0000000001299518
AUTHOR
Joachim Kusz
showing 43 related works from this author
57Fe Mössbauer spectroscopy predicts superstructure for K0.08[Cu(II)(N,N'app)Cl]2[Fe(III)(CN)6].0.92H3O.3H2O.
2007
The compound [Cu(N,N'app)Cl](2)[Fe(CN)(6)].xH(2)O, with N,N'app being bis(N,N'-3-aminopropylpiperazine), was prepared and its structure determined by single crystal X-ray analysis, confirming a ratio of two copper complexes to one iron complex; (57)Fe Mössbauer spectra showed three quadrupole doublets typical of iron(iii) low spin species which call for the presence of a superstructure.
Variable-temperature X-ray crystal structure determinations of {Fe[tren(6-Mepy)3]}(ClO4)2and {Zn[tren(6-Mepy)3]}(ClO4)2compounds: correlation of the …
2007
Variable-temperature X-ray crystal structure determinations (80–330 K) on compounds {Fe[tren(6-Mepy)3]}(ClO4)2(1-Fe) {tren(6-Mepy)3is tris[3-aza-4-(6-methyl-2-pyridyl)but-3-enyl]amine} and {Zn[tren(6-Mepy)3]}(ClO4)2(1-Zn) {tren(6-Mepy)3is tris[3-aza-4-(6-methyl-2-pyridyl)but-3-enyl]amine} were carried out together with a detailed analysis of the unit-cell volume and parameters in the spin transition region for (1-Fe). Both compounds crystallize in the monoclinic system and retained the space groupP21/cat all measured temperatures. The Fe and Zn atoms are surrounded by six N atoms belonging to imine groups and pyridine groups of the trifurcated ligand, adopting a pseudo-octahedral symmetry. …
X-ray powder diffraction and LIESST-effect of the spin transition material [Fe(bpp)2](NCS)2·2H2O
2006
Abstract We have studied the X-ray powder diffraction of the spin transition material [Fe(bpp)2](NCS)2 · 2H2O (bpp: 2,6-bis(pyrazol-3-yl)pyridine) at room temperature. Two crystallographic phases have been observed depending on the sample history of this material. The results obtained corroborate the earlier observations from magnetic and calorimetric studies. Relatively prolonged exposure of the sample to X-rays caused a structural change. LIESST and Reverse-LIESST effects, characterised by 57Fe Mossbauer spectroscopy, have been observed in this material.
X-ray investigation and discussion of the magnetostriction of Gd3T(T= Ni, Rh, Irx) single crystals
2000
The variations of the lattice parameters of Gd3T(T= Ni, Rh, Irx) single crystals with temperature were measured in the range 10–300 K. The compounds with Ni and Rh crystallize in the orthorhombic space groupPnma, but the compound with Ir crystallizes as Gd5Ir2in the monoclinic space groupA2/a. The three compounds exhibit an anomalous anisotropic spontaneous magnetostriction below the magnetic ordering temperature.
Correlations of the distribution of spin states in spin crossover compounds
1999
Abstract Short range correlations of the distribution of high spin (HS) and low spin (LS) states show up in thermal spin transition curves, decay curves of the light induced metastable HS state (LIESST state), and in structural features during the spin transitions. Correlations are due to short range interactions between the spin crossover molecules. Short range interactions may compete with omnipresent long range interactions and give rise to interesting spin transition phenomena. In this paper, the effect of correlations on the thermal spin transition in the mixed crystal system [Fe x Zn 1− x (pic) 3 ]Cl 2 ·EtOH (pic=picolylamine) is discussed. In particular the step in the thermal transi…
LEAD-FREE (Na0.5Bi0.5)1-xBaxTiO3 SINGLE CRYSTALS (0 ≤ x ≤ 0.05) AND THEIR DIELECTRIC AND PYROELECTRIC PROPERTIES
2009
ABSTRACT Lead-free single crystals of Na0.5Bi0.5TiO3-BaTiO3 (NBT-BT) system were prepared by Czochralski method and their dielectric and pyroelectric properties have been studied. The results were compared with these for pure NBT. The obtained samples show pure perovskite structure with rhombohedral symmetry at room temperature. Low frequency (100 Hz–100 kHz) investigations reveal the diffuse phase transitions. The obtained results are discussed in terms of local electric and strain fields caused by different ionic radius of (Na, Bi) and Ba ions. The NBT-BT system is expected to be a new promising candidate for lead-free electronic crystals.
