0000000001301062

AUTHOR

Mario Palacios-corella

showing 42 related works from this author

Bimetallic MnIII–FeII hybrid complexes formed by a functionalized MnIII Anderson polyoxometalate coordinated to FeII: observation of a field-induced …

2015

The synthesis and crystal structure of an Anderson POM functionalized with two 2,6-di(pyrazol-1-yl)-pyridine (1-bpp) ligands are reported (compound 1). High-frequency electron paramagnetic resonance (HF-EPR) and magnetic measurements show that it presents a significant negative axial zero-field splitting and field-induced slow relaxation of magnetization due to the presence of isolated MnIII anisotropic magnetic ions. Complexation of 1 with FeII gives rise to a 2D cationic network formed by Anderson POMs coordinated to two FeII ions through the two tridentate 1-bpp ligands and to other two FeII ions through two oxo ligands in compound 2, and to an anionic polymeric network formed by Anderso…

Materials scienceStereochemistryRelaxation (NMR)General ChemistryCrystal structureLIESSTlaw.inventionCrystallographyMagnetizationlawSpin crossoverPolyoxometalateMaterials ChemistryMoleculeElectron paramagnetic resonanceJournal of Materials Chemistry C
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Spin-crossover compounds based on iron(II) complexes of 2,6-bis(pyrazol-1-yl)pyridine (bpp) functionalized with carboxylic acid and ethyl carboxylic …

2018

International audience; Four new salts of the iron(II) complex of the 2,6-bis(pyrazol-1-yl)pyridine ligand functionalized with a carboxylic acid group (bppCOOH) of formulas [Fe(bppCOOH)2](BF4)2 (1(BF4)2), [Fe(bppCOOH)2](CF3SO3)2·yMe2CO (1(CF3SO3)2·yMe2CO), [Fe(bppCOOH)2](AsF6)2·yMe2CO (1(AsF6)2·yMe2CO) and [Fe(bppCOOH)2](SbF6)2·yMe2CO (1(SbF6)2·yMe2CO) have been prepared and characterized together with a more complete structural and photomagnetic characterization of the previously reported [Fe(bppCOOH)2](ClO4)2 (1(ClO4)2). Furthermore, the iron(II) complex of the ethyl ester derivative of bppCOOH (bppCOOEt) has been prepared and characterized (compound [Fe(bppCOOEt)2](ClO4)2·yMe2CO, 2(ClO4)…

chemistry.chemical_classification010405 organic chemistryLigandCarboxylic acidSpin transition[CHIM.MATE]Chemical Sciences/Material chemistryQuímica010402 general chemistry01 natural sciencesMedicinal chemistryLIESST0104 chemical sciencesInorganic Chemistrychemistry.chemical_compoundchemistrySpin crossoverPyridineÀcids carboxílicsCompostos de coordinacióIsostructuralDerivative (chemistry)
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Spin-crossover iron(ii) complex showing thermal hysteresis around room temperature with symmetry breaking and an unusually high T(LIESST) of 120 K.

2019

We report a Fe(II) complex based on 4′,4′′ carboxylic acid disubstituted dipyrazolylpyridine that shows a spin-crossover close to room temperature associated to a crystallographic phase transition and the LIESST effect with a high T(LIESST) of 120 K.

chemistry.chemical_classificationPhase transitionThermal hysteresisMaterials science010405 organic chemistryCarboxylic acidMetals and AlloysQuímicaGeneral Chemistry010402 general chemistry01 natural sciencesCatalysisLIESST3. Good health0104 chemical sciencesSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsCrystallographychemistrySpin crossoverMaterials ChemistryCeramics and CompositesCompostos de coordinacióSymmetry breakingChemical communications (Cambridge, England)
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Heteroleptic Iron(II) Spin-Crossover Complexes Based on a 2,6-Bis(pyrazol-1-yl)pyridine-type Ligand Functionalized with a Carboxylic Acid

