Author: Ramakirushnan Suriya Narayanan

0000000001300094

AUTHOR

Ramakirushnan Suriya Narayanan

A hexaicosametallic copper(ii) phosphonate

Structure and characterization of [Cu26{2,3,5,6-(Me)4C6H-CH2-PO3}18(μ2-OH)4(μ3-OH)6(μ4-Cl)6(μ-OH2)2(OH2)2(MeCN)4]·6MeCN·15H2O (1) is reported. Complex 1 is the largest discrete molecular homometallic transition metal phosphonate assembly. Remarkably, this gigantic molecular phosphonate has been prepared at room temperature using a normal solution synthetic method.

research product

CCDC 892148: Experimental Crystal Structure Determination

Related Article: Vadapalli Chandrasekhar, Dipankar Sahoo, Ramakirushnan Suriya Narayanan, Raymond J. Butcher, Franscesc Lloret, Emilio Pardo|2013|Dalton Trans.|42|8192|doi:10.1039/c3dt00103b

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