Microstructural and magnetic characterization of dusts from a stone crushing industry in Birbhum, India
2010
Abstract Stone dust sample collected from a stone crushing industry situated at Muhammad Bazar in Birbhum, India, is studied for its physical characterization using various techniques. Morphology and compositional analysis of the stone dust by scanning electron microscopy (SEM) reveal that the dust is an agglomeration of many tiny particles (0.32–2.12 μm), mostly having sharp edges, as well show microstructure heterogeneity. Elements present in the sample are detected by energy dispersive X-ray spectrometry (EDX). The X-ray diffraction (XRD) pattern analysis shows that the sample mainly contains minerals like anorthite, augite, esseneite and albite. An overall antiferromagnetic interaction …
The LIESST state of [Fe(pic)3]Cl2.EtOH – the superstructure under continuous irradiation
2005
The superstructure recently discovered in [Fe(pic)3]Cl2.EtOH at temperatures inside the step region of the high-spin–low-spin transition curve sheds new light on the anomalous transition behaviour in spin crossover compounds. The structure of the metastable LIESST state of [Fe(pic)3]Cl2.EtOH at 10 K has been measured. The decay has been followed by X-ray diffraction using a CCD camera in order to detect reflections of the superstructure building up during the decay. No signal above the noise of the CCD camera was observed, so that even diffuse scattering could not be detected. This finding is in agreement with correlation lengths of pair correlations of molecules in the HS and LS states bei…
Magnetic properties of the TbMn2 single crystals
1999
Abstract Single crystals of TbMn 2 were grown by the Czochralski method from a levitated melt. Results of electrical resistivity, magnetization in strong magnetic fields along the principal crystallographic directions, AC and DC magnetic susceptibility and the temperature dependence of the lattice parameter are presented.
Rod-like ferrites obtained through thermal degradation of a molecular ferrimagnet
2010
This paper presents the characteristics of iron oxides obtained through thermal degradation of a molecular ferrimagnet, {N(n-C4H9)4[Fe II
Structural phase transition to disorder low-temperature phase in [Fe(ptz)6](BF4)2 spin-crossover compounds.
2012
In the spin-crossover compound [Fe(ptz)6](BF4)2 (where ptz=1-n-propyltetrazole) six different phases are observed. When a single crystal is slowly cooled from high temperatures to those below 125 K, the reflections broaden into diffuse maxima and split into two maxima along the c* direction [Kusz, Gütlich & Spiering (2004). Top. Curr. Chem. 234, 129–153]. As both maxima are broad along the c* direction, the short-range order exists only along the c direction and in the ab plane the structure remains long-range ordered. In this disordered phase additional satellite reflections appear. Upon heating above 135 K, the diffuse maxima return to their previous shape and this process is complete…
Study of phase transition in Bi3TiNbO9-BaBi2Nb2O9 ceramics
2016
Abstract The subject of the paper is lead free bismuth layer structure oxides (1-x)Bi3TiNbO9-xBaBi2Nb2O9 (x=0; 1; 2; 3 mol). The influence of Bi3TiNbO9/BaBi2Nb2O9 ratio on dielectric and structural properties was studied in a wide range of temperatures. Change in the ratio causes a decrease in the maximum value of dielectric permittivity and shifts the temperature of ε’max to low values, leading to linear decreasing of average grain size and linear increasing of ceramics density. These results indicate an augment of the packing degree and the participation of pores are significantly decreased with the increase of BaBi2Nb2O9 compound intake. Moreover, for 0.7Bi3TiNbO9-0.3BaBi2Nb2O9 ceramics …
STRUCTURE AND PHASE TRANSITIONS IN [C(NH2)3]SbCl6 CRYSTALS
1998
Abstract The crystal structure of [C(NH2)3]SbCl6 at 298 K (monoclinic, C2/m) and 240 K (monoclinic, P21/a) has been determined. The structure consists of isolated SbCl6− anions and guanidinium cations. Differential scanning calorimetry, dilatometric and dielectric studies revealed two structural phase transitions; a first-order one at 351 K and a second-order one at 265 K. One of the two crystallographically non-equivalent anions, SbCl6−(1), disordered in the room temperature phase is postulated to contribute to the phase transition mechanism at 265 K. A ferroelastic domain structure is found below 351 K.
