0000000001300243

AUTHOR

Jasmin Krause

showing 11 related works from this author

Increasing the nuclearity and spin ground state in a new family of ferromagnetically-coupled {Ni10} disk-like complexes bearing exclusively end-on br…

2018

The synthesis of a new family of ferromagnetically-coupled {Ni10} clusters counterbalanced by various [Ln(NO3)5]2− ions is herein described. The resulting compounds are organic chelate-free and the metal ions are exclusively bridged by end-on azido ligands to stabilize a beautiful disk-like topology reminiscent of the structure of the brucite mineral.

Bridging (networking)010405 organic chemistryChemistryBruciteMetal ions in aqueous solutionMetals and AlloysGeneral Chemistryengineering.material010402 general chemistry01 natural sciencesCatalysis0104 chemical sciencesSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsIonCrystallographyMaterials ChemistryCeramics and CompositesengineeringGround stateChemical Communications
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A Click‐Functionalized Single‐Molecule Magnet Based on Cobalt(II) and Its Analogous Manganese(II) and Zinc(II) Compounds

2014

A mononuclear CoII single-molecule magnet suitable for click chemistry was investigated. [M(oda)(aterpy)] complexes (oda2– = oxodiacetate, aterpy = 4′-azido-2,2′:6′,2″-terpyridine) with M = MnII, ZnII, and CoII were synthesized as azide-functionalized building blocks for the copper-catalyzed azide–alkyne cycloaddition reaction. The required structural integrity of the complexes in solution was proven in great detail by using ESI-MS and NMR spectroscopy. For the six-coordinate [Co(oda)(aterpy)] complex, single-molecule magnet behavior was confirmed with an effective energy barrier of 4.2 cm–1.

Inorganic ChemistrychemistryMagnetPolymer chemistryInorganic chemistryClick chemistrychemistry.chemical_elementSingle-molecule magnetManganeseZincNuclear magnetic resonance spectroscopyCobaltCycloadditionEuropean Journal of Inorganic Chemistry
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Rational linkage of magnetic molecules using click chemistry

2015

Established CuAAC click reactions are used for the first time to assemble magnetic molecules to an extended molecular arrangement. This novel synthetic approach is expected to be a general approach to link SMMs as an important precondition to realize quantum computing.

ChemistryMetals and AlloysNanotechnologyGeneral ChemistryLinkage (mechanical)Combinatorial chemistryCatalysisSurfaces Coatings and FilmsElectronic Optical and Magnetic Materialslaw.inventionMagnetic moleculeslawMaterials ChemistryCeramics and CompositesClick chemistryChemical Communications
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CCDC 965183: Experimental Crystal Structure Determination

2014

Related Article: Christian Plenk, Jasmin Krause, Eva Rentschler|2015|Eur.J.Inorg.Chem.||370|doi:10.1002/ejic.201402955

Space GroupCrystallographyCrystal SystemCrystal Structure(Oxydiacetato)-(4'-azido-22':6'2''-terpyridine)-cobalt(II) dihydrateCell ParametersExperimental 3D Coordinates
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CCDC 1027635: Experimental Crystal Structure Determination

2014

Related Article: Christian Plenk, Jasmin Krause, Eva Rentschler|2015|Eur.J.Inorg.Chem.||370|doi:10.1002/ejic.201402955

Space GroupCrystallographyCrystal System(Oxydiacetato)-(4'-azido-22':6'2''-terpyridine)-manganese(II) hexahydrateCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1864765: Experimental Crystal Structure Determination

2018

Related Article: Jasmin Krause, Dimitris I. Alexandropoulos, Luca M. Carrella, Eva Rentschler, Theocharis C. Stamatatos|2018|Chem.Commun.|54|12499|doi:10.1039/C8CC07722C

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersoctadecakis(mu-azido)-tetradecakis(acetonitrile)-deca-nickel pentakis(nitrato)-gadolinium acetonitrile solvate dihydrateExperimental 3D Coordinates
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CCDC 910513: Experimental Crystal Structure Determination

2015

Related Article: Christian Plenk, Jasmin Krause, Martin Beck, Eva Rentschler|2015|Chem.Commun.|51|6524|doi:10.1039/C5CC00595G

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis(Tetramethylammonium) tetrakis(mu3-4-ethynylsalicylhydroxamato-NOOO'O'')-penta-copper(ii) dihydrateExperimental 3D Coordinates
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CCDC 1869182: Experimental Crystal Structure Determination

2018

Related Article: Jasmin Krause, Dimitris I. Alexandropoulos, Luca M. Carrella, Eva Rentschler, Theocharis C. Stamatatos|2018|Chem.Commun.|54|12499|doi:10.1039/C8CC07722C

octadecakis(mu-azido)-tetradecakis(acetonitrile)-deca-nickel(ii) pentanitrato-yttrium(iii) acetonitrile solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 965184: Experimental Crystal Structure Determination

2014

Related Article: Christian Plenk, Jasmin Krause, Eva Rentschler|2015|Eur.J.Inorg.Chem.||370|doi:10.1002/ejic.201402955

Space GroupCrystallographyCrystal SystemCrystal Structure(Oxydiacetato)-(4'-azido-22':6'2''-terpyridine)-zinc(II) dihydrateCell ParametersExperimental 3D Coordinates
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CCDC 1864766: Experimental Crystal Structure Determination

2018

Related Article: Jasmin Krause, Dimitris I. Alexandropoulos, Luca M. Carrella, Eva Rentschler, Theocharis C. Stamatatos|2018|Chem.Commun.|54|12499|doi:10.1039/C8CC07722C

octadecakis(mu-azido)-tetradecakis(acetonitrile)-deca-nickel pentakis(nitrato)-terbium acetonitrile solvate dihydrateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1864767: Experimental Crystal Structure Determination

2018

Related Article: Jasmin Krause, Dimitris I. Alexandropoulos, Luca M. Carrella, Eva Rentschler, Theocharis C. Stamatatos|2018|Chem.Commun.|54|12499|doi:10.1039/C8CC07722C

Space GroupCrystallographyCrystal Systemoctadecakis(mu-azido)-tetradecakis(acetonitrile)-deca-nickel pentakis(nitrato)-dysprosium acetonitrile solvate monohydrateCrystal StructureCell ParametersExperimental 3D Coordinates
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