0000000001300453
AUTHOR
Maria Cherepanova
Synthesis of novel functionalized cispentacins through C–C oxidative cleavage of diendo-norbornene β-amino acid
Difunctionalized cispentacin derivatives with two new stereogenic centres have been synthesized from a diendo-norbornene β-amino acid in a stereocontrolled route, involving C–C double bond functionalization by dihydroxylation, followed by oxidative ring cleavage and transformation of the dialdehyde intermediates through a Wittig reaction.
CCDC 919638: Experimental Crystal Structure Determination
Related Article: Maria Cherepanova, Loránd Kiss, Reijo Sillanpää, Ferenc Fülöp|2013|RSC Advances|3|9757|doi:10.1039/C3RA41963K