Microstructural and magnetic characterization of fly ash from Kolaghat Thermal Power Plant in West Bengal, India
2011
Abstract This paper reports on the physical nature of the fly ash sample of the Kolaghat Thermal Power Plant, India with an emphasis on its ultrafine nature. This paper also deals with the measurement of the magnetic properties of the fine particles of the fly ash sample. Particle sizes of this fly ash sample estimated from the SEM images lie within 0.16–5.50 μm, and the EDX spectral analysis indicates the presence of O, Al, Si, C, Fe, Mg, Na, K and Ti in this sample. From the XRD study, it is found that physical nature of conglomeration in the fly ash is crystalline and the major components are mullite (Al 6 Si 2 O 13 ) and quartz (SiO 2 ). Additionally, the presence of hematite, microclin…
Iron(II) Metallomesogens Exhibiting Coupled Spin State and Liquid Crystal Phase Transitions near Room Temperature
2008
Reaction of the ligand 2,2,2-tris(2-aza-3-((5-akloxy)(6-methyl)(2-pyridyl))prop-2-enyl)ethane (C n -tameMe) with Fe(X) 2 . sH 2 O salts afforded a series of spin crossover metallomesogens with general formula [Fe(C n -tame)](X) 2 . sH 2 O (s ≥ 0), with n = 6, 10, 12, 14, 16, 17, 18, or 20 and X =ClO 4 - or BF 4 -. Single crystal X-ray measurements have been performed on the [Fe(C 6 -tameMe)](ClO 4 ) 2 (C 6 -1) derivative at 100 K. The complex C 6 -1 crystallizes in the triclinic system and adopts the Pbca space group. The iron(II) ion is in a distorted octahedral environment shaped by three imine and three pyridine nitrogen atoms of the C n -tameMe ligand. The average Fe-N im and Fe-N py bo…
Structural and Dielectric Properties of (Na0.5Bi0.5)0.70Ba0.30TiO3 Ceramics.
2003
Abstract A (Na0.5Bi0.5)0.70Ba0.30TiO3 ceramic has been studied by X-ray diffraction and by measurements of dielectric and ferroelectric properties between room temperature and 450 °C. A sharp increase in the electric permittivity and dielectric loss near 200 °C has been observed. This sharp increase in dielectric responses indicates a transformation between normal and relaxor ferroelectric states. It is found that polar regions can exist at higher temperatures. The X-ray diffraction study shows that the transformation corresponds to the first order phase transition from tetragonal to cubic. The use of the (Na0.5Bi0.5)0.70Ba0.30TiO3 ceramic for device application has also been indicated.
X-ray structure study of the light-induced metastable states of the spin-crossover compound [Fe(mtz)6](BF4)2
2001
Iron(II) complexes exhibiting thermal spin-crossover may be converted from the1A1low-spin (LS) state to the5T2high-spin (HS) state by irradiation with green light (light-induced excited spin-state trapping, LIESST) and from the LS to the HS state by irradiation with red light (reverse LIESST). The lifetime of the metastable LIESST states may be sufficiently long to enable an X-ray diffraction study. The lattice parameters of a single crystal of [Fe(mtz)6](BF4)2(mtz = methyltetrazole) (space groupP21/n) were measured between 300 and 10 K. While one Fe lattice site (A) of the crystal changes from the HS to the LS state near 78 K, the other site (B) remains in the LS state. Using the green lig…
Anomalies in low-temperature lattice parameters of ErFeO3 and ErAlO3 single crystals: correlation with magnetic properties
2005
Abstract The paper presents the results of an experimental study of thermal expansion of isostructural orthorhombic ErFeO3 and ErAlO3 single crystals. Changes of lattice parameters have been investigated by X-ray measurements in the 10–300 K temperature range. Above ∼150 K, experimental results correspond well to the phonon mechanism. At low temperatures distinct anisotropic anomalies were observed in both compounds; and a correlation with the magnetic properties of the relevant ions is noted.
