Author: Florent Desroches

0000000001299579

AUTHOR

Florent Desroches

showing 3 related works from this author

Selective recognition of small hydrogen bond acceptors by a calix[6]arene-based molecular container

2019

Selective molecular recognition is of primary importance for applications such as sensing and separation of chemicals. This work describes the host-guest and crystallisation properties of a penta-carbamated calix[6]arene designed as a molecular container with a H-donating recognition group directed towards the heart of the cavity. As demonstrated by NMR spectroscopy and X-ray diffraction studies, this macrocyclic receptor can selectively recognise small H-bond acceptors through one or two hydrogen bonds, the guests nesting inside the polyaromatic cavity surrounded by eleven bulky tert-butyl groups.

Primary (chemistry)010405 organic chemistryChemistryHydrogen bondGeneral Chemistry010402 general chemistryContainer (type theory)01 natural sciencesCombinatorial chemistry0104 chemical scienceskemialliset sidoksetmacrocyclesMolecular recognitionCalixarenehalogeenisidoksetChimiemolecular recognitionCalixarenesinclusion complexeshost-guest

researchProduct

CCDC 1952601: Experimental Crystal Structure Determination

2019

Related Article: Roy Lavendomme, Florent Desroches, Steven Moerkerke, Filip Topić, Johan Wouters, Kari Rissanen, Michel Luhmer, Ivan Jabin|2020|Supramol.Chem.|32|23|doi:10.1080/10610278.2019.1679374

Space GroupCrystallographyCrystal SystemCrystal Structure51117232935-hexa-t-butyl-37-hydroxy-3839404142-pentakis((t-butylcarbamoyl)oxy)calix(6)arene dimethyl sulfoxide clathrate 1122-tetrachloroethane unknown solvateCell ParametersExperimental 3D Coordinates

researchProduct

CCDC 1959492: Experimental Crystal Structure Determination

2019

Related Article: Roy Lavendomme, Florent Desroches, Steven Moerkerke, Filip Topić, Johan Wouters, Kari Rissanen, Michel Luhmer, Ivan Jabin|2020|Supramol.Chem.|32|23|doi:10.1080/10610278.2019.1679374

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters51117232935-hexa-t-butyl-37-hydroxy-3839404142-pentakis((t-butylcarbamoyl)oxy)calix(6)arene chloroform unknown solvateExperimental 3D Coordinates

researchProduct

PEPhysical Sciences and Engineering
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