2019

Two new heteroleptic complexes [Fe- (1bppCOOH)(3bpp-bph)](ClO4)2·solv (1·solv, solv = various solvents; 1bppCOOH = 2,6-bis(1H-pyrazol-1-yl)- isonicotinic acid; 3bpp-bph = 2,6-bis(5-([1,1′-biphenyl]-4- yl)-1H-pyrazol-3-yl)pyridine) and [Fe(1bppCOOH)- (1bppCOOEt)](ClO4)2 ·0.5Me2CO (2·0.5Me2CO, 1bppCOOEt = ethyl 2,6-bis(1H-pyrazol-1-yl)isonicotinate) were designed and prepared. The heteroleptic compound 1· solv was obtained by the combination of stoichiometric amounts of Fe(ClO4)2, 1bppCOOH, and 3bpp-bph, and it was designed to fine-tune the spin crossover (SCO) properties with respect to the previously reported homoleptic compound [Fe(1bppCOOH)2](ClO4)2. Indeed, the introduction of a new subs…

chemistry.chemical_classification010405 organic chemistryLigandCarboxylic acidEnllaços químicsQuímica organometàl·licaKetones010402 general chemistryIsonicotinic acidLigands01 natural sciencesMedicinal chemistry0104 chemical sciencesInorganic Chemistrychemistry.chemical_compoundLligandschemistrySpin crossoverCetonesPyridineCompostos de coordinacióPhysical and Theoretical ChemistryInorganic Chemistry
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Field-induced slow relaxation of magnetization in a mononuclear Co(II) complex of 2,6-bis(pyrazol-1-yl)pyridine functionalized with a carboxylic acid

2018

Abstract Combining Co(II) with the 2,6-bis-(pyrazol1-yl)pyridine ligand functionalized with a carboxylic acid group (bppCOOH) results in the compound [CoII(bppCOOH)2](ClO4)2·2Me2CO, which shows a field-induced slow relaxation of magnetization as a result of the magnetic anisotropy of the distorted octahedral coordination of high-spin Co(II). Co(II)/Fe(II) solid solutions of bppCOOH have been prepared to study the influence of Co(II) on the spin crossover properties of Fe(II). Magnetic characterization of [Fe0.92Co0.08(bppCOOH)2](ClO4)2 indicates that the Cobalt dopant leads to a reduction of T1/2 and a loss of cooperativity of the spin transition.

chemistry.chemical_classification010405 organic chemistryCarboxylic acidRelaxation (NMR)Spin transitionchemistry.chemical_element010402 general chemistry01 natural sciences0104 chemical sciencesInorganic ChemistryCrystallographyMagnetizationchemistry.chemical_compoundMagnetic anisotropychemistrySpin crossoverPyridineMaterials ChemistryPhysical and Theoretical ChemistryCobaltPolyhedron
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Redox and guest tunable spin-crossover properties in a polymeric polyoxometalate

2023

A bifunctionalized polyoxometalate (POM), [V6O19(C16H15N6O)2]2−, which contains a redox active hexavanadate moiety covalently linked to two tridentate 2,6-bis(pyrazol-1-yl)pyridine (1-bpp) ligands, has been prepared and characterized. Reaction of this hybrid molecule with Fe(II) or Zn(II) ions produces crystalline neutral 1D networks of formula Fe[V6O19(C16H15N6O)2]·solv (2) and Zn[V6O19(C16H15N6O)2]·solv (3) (solv = solvent molecules). Magnetic properties of 2 show an abrupt spin-crossover (SCO) with the temperature, which can be induced by light irradiation at 10 K (Light-Induced Excited Spin-State Trapping, LIESST effect). Interestingly, this porous and flexible structure enables reversi…

General ChemistryQuímicaIndústria químicaChemical Science
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Biodegradable Metal-Organic Framework-Based Microrobots (MOFBOTs).

2020

Microrobots and metal–organic frameworks (MOFs) have been identified as promising carriers for drug delivery applications. While clinical applications of microrobots are limited by their low drug loading efficiencies and the poor degradability of the materials used for their fabrication, MOFs lack motility and targeted drug delivery capabilities. The combination of these two fields marks the beginning of a new era; MOF‐based small‐scale robots (MOFBOTs) for biomedical applications. Yet, biodegradability is a major hurdle in the field of micro‐ and nanoswimmers including small‐scale robots. Here, a highly integrated MOFBOT that is able to realize magnetic locomotion, drug delivery, and selec…

zeolitic imidazolate frameworksMaterials scienceBiomedical EngineeringPharmaceutical ScienceNanotechnology02 engineering and technology010402 general chemistrybiodegradation01 natural sciencesBiomaterialsmetal–organic frameworksDrug Delivery SystemsNeoplasmsHumansMetal-Organic FrameworksBiodegradable metal021001 nanoscience & nanotechnologyControlled release0104 chemical sciencesMagnetic FieldsTargeted drug deliverySelective degradationDoxorubicindrug deliveryDrug deliverybiodegradation; drug delivery; metal–organic frameworks; microrobots; zeolitic imidazolate frameworksChemotherapeutic drugs0210 nano-technologymicrorobotsAdvanced healthcare materials
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Insertion of single-ion magnets based on mononuclear Co(II) complexes into ferromagnetic oxalate-based networks