Structural, thermal, dielectric and ferroelectric properties of Na0.5K0.5NbO3and Na0.5K0.5NbO3+0.5mol%MnO2ceramics
2014
Lead-free Na0.5K0.5NbO3 and Na0.5K0.5NbO3+0.5mol%MnO2 ceramics were fabricated by solid state hot pressing sintering process. The phase structure and thermal, dielectric and ferroelectric properties of these ceramics were investigated. X-ray measurements showed that all samples have a single perovskite structure and possess orthorhombic–tetragonal and tetragonal–cubic phase transitions. Sequence of phase transitions was confirmed by differential scanning calorimetry (DSC) and dielectric measurements. Obtained results showed that optimal temperature sintering of Na0.5K0.5 NbO3+0.5mol%MnO2 ceramics is 1100 °C. The results show that investigated ceramics are one of the promising materials as e…
Structural and electric characteristics of (Na0.5Bi0.5)0.50Ba0.50TiO3 and (Na0.5Bi0.5)0.20Ba0.80TiO3 ceramics
2003
Abstract (Na0.5Bi0.5)0.50Ba0.50TiO3 and (Na0.5Bi0.5)0.20Ba0.80TiO3 ceramics have been prepared by the solid state reaction and studied by X-ray diffraction and by measurements of dielectric and ferroelectric properties between room temperature and 550 °C. A sharp increase in the electric permittivity and dielectric loss near 212 °C (for the first material) and near 205 °C (for the second material) on heating with remarkable thermal hysteresis have been observed. This sharp increase in dielectric responses indicates transformation between normal and relaxor ferroelectric states. The X-ray diffraction study shows that this transformation corresponds to the first order phase transition from te…
PHASE TRANSITIONS IN HALOGENOANTIMONATE(V) CRYSTALS: [N(CH3)4]SbCl6 AND [N(C2H5)4]SbCl6
1998
Abstract New crystals of the family of alkylammonium chloroantimonates(V), [N(CH 3 ) 4 ]SbCl 6 and [N(C 2 H 5 ) 4 ]SbCl 6 , have been grown and systematically studied. X-ray studies show that [N(C 2 H 5 ) 4 ]SbCl 6 is composed of isolated cations and ideal SbCl 6 − octahedra. Differential scanning calorimetry, dilatometric and dielectric measurements reveal structural phase transitions in [N(CH 3 ) 4 ]SbCl 6 and [N(C 2 H 5 ) 4 ]SbCl 6 of first order at 236 and 345 K, respectively. The measurements of 1 H-NMR spin-lattice relaxation times, T 1 , show that mechanism of the phase transitions in [N(CH 3 ) 4 ]SbCl 6 and [N(C 2 H 5 ) 4 ]SbCl 6 is due to the reorientations of the tetraalkylammoniu…
Spin- and phase transition in the spin crossover complex [Fe(ptz)6](BF4)2 studied by nuclear inelastic scattering of synchrotron radiation and by DFT…
2006
Abstract Nuclear inelastic scattering (NIS) spectra of [Fe(ptz) 6 ](BF 4 ) 2 (ptz = 1- n -propyl-tetrazole) have been measured for five phases differing in spin state and crystallographic structure. Different spectral patterns have been found for the low-spin and high-spin phases and are described in terms of normal coordinate analysis of the complex molecule. For both low-spin and high-spin phases the conversion from ordered to disordered phase results in splitting of the observed NIS bands. Packing becomes visible in the NIS spectra via coupling of the Fe–N stretching vibrations with those of the terminal n -propyl groups. The DFT-based normal coordinate analysis also reveals the characte…
Experimental and theoretical characterization of chelidonic acid structure
2022
