0000000001299209
AUTHOR
Bernhard Zobel
Cyclic Dinuclear Organotin Cations Stabilized by Bulky Substituents
The syntheses of sterically congested 2,2-bis(diorganochloridostannyl)propane, Me2C(SnClR2)2 (1; R = CH(SiMe3)2), the related salts [cyclo-{Me2C(SnR2)2X}B(ArF)4] (2, X = Cl; 3, X = OAc; 4, X = OH; ArF = 3,5-(CF3)2C6H3), and the four-membered-ring cyclo-{Me2C(SnR2)2O} (5) are reported. The compounds have been characterized by elemental and EDX analyses, 1H, 11B, 13C, 19F, 29Si, and 119Sn NMR and IR spectroscopy, electrospray ionization mass spectrometry, and single-crystal X-ray diffraction analysis.
CCDC 1409484: Experimental Crystal Structure Determination
Related Article: Michael Wagner, Bernhard Zobel, Christina Dietz, Dieter Schollmeyer, and Klaus Jurkschat|2015|Organometallics|34|5602|doi:10.1021/acs.organomet.5b00829
CCDC 1409486: Experimental Crystal Structure Determination
Related Article: Michael Wagner, Bernhard Zobel, Christina Dietz, Dieter Schollmeyer, and Klaus Jurkschat|2015|Organometallics|34|5602|doi:10.1021/acs.organomet.5b00829
CCDC 1409487: Experimental Crystal Structure Determination
Related Article: Michael Wagner, Bernhard Zobel, Christina Dietz, Dieter Schollmeyer, and Klaus Jurkschat|2015|Organometallics|34|5602|doi:10.1021/acs.organomet.5b00829
CCDC 1409488: Experimental Crystal Structure Determination
Related Article: Michael Wagner, Bernhard Zobel, Christina Dietz, Dieter Schollmeyer, and Klaus Jurkschat|2015|Organometallics|34|5602|doi:10.1021/acs.organomet.5b00829
CCDC 1409485: Experimental Crystal Structure Determination
Related Article: Michael Wagner, Bernhard Zobel, Christina Dietz, Dieter Schollmeyer, and Klaus Jurkschat|2015|Organometallics|34|5602|doi:10.1021/acs.organomet.5b00829