0000000001301036

AUTHOR

Rongmin Yu

showing 11 related works from this author

Chiral Organometallic Triangles with Rh−Rh Bonds. 2. Compounds Prepared from Enantiopure cis-Rh2(C6H4PPh2)2(OAc)2(HOAc)2 and Their Catalytic Potentia…

2005

Enantiomers of the orthometalated dirhodium compound cis-Rh2(C6H4PPh2)2(OAc)2(HOAc)2 (R-1 and S-1) were prepared from carboxylate exchange reactions of the resolved diasteroisomers of cis-Rh2(C6H4PPh2)2(protos)2(H2O)2 (protos = N-4-methylphenylsulfonyl-l-proline anion) and acetic acid. These compounds react with excess Me3OBF4 in CH3CN, producing the enantiomers of [cis-Rh2(C6H4PPh2)2(CH3CN)6](BF4)2 (R-2 and S-2) which have six labile and replaceable CH3CN ligands in equatorial and axial positions. Reactions of R-2 and S-2 with tetraethylammonium salts of the linear dicarboxylic acids, terephthalic acid (HO2CC6H4CO2H), oxalic acid (HO2CCO2H), and 4,4'-diphenyl-dicarboxylic acid (HO2CC6H4C6H…

Inorganic ChemistryTerephthalic acidAcetic acidchemistry.chemical_compoundEnantiopure drugchemistryStereochemistryOxalic acidCarboxylatePhysical and Theoretical ChemistryEnantiomerMedicinal chemistryCatalysisInorganic Chemistry
researchProduct

CCDC 291814: Experimental Crystal Structure Determination

2006

Related Article: F.A.Cotton, C.A.Murillo, S.-E.Stiriba, Xiaoping Wang, Rongmin Yu|2005|Inorg.Chem.|44|8223|doi:10.1021/ic051282c

Space GroupCrystallographyCrystal SystemCrystal StructureRRR-tris(mu~4~-44'-biphenyl-11'-dicarboxylato)-hexakis(mu~2~-2-(diphenylphosphino)phenyl)-bis(dichloromethane)-tetrapyridyl-hexa-rhodium dichloromethane methanol solvateCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 291816: Experimental Crystal Structure Determination

2006

Related Article: F.A.Cotton, C.A.Murillo, S.-E.Stiriba, Xiaoping Wang, Rongmin Yu|2005|Inorg.Chem.|44|8223|doi:10.1021/ic051282c

SSS-tris(mu~4~-benzene-14-dicarboxylato)-hexakis(mu~2~-2-(diphenylphosphino)phenyl)-tris(methanol)-tripyridyl-hexa-rhodium dichloromethane methanol solvate hydrateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 291817: Experimental Crystal Structure Determination

2006

Related Article: F.A.Cotton, C.A.Murillo, S.-E.Stiriba, Xiaoping Wang, Rongmin Yu|2005|Inorg.Chem.|44|8223|doi:10.1021/ic051282c

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersSSS-tris(mu~4~-oxalato)-hexakis(mu~2~-2-(diphenylphosphino)phenyl)-(methanol)-pentapyridyl-hexa-rhodium dichloromethane methanol solvateExperimental 3D Coordinates
researchProduct

CCDC 291810: Experimental Crystal Structure Determination

2006

Related Article: F.A.Cotton, C.A.Murillo, S.-E.Stiriba, Xiaoping Wang, Rongmin Yu|2005|Inorg.Chem.|44|8223|doi:10.1021/ic051282c

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(S)-cis-bis(mu2-acetato)-bis(mu2-2-(diphenylphosphino)phenyl)-bis(acetic acid)-di-rhodiumExperimental 3D Coordinates
researchProduct

CCDC 291813: Experimental Crystal Structure Determination

2006

Related Article: F.A.Cotton, C.A.Murillo, S.-E.Stiriba, Xiaoping Wang, Rongmin Yu|2005|Inorg.Chem.|44|8223|doi:10.1021/ic051282c

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersRRR-tris(mu~4~-oxalato)-hexakis(mu~2~-2-(diphenylphosphino)phenyl)-(dichloromethane)-pentapyridyl-hexa-rhodium dichloromethane solvateExperimental 3D Coordinates
researchProduct

CCDC 291818: Experimental Crystal Structure Determination

2006

Related Article: F.A.Cotton, C.A.Murillo, S.-E.Stiriba, Xiaoping Wang, Rongmin Yu|2005|Inorg.Chem.|44|8223|doi:10.1021/ic051282c

Space GroupCrystallographyRRR(SSS)-tris(mu~4~-benzene-14-dicarboxylato)-hexakis(mu~2~-2-(diphenylphosphino)phenyl)-pentakis(methanol)-pyridyl-hexa-rhodium dichloromethane methanol solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 291809: Experimental Crystal Structure Determination

2006

Related Article: F.A.Cotton, C.A.Murillo, S.-E.Stiriba, Xiaoping Wang, Rongmin Yu|2005|Inorg.Chem.|44|8223|doi:10.1021/ic051282c

Space GroupCrystallographyCrystal SystemCrystal Structure(R)-cis-bis(mu2-acetato)-bis(mu2-2-(diphenylphosphino)phenyl)-bis(acetic acid)-di-rhodiumCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 291811: Experimental Crystal Structure Determination

2006

Related Article: F.A.Cotton, C.A.Murillo, S.-E.Stiriba, Xiaoping Wang, Rongmin Yu|2005|Inorg.Chem.|44|8223|doi:10.1021/ic051282c

SSS-tris(mu4-benzene-14-dicarboxylato)-hexakis(mu2-2-(diphenylphosphino)phenyl)-hexapyridyl-hexa-rhodium dichloromethane methanol sesquihydrateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 291812: Experimental Crystal Structure Determination

2006

Related Article: F.A.Cotton, C.A.Murillo, S.-E.Stiriba, Xiaoping Wang, Rongmin Yu|2005|Inorg.Chem.|44|8223|doi:10.1021/ic051282c

Space GroupCrystallographyCrystal SystemCrystal StructureSSS-tris(mu~4~-oxalato)-hexakis(mu~2~-2-(diphenylphosphino)phenyl)-(dichloromethane)-pentapyridyl-hexa-rhodium dichloromethane solvateCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 291815: Experimental Crystal Structure Determination

2006

Related Article: F.A.Cotton, C.A.Murillo, S.-E.Stiriba, Xiaoping Wang, Rongmin Yu|2005|Inorg.Chem.|44|8223|doi:10.1021/ic051282c

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersSSS-tris(mu~4~-oxalato)-hexakis(mu~2~-2-(diphenylphosphino)phenyl)-aqua-pentakis(methanol)-hexa-rhodium dichloromethane methanol solvateExperimental 3D Coordinates
researchProduct