Abstract Chelidonic acid (4-oxo-4H-pyran-2,6-dicarboxylic acid) is present in plants of Papaveraceae family, especially in Chelidonium majus. Due to its anticancer, antibacterial, hepatoprotective, and antioxidant properties, it has been used in medical treatments. In this work, the X-ray structure of methanol solvate of chelidonic acid was determined. Layers of chelidonic acid are held by hydrogen bonds via COOH and C = O fragments and additionally bridged by methanol. The formed H-bond network between two acid units is different from typical –COOH dimers observed, e.g., in crystals of isophtalic acid. The molecular structure of 2,6-dimethyl-γ-pyrone (2Me4PN) and chelidonic acid, a 2,6-dic…
Spontaneous magnetostriction and thermal expansibility of TmFeO3 and LuFeO3 rare earth orthoferrites
2001
Abstract At low temperatures the TmFeO3 orthoferrite shows a strong spontaneous magnetostriction generated by rare earth Tm atoms. This effect essentially depends on the temperature and orientation of the weak ferromagnetism vector of the Fe sublattice and reaches largest values for the directions [1 0 0] and [0 0 1]. The spin reorientation process in TmFeO3 marks itself mainly in the change of the signs of the linear thermal expansion coefficients in the directions mentioned above. Some additional singularities of thermal dependencies of expansion coefficients are observed below 20 K, which may be due to a magnetic compensation effect in the investigated orthoferrite.
X-ray study of the light-induced metastable state of a spin-crossover compound
2000
Iron(II) complexes exhibiting thermal spin crossover may be converted from the1A1low-spin (LS) state to the5T2high-spin (HS) state by irradiation with green light (light-induced excited spin-state trapping, LIESST). The lifetime of the metastable LIESST state may be sufficiently long for X-ray diffraction study. The lattice parameters of a single crystal of [Fe(ptz)6](BF4)2(ptz = propyltetrazole) were measured between 300 and 10 K, while the crystal changed from the HS to the LS state near 135 K. Using the green light (514 nm) of an argon-ion laser, the crystal was quantitatively converted to the metastable LIESST state at 10 K; its lattice parameters were measured up to 50 K, at which poin…
X-ray diffraction, optical birefringence, and87Rb nuclear magnetic resonance spectroscopy of the paraelectric and antiferroelectric phases of Rb3DxH1…
2002
The antiferroelectric (AFE) phase transition of Rb3DxH1-x(SO4)2 was studied using x-ray diffraction, optical birefringence, and nuclear magnetic resonance. The orientation dependence of the resonance lines deduced from the quadrupole-perturbed 87Rb nuclear magnetic resonance of Rb3D(SO4)2 single crystals indicates slight deviations from the monoclinic symmetry in the paraelectric and the AFE phases. The dynamical critical exponents as deduced from measurements of the spin-lattice relaxation times depend on the deuteron concentration. Additionally, we have carried out x-ray single-crystal diffraction as well as optical birefringence measurements and find clear evidence for a structural phase…
High Temperature Study of Metamict Steenstrupine
2010
Metamict minerals contain radioactive elements that degrade their crystal structure. Unlike other metamict minerals, annealing process under ambient pressure do not lead to direct recrystallization of steenstrupine.
