common assumption, the results reveal that the structural thermal effects that may affect the energy level scheme and magnetic anisotropy below 100 K are negligible.

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CCDC 1045633: Experimental Crystal Structure Determination

Related Article: Kang Qian, José J. Baldoví, Shang-Da Jiang, Alejandro Gaita-Ariño, Yi-Quan Zhang, Jacob Overgaard, Bing-Wu Wang, Eugenio Coronado, Song Gao|2015|Chemical Science|6|4587|doi:10.1039/C5SC01245G

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CCDC 766166: Experimental Crystal Structure Determination

Related Article: Peng-Fei Wang, Yan Duan, J.M.Clemente-Juan, You Song, Kang Qian, Song Gao, Li-Min Zheng|2011|Chem.-Eur.J.|17|3579|doi:10.1002/chem.201002348

research product

CCDC 1045632: Experimental Crystal Structure Determination

Related Article: Kang Qian, José J. Baldoví, Shang-Da Jiang, Alejandro Gaita-Ariño, Yi-Quan Zhang, Jacob Overgaard, Bing-Wu Wang, Eugenio Coronado, Song Gao|2015|Chemical Science|6|4587|doi:10.1039/C5SC01245G

research product

CCDC 1045631: Experimental Crystal Structure Determination

Related Article: Kang Qian, José J. Baldoví, Shang-Da Jiang, Alejandro Gaita-Ariño, Yi-Quan Zhang, Jacob Overgaard, Bing-Wu Wang, Eugenio Coronado, Song Gao|2015|Chemical Science|6|4587|doi:10.1039/C5SC01245G

research product