0000000001299902
AUTHOR
Oleh Stetsiuk
showing 11 related works from this author
Mononuclear and One-Dimensional Cobalt(II) Complexes with the 3,6-Bis(picolylamino)-1,2,4,5-tetrazine Ligand
2018
International audience
Mono- and Binuclear Copper(II) and Nickel(II) Complexes with the 3,6-Bis(picolylamino)-1,2,4,5-Tetrazine Ligand
2021
Four new compounds of formulas [Cu(hfac)2(L)] (1), [Ni(hfac)2(L)] (2), [{Cu(hfac)2}2(µ-L)]·2CH3OH (3) and [{Ni(hfac)2}2(µ-L)]·2CH3CN (4) [Hhfac = hexafluoroacetylacetone and L = 3,6-bis(picolylamino)-1,2,4,5-tetrazine] have been prepared and their structures determined by X-ray diffraction on single crystals. Compounds 1 and 2 are isostructural mononuclear complexes where the metal ions [copper(II) (1) and nickel(II) (2)] are six-coordinated in distorted octahedral MN2O4 surroundings which are built by two bidentate hfac ligands plus another bidentate L molecule. This last ligand coordinates to the metal ions through the nitrogen atoms of the picolylamine fragment. Compounds 3 and 4 are cen…
Co-existence of ferro- and antiferromagnetic interactions in a hexanuclear mixed-valence CoIII2MnII2MnIV2 cluster sustained by a multidentate Schiff …
2019
The successful utilization of the “direct synthesis” approach yielded the unprecedented hexanuclear complex of formula [Co2MnII2MnIV2(L1)4Cl2(μ3-O)2(dmf)4]·2dmf (1) (H3L is the Schiff base derived from the condensation of salicylaldehyde and 3-aminopropane-1,2-diol). Single crystal X-ray analysis revealed that 1 crystallizes in the monoclinic system P21/c and it contains a rare mixed-valence {CoIII2MnII2MnIV2(μ2-O)8(μ3-O)2} core where all metal ions are linked through the phenolato and alkoxo groups of the L3− ligand. Besides the charge balance resulting from the X-ray structure, the oxidation state of the metal ions has been confirmed by XPS spectroscopy. Cryomagnetic studies indicate the …
CCDC 2070862: Experimental Crystal Structure Determination
2021
Related Article: Oleh Stetsiuk, Abdelkrim El-Ghayoury, Francesc Lloret, Miguel Julve, Narcis Avarvari|2021|Molecules|26|2122|doi:10.3390/molecules26082122
CCDC 1580448: Experimental Crystal Structure Determination
2018
Related Article: Oleh Stetsiuk, Abdelkrim El-Ghayoury, Francesc Lloret, Miguel Julve, Narcis Avarvari|2018|Eur.J.Inorg.Chem.||449|doi:10.1002/ejic.201701224
CCDC 1580449: Experimental Crystal Structure Determination
2018
Related Article: Oleh Stetsiuk, Abdelkrim El-Ghayoury, Francesc Lloret, Miguel Julve, Narcis Avarvari|2018|Eur.J.Inorg.Chem.||449|doi:10.1002/ejic.201701224
CCDC 1580450: Experimental Crystal Structure Determination
2018
Related Article: Oleh Stetsiuk, Abdelkrim El-Ghayoury, Francesc Lloret, Miguel Julve, Narcis Avarvari|2018|Eur.J.Inorg.Chem.||449|doi:10.1002/ejic.201701224
CCDC 2070865: Experimental Crystal Structure Determination
2021
Related Article: Oleh Stetsiuk, Abdelkrim El-Ghayoury, Francesc Lloret, Miguel Julve, Narcis Avarvari|2021|Molecules|26|2122|doi:10.3390/molecules26082122
CCDC 1819913: Experimental Crystal Structure Determination
2019
Related Article: Oleh Stetsiuk, Valentyn Synytsia, Svitlana R. Petrusenko, Vladimir N. Kokozay, Abdelkrim El-Ghayoury, Joan Cano, Francesc Lloret, Miguel Julve, Benoit Fleury, Narcis Avarvari|2019|Dalton Trans.|48|11862|doi:10.1039/C9DT02503K
CCDC 2070864: Experimental Crystal Structure Determination
2021
Related Article: Oleh Stetsiuk, Abdelkrim El-Ghayoury, Francesc Lloret, Miguel Julve, Narcis Avarvari|2021|Molecules|26|2122|doi:10.3390/molecules26082122
CCDC 2070863: Experimental Crystal Structure Determination
2021
Related Article: Oleh Stetsiuk, Abdelkrim El-Ghayoury, Francesc Lloret, Miguel Julve, Narcis Avarvari|2021|Molecules|26|2122|doi:10.3390/molecules26082122