Crystallographic, electronic structure and magnetic properties of the GdTAl; T=Co, Ni and Cu ternary compounds
2000
Abstract Single phase GdCoAl, GdCuAl and single crystal GdNiAl samples of good quality were synthesized. The electrical resistivity, magnetization and AC susceptibility as a function of temperature revealed in all these compounds a ferromagnetic ordering at 100, 83 and 60 K, respectively. A magnetic transition, probably to a non-colinear structure was observed in GdNiAl at 31 K as well as the presence of the third magnetic transition at 14 K, while in the GdCuAl compound an evidence of similar transition was found at 23 K. In GdNiAl a transition between two different crystallographic phases of ZrNiAl-type was observed at 220 K. The transition was accompanied by rapid jumps of crystal lattic…
Crystal‐Structure Studies of Mononuclear Iron(II) Complexes with Two‐Step Spin Crossover: [Fe{5‐NO 2 ‐sal‐N(1,4,7,10)}] Revisited
2013
In the region of the spin transition of spin-crossover (SCO) compounds there coexist molecules in both high-spin (HS) and low-spin (LS) states. In the case of two-step spin transition, theoretical predictions and computer simulations have shown that HS and LS complex molecules should be ordered in the plateau region. Several examples that support this hypothesis are already presented in the literature. Herein, we discuss a mononuclear complex of iron(II) with two-step spin transition in terms of long-range ordering of HS and LS molecules. In such compounds, spin transition is associated with the formation of a superstructure. However, previous studies of the [Fe{5-NO2-sal-N(1,4,7,10)}] [5-N…
Control of the spin state by charge and ligand substitution: two-step spin crossover behaviour in a novel neutral iron(II) complex
2014
The influence of the charge and steric hindrance on the spin state of a series of four monomeric Fe-II complexes derived from the tridentate tigands 2-(1H-benzoimidazol-2-yl)-1,10-phenanthroline (Hphenbi) and 2-(1H-benzoimidazol-2-yl-9-methyl-1,10-phenanthroline (Hmphenbi) and their deprotonated forms (phenbi(-), mphenbi(-)) are investigated. The crystal structure and magnetic properties show that [Fe(Hphenbi)(2)](BF4)(2)center dot 1.5C(6)H(5)NO(2)center dot H2O (1) and its neutral form [Fe(phenbi)(2)]center dot 2CHCl(3)center dot H2O (2) are low-spin complexes at 400 K due to the strong ligand field imparted by the terpyridine-like tigand. In contrast, the steric hindrance induced by the m…
Iron(II) Spin Transition Complexes with Dendritic Ligands, Part I
2008
The ligands G1- and G2-oligo (benzyl ether) (PBE) dendrons and their iron(II) complexes [Fe(Gn-PBE)3]A2·xH2O (with n = 1, 2 and A = triflate, tosylate) were prepared. The magnetic properties of the complexes were investigated by a SQUID magnetometer. All complexes exhibit gradual spin transition below room temperature. At very low temperatures the magnetic behaviour reflects zero-field splitting (ZFS) effects. 57Fe-Mossbauer spectroscopy was performed to distinguish between ZFS of high spin species and spin state conversion into the low spin state. Further characterisation was carried out by thermogravimetric analysis (TGA) and FT-IR spectroscopy. Structural features have been determined by…
Synchrotron powder-diffraction study of the spin transition compound [Fe(bpp)2](NCS)2·2H2O and soft X-ray-induced structural phase conversion
2008
Abstract We have studied the high spin and low spin structural phases of the two-step spin transition compound [Fe(bpp) 2 ](NCS) 2 ·2H 2 O (bpp: 2,6-bis(pyrazol-3-yl)pyridine) of different sample history with X-ray synchrotron ( λ ∼ 0.32 A) powder diffraction at different temperatures as well as with usual X-ray ( λ ∼ 1.54 A) powder diffraction at room temperature by performing rapid repeated scans at regular intervals of time. A structural phase transition occurs only during the first step of the spin transition. Time dependent interconversions of the two crystallographic phases have been observed at room temperature for this material. The results indicate that a soft X-ray (Cu-K α )-ind…
Mononuclear Complexes of Iron(II) Based on Symmetrical Tripodand Ligands: Novel Parent Systems for the Development of New Spin Crossover Metallomesog…
2011
The synthesis and characterization of a series of mononuclear tripodand-based FeII complexes by means of Mossbauer andUV/Vis spectroscopic as well as magnetic methods is reported. The complexes were obtained from the reactions of FeII salt with heterocyclic aldehydes (imd = imidazole-4(5)-carboxaldehyde, py = picolinaldehyde, or 6-Mepy = 6-methylpicolinaldehyde) and a symmetric triamine [tren = tris(2-aminoethyl)amine, tame = 2,2,2-tris(aminomethyl)ethane, or tach = 1,3,5-cis,cis-cyclohexanetriamin]. Because of extreme rigidity of the capping triamine tach, the molecular structure of {Fe[tach(imd)3](BF4)2} (1) features an unprecedented tapered trigonal prismatic FeN6 polyhedron. The molecul…
High Temperature Study of Metamict Rinkite
2013
Metamict minerals contain radioactive elements that degrade their crystal structure. During the annealing process under ambient pressure in argon atmosphere the sample of metamict rinkite recrystallizes to the primary crystalline form at 700°C. Further heating leads to the formation of a new crystalline phase.
