6533b7d0fe1ef96bd125b9b2
RESEARCH PRODUCT
57Fe Mössbauer spectroscopy predicts superstructure for K0.08[Cu(II)(N,N'app)Cl]2[Fe(III)(CN)6].0.92H3O.3H2O.
C. Matthias GrunertS. ReimanJoachim KuszP. GütlichUday MukhopadhyayIvan Bernalsubject
Metals and Alloyschemistry.chemical_elementGeneral ChemistryCopperCatalysisSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsCrystallographyNuclear magnetic resonancechemistryQuadrupoleMössbauer spectroscopyMaterials ChemistryCeramics and CompositesIron complexMossbauer spectraSingle crystalSuperstructure (condensed matter)description
The compound [Cu(N,N'app)Cl](2)[Fe(CN)(6)].xH(2)O, with N,N'app being bis(N,N'-3-aminopropylpiperazine), was prepared and its structure determined by single crystal X-ray analysis, confirming a ratio of two copper complexes to one iron complex; (57)Fe Mössbauer spectra showed three quadrupole doublets typical of iron(iii) low spin species which call for the presence of a superstructure.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2007-03-29 | Chemical communications (Cambridge, England) |