2021

The 1 : 2 and 1 : 1 Co(ii) complexes of the L ligand (L = 6-(3,5-diamino-2,4,6-triazinyl)2,2'-bipyridine) with formulas [CoII(L)2](ClO4)2·0.5MeCN·Et2O (1) and [CoII(L)(CH3CN)2(H2O)](ClO4)2·MeCN (2) have been prepared. The structural and magnetic characterization of the two compounds shows that they contain octahedral high-spin Co(ii) and present a field-induced slow relaxation of the magnetization. 1 has been inserted into a bimetallic oxalate-based network leading to a novel achiral 3D compound of formula [CoII(L)2][MnIICrIII(ox)3]2·(solvate) (3) exhibiting ferromagnetic ordering below 4.6 K. EPR measurements suggest a weak magnetic coupling between the two sublattices.

Materials science010405 organic chemistryLigandRelaxation (NMR)Química organometàl·lica010402 general chemistry01 natural sciencesOxalate3. Good health0104 chemical scienceslaw.inventionInorganic Chemistrychemistry.chemical_compoundMagnetizationCrystallographyOctahedronchemistryFerromagnetismlawElectron paramagnetic resonanceBimetallic strip
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Hexakis-adducts of [60]fullerene as molecular scaffolds of polynuclear spin-crossover molecules

2021

A family of hexakis-substituted [60]fullerene adducts endowed with the well-known tridentate 2,6-bis(pyrazol-1-yl)pyridine (bpp) ligand for spin-crossover (SCO) systems has been designed and synthesized. It has been experimentally and theoretically demonstrated that these molecular scaffolds are able to form polynuclear SCO complexes in solution. UV-vis and fluorescence spectroscopy studies have allowed monitoring of the formation of up to six Fe(ii)–bpp SCO complexes. In addition, DFT calculations have been performed to model the different complexation environments and simulate their electronic properties. The complexes retain SCO properties in the solid state exhibiting both thermal- and …

Materials scienceFullerene010405 organic chemistryLigandQuímicaGeneral Chemistry010402 general chemistry01 natural sciencesFluorescence spectroscopy3. Good health0104 chemical sciencesAdductChemistrychemistry.chemical_compoundCrystallographysymbols.namesakechemistrySpin crossoverPyridinesymbolsMoleculeRaman spectroscopyMaterialsChemical Science
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Influence of Proton Conducting Cations on the Structure and Properties of 2D Anilate-Based Magnets

2017

The syntheses, structures, magnetic, and proton conductivity properties of a family of bimetallic anilate-based compounds with inserted alkylammonium cations are presented. The structures of (Me2NH2)[MnIICrIII(Br2An)3]·2H2O (1), (Et2NH2)[MnIICrIII(Br2An)3] (2), (Et3NH)[MnIICrIII(Cl2An)3] (3), and [(Et)(i-Pr)2NH]-[MnIICrIII(Br2An)3]·(CHCl3)0.5·(H2O) (4) contain a 2D anionic network formed by Mn(II) and Cr(III) ions linked through anilate ligands. In 1, 2, and 3, the hexagonal holes of this network are occupied by Me2NH2+, Et2NH2+, or Et3NH+ cations. Interestingly, the small increase of size of the templating cation in 4 ([(Et)(i-Pr)2NH]+ in the place of Me2NH2+, Et2NH2+ or Et3NH+), gives ris…

Anilate-Based Magnets25-Dihydroxy-14-benzoquinone Dianion DerivativesProton010405 organic chemistryHexagonal crystal systemChemistryConductivity010402 general chemistry01 natural sciencesProton-conductivity0104 chemical sciencesIonInorganic ChemistryEspectroscopíaCrystallographyImanes superconductoresFerrimagnetismMagnetAnionesPhysical and Theoretical ChemistryBimetallic strip
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Fe(II) spin crossover complexes of a derivative of 2,6-bis(pyrazol-1-yl)pyridine (1-bpp) functionalized with a carboxylic acid in the 3-pyridyl posit…

