0000000001299481

AUTHOR

Aron J. Huckaba

showing 9 related works from this author

A new cross-linkable 9,10-diphenylanthracene derivative as a wide bandgap host for solution-processed organic light-emitting diodes

2018

Efficient organic light-emitting diodes (OLEDs) can be obtained using multilayered architectures where the processes of charge injection, transport and recombination are separated and optimized in each layer. Processing these structures from solution requires strategies to avoid redissolution or damage of the previously deposited layers. Several reports have demonstrated the development of cross-linkable hole transport materials, while less literature describes the synthesis and applications of such wide bandgap host materials for multilayered OLEDs. In this work we introduce a cross-linkable derivative of 9-(4-(10-phenylanthracene-9-yl)phenyl)-9H-carbazole incorporating styrene moieties (S…

chemistry.chemical_classificationMaterials sciencebusiness.industryBand gapRadical polymerization910-Diphenylanthracene02 engineering and technologyGeneral ChemistryPolymerElectroluminescence010402 general chemistry021001 nanoscience & nanotechnology01 natural sciences0104 chemical scienceschemistry.chemical_compoundchemistryMaterials ChemistryOLEDOptoelectronics0210 nano-technologybusinessLayer (electronics)DiodeJournal of Materials Chemistry C
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Molecular Engineering of Iridium Blue Emitters Using Aryl N‐Heterocyclic Carbene Ligands

2016

The synthesis of a new series of neutral bis[2-(2,4-difluorophen-2-yl)pyridine][1-(2-aryl)-3-methylimidazol-2-ylidene]iridium(III) complexes is reported. Each complex has been characterized by NMR spectroscopy, UV/Vis spectrophotometry, and cyclic voltammetry, and the photophysical properties examined in depth. Furthermore, two of the complexes have been characterized by single-crystal X-ray diffraction analysis. By systematically modifying the cyclometalating aryl group on the N-heterocyclic carbene (NHC) ligand from 2,4-dimethoxyphenyl to 6-methoxy-2-methyl-3-pyridyl, the energy levels of the Ir complexes were modified to produce new blue emitters with increased HOMO and triplet-state ene…

LigandArylchemistry.chemical_element02 engineering and technologyNuclear magnetic resonance spectroscopy010402 general chemistry021001 nanoscience & nanotechnologyPhotochemistry01 natural sciences0104 chemical sciencesInorganic Chemistrychemistry.chemical_compoundchemistryPyridineOLEDIridiumCyclic voltammetry0210 nano-technologyCarbeneEuropean Journal of Inorganic Chemistry
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Phosphine Oxide Derivative as a Passivating Agent to Enhance the Performance of Perovskite Solar Cells

2021

Defects of metal-halide perovskites detrimentally influence the optoelectronic properties of the thin film and, ultimately, the photovoltaic performance of perovskite solar cells (PSCs). Especially, defect-mediated nonradiative recombination that occurs at the perovskite interface significantly limits the power conversion efficiency (PCE) of PSCs. In this regard, interfacial engineering or surface treatment of perovskites has become a viable strategy for reducing the density of surface defects, thereby improving the PCE of PSCs. Here, an organic molecule, tris(5-((tetrahydro-2H-pyran-2-yl)oxy)pentyl) phosphine oxide (THPPO), is synthesized and introduced as a defect passivation agent in PSC…

Phosphine oxideMaterials sciencePhotovoltaic systemEnergy Engineering and Power Technology02 engineering and technology010402 general chemistry021001 nanoscience & nanotechnology7. Clean energy01 natural sciences0104 chemical scienceschemistry.chemical_compoundchemistryChemical engineeringMaterials ChemistryElectrochemistryChemical Engineering (miscellaneous)Lewis acids and basesElectrical and Electronic EngineeringThin film0210 nano-technologyÒxidsMaterialsDerivative (chemistry)Cèl·lules fotoelèctriquesPerovskite (structure)ACS Applied Energy Materials
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Bis(arylimidazole) Iridium Picolinate Emitters and Preferential Dipole Orientation in Films

2018

The straightforward synthesis and photophysical properties of a new series of heteroleptic iridium(III) bis(2-arylimidazole) picolinate complexes are reported. Each complex has been characterized by nuclear magnetic resonance, UV-vis, cyclic voltammetry, and photoluminescent angle dependency, and the emissive properties of each are described. The preferred orientation of transition dipoles in emitter/host thin films indicated more preferred orientation than homoleptic complex Ir(ppy)3.