Dielectric and magnetic properties of CdMoO4:Gd3+ single crystal
2014
Broadband dielectric spectroscopy and magnetic measurements provide experimental evidence that the CdMoO4:Gd 3+ single crystal is the paramagnet with low relative dielectric permittivity (er � 8), which slightly depends on the temperature and frequencies. Magnetization with zero coercivity and remanence is almost a universal function of l0H/T, characterizing superparamagnetic-like behavior. These results are being considered in a framework of the random distribution of the Ga 3+ ions in the tetragonal structure.
The deformation tensor ∊ of the spin transition in the mixed crystal [Fe0.46Zn0.54(ptz)6](BF4)2
2004
The conversion of the spin state of complexes exhibiting thermal spin crossover from the1A1low-spin (LS) state to the5T2high-spin (HS) state is accompanied by a deformation of the lattice due to the larger bond lengths in the HS state as compared with the LS state. In a previous work [Kuszet al.(2000).J. Appl. Cryst.33, 201–205], it has been shown that the deformation of the lattice, corrected for its temperature dependence, can be described by an almost temperature-independent tensor ∊ multiplied by the fraction of molecules in the HS state, γHS. Here the dependence of ∊ in a mixed single crystal of [Fe0.46Zn0.54(ptz)6](BF4)2(ptz = propyltetrazole) with a transition temperature near 110 K …
CCDC 1007129: Experimental Crystal Structure Determination
2014
Related Article: Maksym Seredyuk, Kateryna O. Znovjyak, Joachim Kusz, Maria Nowak, M. Carmen Muñoz, Jose Antonio Real|2014|Dalton Trans.|43|16387|doi:10.1039/C4DT01885K
CCDC 1007130: Experimental Crystal Structure Determination
2014
Related Article: Maksym Seredyuk, Kateryna O. Znovjyak, Joachim Kusz, Maria Nowak, M. Carmen Muñoz, Jose Antonio Real|2014|Dalton Trans.|43|16387|doi:10.1039/C4DT01885K
CCDC 1007126: Experimental Crystal Structure Determination
2014
Related Article: Maksym Seredyuk, Kateryna O. Znovjyak, Joachim Kusz, Maria Nowak, M. Carmen Muñoz, Jose Antonio Real|2014|Dalton Trans.|43|16387|doi:10.1039/C4DT01885K
CCDC 1007125: Experimental Crystal Structure Determination
2014
Related Article: Maksym Seredyuk, Kateryna O. Znovjyak, Joachim Kusz, Maria Nowak, M. Carmen Muñoz, Jose Antonio Real|2014|Dalton Trans.|43|16387|doi:10.1039/C4DT01885K
CCDC 1007128: Experimental Crystal Structure Determination
2014
Related Article: Maksym Seredyuk, Kateryna O. Znovjyak, Joachim Kusz, Maria Nowak, M. Carmen Muñoz, Jose Antonio Real|2014|Dalton Trans.|43|16387|doi:10.1039/C4DT01885K
CCDC 2144108: Experimental Crystal Structure Determination
2022
Related Article: Natalina Makieieva, Teobald Kupka, Grzegorz Spaleniak, Oimahmad Rahmonov, Agata Marek, Alfred Błażytko, Leszek Stobiński, Nataliya Stadnytska, Danuta Pentak, Aneta Buczek, Małgorzata A. Broda, Piotr Kuś, Joachim Kusz, Maria Książek|2022|Struct.Chem.|33|2133|doi:10.1007/s11224-022-02026-7
CCDC 1007127: Experimental Crystal Structure Determination
2014
Related Article: Maksym Seredyuk, Kateryna O. Znovjyak, Joachim Kusz, Maria Nowak, M. Carmen Muñoz, Jose Antonio Real|2014|Dalton Trans.|43|16387|doi:10.1039/C4DT01885K