2019

Abstract The preparation of a new bis(pyrazol-1-yl)pyridine (1-bpp) derivative functionalized with a carboxylic acid in the 3-pyridyl position, bpp3-COOH ligand is reported together with the structure and spin-crossover (SCO) properties of [FeII(bpp3-COOH)2](ClO4)2·0.5EtOH·0.5H2O (1). Magnetic properties of 1 indicate that LS is favored. Desolvation leads to a gradual and incomplete SCO. Solvated and desolvated compounds show LIESST effect.

chemistry.chemical_classification010405 organic chemistryLigandCarboxylic acid010402 general chemistry01 natural sciencesMedicinal chemistryLIESST0104 chemical sciences3. Good healthInorganic Chemistrychemistry.chemical_compoundchemistrySpin crossoverPyridineÀcids carboxílicsMaterials ChemistryDesolvationCompostos de coordinacióPhysical and Theoretical ChemistryDerivative (chemistry)Polyhedron
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Iron(II) complex of 2-(1H-pyrazol-1-yl)pyridine-4-carboxylic acid (ppCOOH) suitable for surface deposition

2018

The synthesis, structural and magnetic characterization of the tris iron(II) complex of 2-(1H-pyrazol-1-yl)pyridine-4-carboxylic acid (ppCOOH) ligand are reported in [Fe(ppCOOH)3](ClO4)2·0.5H2O·2EtOH. Single crystal structure and magnetic characterization of the bulk compound show that the low-spin state is dominant from 2 to 400 K. ESI-MS and UV–Vis spectroscopy experiments indicate that acetonitrile solutions of this complex are stable with time. ESI-MS confirms the presence of the tris complex in solution. This complex can be deposited onto SiO2 surfaces due to the presence of carboxylic acid groups by immersing the substrates into acetonitrile solutions of the complex. XPS spectra of th…

chemistry.chemical_classification010405 organic chemistryLigandCarboxylic acidSubstrate (chemistry)010402 general chemistry01 natural sciences0104 chemical scienceschemistry.chemical_compoundCrystallographychemistrySpin crossoverPyridineMonolayerMaterials ChemistryPhysical and Theoretical ChemistryAcetonitrileSingle crystal
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CCDC 1491090: Experimental Crystal Structure Determination

2017

Related Article: Mario Palacios-Corella, Alejandro Fernández-Espejo, Montse Bazaga-García, Enrique R. Losilla, Aurelio Cabeza, Miguel Clemente-León, Eugenio Coronado|2017|Inorg.Chem.|56|13865|doi:10.1021/acs.inorgchem.7b01965

Space GroupCrystallographycatena-[triethylammonium tris(mu-25-dichloro-36-dioxocyclohexa-14-diene-14-bis(olato))-chromium(iii)-manganese(ii)]Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1856807: Experimental Crystal Structure Determination

2018

Related Article: Miguel Clemente Leon, Víctor García-López, Mario Palacios-Corella, Alexandre Abhervé, Isaac Pellicer-Carreño, Cédric Desplanches, Eugenio Coronado|2018|Dalton Trans.|47|16958|doi:10.1039/C8DT03511C

Space GroupCrystallographybis[26-bis(1H-pyrazol-1-yl)pyridine-4-carboxylic acid]-iron(ii) bis(hexafluoroarsenate) acetone solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1564530: Experimental Crystal Structure Determination

2017

Related Article: Mario Palacios-Corella, Alejandro Fernández-Espejo, Montse Bazaga-García, Enrique R. Losilla, Aurelio Cabeza, Miguel Clemente-León, Eugenio Coronado|2017|Inorg.Chem.|56|13865|doi:10.1021/acs.inorgchem.7b01965

Space GroupCrystallographyCrystal SystemCrystal Structurecatena-[diethylammonium tris(mu-25-dibromo-36-dioxocyclohexa-14-dien-14-diolato)-chromium(iii)-manganese(ii)]Cell ParametersExperimental 3D Coordinates
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CCDC 1564529: Experimental Crystal Structure Determination

2017

Related Article: Mario Palacios-Corella, Alejandro Fernández-Espejo, Montse Bazaga-García, Enrique R. Losilla, Aurelio Cabeza, Miguel Clemente-León, Eugenio Coronado|2017|Inorg.Chem.|56|13865|doi:10.1021/acs.inorgchem.7b01965