PhotoluminescenceMaterials sciencePicolinate emittersGeneral Chemical EngineeringThin filmschemistry.chemical_elementHOL - Holst02 engineering and technologyOrientation (graph theory)010402 general chemistry01 natural sciencesArticleEmissive propertieslcsh:Chemistrychemistry.chemical_compoundIridiumThin filmHomolepticCommon emitterTS - Technical SciencesIndustrial InnovationGeneral Chemistry021001 nanoscience & nanotechnology0104 chemical sciencesDipoleCrystallographychemistrylcsh:QD1-999Nano TechnologyCyclic voltammetryElectronics0210 nano-technology
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CCDC 1445197: Experimental Crystal Structure Determination

2016

Related Article: Sadig Aghazada, Aron J. Huckaba, Antonio Pertegas, Azin Babaei, Giulia Grancini, Iwan Zimmermann, Henk Bolink and Mohammad Khaja Nazeeruddin|2016|Eur.J.Inorg.Chem.||5089|doi:10.1002/ejic.201600971

Space GroupCrystallographyCrystal SystemCrystal Structure(2-methyl-6-methoxy-3-(3-methylimidazol-1-yl-2-ylidene)pyridin-4-yl)-bis(35-difluoro-2-(2-pyridyl)phenyl)-iridiumCell ParametersExperimental 3D Coordinates
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CCDC 1445196: Experimental Crystal Structure Determination

2016

Related Article: Sadig Aghazada, Aron J. Huckaba, Antonio Pertegas, Azin Babaei, Giulia Grancini, Iwan Zimmermann, Henk Bolink and Mohammad Khaja Nazeeruddin|2016|Eur.J.Inorg.Chem.||5089|doi:10.1002/ejic.201600971

Space GroupCrystallographyCrystal SystemCrystal Structure(26-dimethoxy-3-(3-methylimidazol-1-yl-2-ylidene)pyridin-4-yl)-bis(35-difluoro-2-(2-pyridyl)phenyl)-iridiumCell ParametersExperimental 3D Coordinates
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CCDC 1583689: Experimental Crystal Structure Determination

2018

Related Article: Aron J. Huckaba, Alessia Senes, Sadig Aghazada, Azin Babaei, Stefan C. J. Meskers, Iwan Zimmermann, Pascal Schouwink, Natalia Gasilova, René A. J. Janssen, Henk J. Bolink, Mohammad Khaja Nazeeruddin|2018|ACS Omega|3|2673|doi:10.1021/acsomega.8b00137

bis(2-{1-[246-tri-isopropylphenyl]-1H-imidazol-2-yl}phenyl)-(pyridine-2-carboxylato)-iridium hydrateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1583690: Experimental Crystal Structure Determination

2018

Related Article: Aron J. Huckaba, Alessia Senes, Sadig Aghazada, Azin Babaei, Stefan C. J. Meskers, Iwan Zimmermann, Pascal Schouwink, Natalia Gasilova, René A. J. Janssen, Henk J. Bolink, Mohammad Khaja Nazeeruddin|2018|ACS Omega|3|2673|doi:10.1021/acsomega.8b00137

Space GroupCrystallographybis(2-{1-[26-di-isopropylphenyl]-1H-imidazol-2-yl}phenyl)-(4-methoxypyridine-2-carboxylate)-iridium hemihydrateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1584183: Experimental Crystal Structure Determination

2018

Related Article: Aron J. Huckaba, Alessia Senes, Sadig Aghazada, Azin Babaei, Stefan C. J. Meskers, Iwan Zimmermann, Pascal Schouwink, Natalia Gasilova, René A. J. Janssen, Henk J. Bolink, Mohammad Khaja Nazeeruddin|2018|ACS Omega|3|2673|doi:10.1021/acsomega.8b00137

Space GroupCrystallographybis(2-{1-[26-di-isopropylphenyl]-1H-imidazol-2-yl}phenyl)-(4-methylpyridine-2-carboxylato)-iridiumCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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