0000000001299512
AUTHOR
E. Goreshnik
The first copper(I)-olefin complexes bearing a 1,3,4-oxadiazole core: Alternating-current electrochemical crystallization, X-ray experiment and DFT study
By means of alternating-current electrochemical technique, four new π-complexes, namely [Cu2(C11H10N2OS)2Br1.91Cl0.09] (1), [Cu(C11H10N2OS)NO3] (2), [Cu2(C11H10N2OS)2(H2O)2](BF4)2 (3) and [Cu2(C11H10N2OS)2(H2O)2](ClO4)2 (4), were obtained using copper(II) salts and the 2-(allylthio)-5-phenyl-1,3,4-oxadiazole (C11H10N2OS) ligand. The metal and halogen centers in 1 form Cu2X2 dimers; the N-atom from the oxadiazole ring and the Cdouble bond; length as m-dashC bond of the allyl group from the same ligand complete the copper coordination environment, giving [Cu(C11H10N2OS)X]2 isolated fragments. The ligand plays the same chelating role in 2, whereas the O (NO3) atom occupies the third position i…
CCDC 1531991: Experimental Crystal Structure Determination
Related Article: Yu. Slyvka, E. Goreshnik, G. Veryasov, D. Morozov, M. Luk'yanov, M. Mys'kiv|2017|Polyhedron|133|319|doi:10.1016/j.poly.2017.05.052
CCDC 226111: Experimental Crystal Structure Determination
Related Article: E.Goreshnik, D.Schollmeier, M.Mys'kiv|2003|Acta Crystallogr.,Sect.C:Cryst.Struct.Commun.|59|m478|doi:10.1107/S0108270103021978
CCDC 1531992: Experimental Crystal Structure Determination
Related Article: Yu. Slyvka, E. Goreshnik, G. Veryasov, D. Morozov, M. Luk'yanov, M. Mys'kiv|2017|Polyhedron|133|319|doi:10.1016/j.poly.2017.05.052
CCDC 236023: Experimental Crystal Structure Determination
Related Article: E.Goreshnik, D.Schollmeyer, M.Mys'kiv|2004|Acta Crystallogr.,Sect.E:Struct.Rep.Online|60|m279|doi:10.1107/S1600536804002466
CCDC 1531993: Experimental Crystal Structure Determination
Related Article: Yu. Slyvka, E. Goreshnik, G. Veryasov, D. Morozov, M. Luk'yanov, M. Mys'kiv|2017|Polyhedron|133|319|doi:10.1016/j.poly.2017.05.052
CCDC 1531990: Experimental Crystal Structure Determination
Related Article: Yu. Slyvka, E. Goreshnik, G. Veryasov, D. Morozov, M. Luk'yanov, M. Mys'kiv|2017|Polyhedron|133|319|doi:10.1016/j.poly.2017.05.052
CCDC 226110: Experimental Crystal Structure Determination
Related Article: E.Goreshnik, D.Schollmeier, M.Mys'kiv|2003|Acta Crystallogr.,Sect.C:Cryst.Struct.Commun.|59|m478|doi:10.1107/S0108270103021978
CCDC 268080: Experimental Crystal Structure Determination
Related Article: E.Goreshnik, D.Schollmeyer, M.Mys'kiv|2005|Acta Crystallogr.,Sect.C:Cryst.Struct.Commun.|61|m127|doi:10.1107/S0108270105000806