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinatescatena-[dimethylammonium tris(mu-25-dibromo-36-dioxocyclohexa-14-dien-14-diolato)-chromium(iii)-manganese(ii) dihydrate]
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CCDC 1856804: Experimental Crystal Structure Determination

2018

Related Article: Miguel Clemente Leon, Víctor García-López, Mario Palacios-Corella, Alexandre Abhervé, Isaac Pellicer-Carreño, Cédric Desplanches, Eugenio Coronado|2018|Dalton Trans.|47|16958|doi:10.1039/C8DT03511C

bis[26-bis(1H-pyrazol-1-yl)pyridine-4-carboxylic acid]-iron(ii) bis(tetrafluoroborate)Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1917753: Experimental Crystal Structure Determination

2019

Related Article: Víctor García-López, Mario Palacios-Corella, Verónica Gironés-Pérez, Carlos Bartual-Murgui, José Antonio Real, Eric Pellegrin, Javier Herrero-Martín, Guillem Aromí, Miguel Clemente-León, Eugenio Coronado|2019|Inorg.Chem.|58|12199|doi:10.1021/acs.inorgchem.9b01526

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters[26-bis(1H-pyrazol-1-yl)pyridine-4-carboxylic acid]-[ethyl 26-bis(1H-pyrazol-1-yl)pyridine-4-carboxylate]-iron(ii) bis(perchlorate) acetone solvateExperimental 3D Coordinates
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CCDC 1856814: Experimental Crystal Structure Determination

2018

Related Article: Miguel Clemente Leon, Víctor García-López, Mario Palacios-Corella, Alexandre Abhervé, Isaac Pellicer-Carreño, Cédric Desplanches, Eugenio Coronado|2018|Dalton Trans.|47|16958|doi:10.1039/C8DT03511C

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis[26-bis(1H-pyrazol-1-yl)pyridine-4-carboxylic acid]-iron(ii) diperchlorateExperimental 3D Coordinates
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CCDC 1856808: Experimental Crystal Structure Determination

2018

Related Article: Miguel Clemente Leon, Víctor García-López, Mario Palacios-Corella, Alexandre Abhervé, Isaac Pellicer-Carreño, Cédric Desplanches, Eugenio Coronado|2018|Dalton Trans.|47|16958|doi:10.1039/C8DT03511C

bis[26-bis(1H-pyrazol-1-yl)pyridine-4-carboxylic acid]-iron(ii) bis(hexafluoroantimonate) acetone solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 2213981: Experimental Crystal Structure Determination

2023

Related Article: Mario Palacios-Corella, Víctor García-López, Joao Carlos Waerenborgh, Bruno J. C. Vieira, Guillermo Mínguez Espallargas, Miguel Clemente-León, Eugenio Coronado|2023|Chemical Science|14|3048|doi:10.1039/D2SC05800F

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-(heptakis(mu-oxo)-bis(mu-N-[13-dioxy-2-(oxymethyl)propan-2-yl]-26-bis(1H-pyrazol-1-yl)pyridine-4-carboxamide)-hexaoxo-hexa-vanadium-zinc acetonitrile dimethylformamide unknown solvate)Experimental 3D Coordinates
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CCDC 1856805: Experimental Crystal Structure Determination

2018

Related Article: Miguel Clemente Leon, Víctor García-López, Mario Palacios-Corella, Alexandre Abhervé, Isaac Pellicer-Carreño, Cédric Desplanches, Eugenio Coronado|2018|Dalton Trans.|47|16958|doi:10.1039/C8DT03511C

bis[26-bis(1H-pyrazol-1-yl)pyridine-4-carboxylic acid]-iron(ii) bis(tetrafluoroborate)Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1944601: Experimental Crystal Structure Determination

2019

Related Article: Víctor García-López, Mario Palacios-Corella, Salvador Cardona-Serra, Miguel Clemente-León, Eugenio Coronado|2019|Chem.Commun.|55|12227|doi:10.1039/C9CC05988A

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis[11'-(pyridine-26-diyl)bis(1H-pyrazole-4-carboxylic acid)]-iron(ii) bis(perchlorate) acetone solvateExperimental 3D Coordinates
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CCDC 1856813: Experimental Crystal Structure Determination

2018

Related Article: Miguel Clemente Leon, Víctor García-López, Mario Palacios-Corella, Alexandre Abhervé, Isaac Pellicer-Carreño, Cédric Desplanches, Eugenio Coronado|2018|Dalton Trans.|47|16958|doi:10.1039/C8DT03511C

Space GroupCrystallographyCrystal Systembis[ethyl 26-bis(1H-pyrazol-1-yl)pyridine-4-carboxylate]-iron(ii) diperchlorate acetone solvateCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1058520: Experimental Crystal Structure Determination

2015

Related Article: Alexandre Abhervé, Mario Palacios-Corella, Juan Modesto Clemente-Juan, Raphael Marx, Petr Neugebauer, Joris van Slageren, Miguel Clemente-León, Eugenio Coronado|2015|J.Mater.Chem.C|3|7936|doi:10.1039/C5TC01089F

Space GroupCrystallographyCrystal SystemCrystal Structurecatena-[bis(mu-N-(13-dioxy-2-(oxymethyl)propan-2-yl)-26-di(1H-pyrazol-1-yl)isonicotinamide)-octakis(mu-oxo)-diaqua-bis(NN-dimethylformamide)-decaoxo-di-iron-manganese-hexa-molybdenum hydroxide NN-dimethylformamide solvate monohydrate]Cell ParametersExperimental 3D Coordinates
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CCDC 1917752: Experimental Crystal Structure Determination

2019

Related Article: Víctor García-López, Mario Palacios-Corella, Verónica Gironés-Pérez, Carlos Bartual-Murgui, José Antonio Real, Eric Pellegrin, Javier Herrero-Martín, Guillem Aromí, Miguel Clemente-León, Eugenio Coronado|2019|Inorg.Chem.|58|12199|doi:10.1021/acs.inorgchem.9b01526

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters{26-bis[5-([11'-biphenyl]-4-yl)-1H-pyrazol-3-yl]pyridine}-[26-bis(1H-pyrazol-1-yl)pyridine-4-carboxylic acid]-iron(ii) bis(perchlorate) acetone solvateExperimental 3D Coordinates
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CCDC 1856809: Experimental Crystal Structure Determination

2018

Related Article: Miguel Clemente Leon, Víctor García-López, Mario Palacios-Corella, Alexandre Abhervé, Isaac Pellicer-Carreño, Cédric Desplanches, Eugenio Coronado|2018|Dalton Trans.|47|16958|doi:10.1039/C8DT03511C

Space GroupCrystallographyCrystal Systembis[26-bis(1H-pyrazol-1-yl)pyridine-4-carboxylic acid]-iron(ii) bis(trifluoromethanesulfonate) acetone solvateCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1058519: Experimental Crystal Structure Determination

2015

Related Article: Alexandre Abhervé, Mario Palacios-Corella, Juan Modesto Clemente-Juan, Raphael Marx, Petr Neugebauer, Joris van Slageren, Miguel Clemente-León, Eugenio Coronado|2015|J.Mater.Chem.C|3|7936|doi:10.1039/C5TC01089F

Space GroupCrystallographyCrystal Systemtris(tetra-n-butylammonium) bis(mu-N-(13-dioxy-2-(oxymethyl)propan-2-yl)-26-di(1H-pyrazol-1-yl)isonicotinamide)-hexakis(mu-oxo)-dodecaoxo-manganese-hexa-molybdenum NN-dimethylacetamide solvate hydrateCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 2213982: Experimental Crystal Structure Determination

2023

Related Article: Mario Palacios-Corella, Víctor García-López, Joao Carlos Waerenborgh, Bruno J. C. Vieira, Guillermo Mínguez Espallargas, Miguel Clemente-León, Eugenio Coronado|2023|Chemical Science|14|3048|doi:10.1039/D2SC05800F

Space GroupCrystallographybis(tetra-n-butylammonium) bis(mu-N-[13-dioxy-2-(oxymethyl)propan-2-yl]-26-bis(1H-pyrazol-1-yl)pyridine-4-carboxamide)-heptakis(mu-oxo)-hexaoxo-hexa-vanadium dimethylacetamide solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1584808: Experimental Crystal Structure Determination

2018

Related Article: Víctor García-López, Mario Palacios-Corella, Miguel Clemente-León, Eugenio Coronado|2018|J.Coord.Chem.|71|763|doi:10.1080/00958972.2018.1430790

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterstris(2-(1H-pyrazol-1-yl)pyridine-4-carboxylic acid)-iron(ii) diperchlorate ethanol solvate hemihydrateExperimental 3D Coordinates
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CCDC 1856812: Experimental Crystal Structure Determination

2018

Related Article: Miguel Clemente Leon, Víctor García-López, Mario Palacios-Corella, Alexandre Abhervé, Isaac Pellicer-Carreño, Cédric Desplanches, Eugenio Coronado|2018|Dalton Trans.|47|16958|doi:10.1039/C8DT03511C

Space GroupCrystallographyCrystal Systembis[26-bis(1H-pyrazol-1-yl)pyridine-4-carboxylic acid]-iron(ii) bis(trifluoromethanesulfonate) acetone solvateCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1491091: Experimental Crystal Structure Determination

2017

Related Article: Mario Palacios-Corella, Alejandro Fernández-Espejo, Montse Bazaga-García, Enrique R. Losilla, Aurelio Cabeza, Miguel Clemente-León, Eugenio Coronado|2017|Inorg.Chem.|56|13865|doi:10.1021/acs.inorgchem.7b01965

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-(di-isopropyl(ethyl)ammonium tris(mu-25-dibromo-36-dioxy-14-benzoquinone)-chromium-manganese chloroform solvate monohydrate)Experimental 3D Coordinates
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CCDC 2213983: Experimental Crystal Structure Determination

2023

Related Article: Mario Palacios-Corella, Víctor García-López, Joao Carlos Waerenborgh, Bruno J. C. Vieira, Guillermo Mínguez Espallargas, Miguel Clemente-León, Eugenio Coronado|2023|Chemical Science|14|3048|doi:10.1039/D2SC05800F

Space GroupCrystallographyCrystal Systembis(cobaltocenium) bis(mu-hydroxo)-bis(mu-N-[13-oxy-2-(oxymethyl)propan-2-yl]-26-bis(1H-pyrazol-1-yl)pyridine-4-carboxamide)-pentakis(mu-oxo)-hexaoxo-hexa-vanadium acetonitrile solvateCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1856811: Experimental Crystal Structure Determination

2018

Related Article: Miguel Clemente Leon, Víctor García-López, Mario Palacios-Corella, Alexandre Abhervé, Isaac Pellicer-Carreño, Cédric Desplanches, Eugenio Coronado|2018|Dalton Trans.|47|16958|doi:10.1039/C8DT03511C

bis[26-bis(1H-pyrazol-1-yl)pyridine-4-carboxylic acid]-iron(ii) bis(hexafluoroantimonate) acetone solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1856810: Experimental Crystal Structure Determination

2018

Related Article: Miguel Clemente Leon, Víctor García-López, Mario Palacios-Corella, Alexandre Abhervé, Isaac Pellicer-Carreño, Cédric Desplanches, Eugenio Coronado|2018|Dalton Trans.|47|16958|doi:10.1039/C8DT03511C

Space GroupCrystallographyCrystal Systembis[ethyl 26-bis(1H-pyrazol-1-yl)pyridine-4-carboxylate]-iron(ii) diperchlorate acetone solvateCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1917754: Experimental Crystal Structure Determination

2019

Related Article: Víctor García-López, Mario Palacios-Corella, Verónica Gironés-Pérez, Carlos Bartual-Murgui, José Antonio Real, Eric Pellegrin, Javier Herrero-Martín, Guillem Aromí, Miguel Clemente-León, Eugenio Coronado|2019|Inorg.Chem.|58|12199|doi:10.1021/acs.inorgchem.9b01526

[26-bis(1H-pyrazol-1-yl)pyridine-4-carboxylic acid]-[ethyl 26-bis(1H-pyrazol-1-yl)pyridine-4-carboxylate]-iron bis(perchlorate) acetone solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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2023

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Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinatescatena-(cobaltocenium heptakis(mu-oxo)-bis(mu-N-[13-dioxy-2-(oxymethyl)propan-2-yl]-26-bis(1H-pyrazol-1-yl)pyridine-4-carboxamide)-hexaoxo-hexa-vanadium-zinc unknown solvate tetrahydrate)
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2019

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters{26-bis[5-([11'-biphenyl]-4-yl)-1H-pyrazol-3-yl]pyridine}-[26-bis(1H-pyrazol-1-yl)pyridine-4-carboxylic acid]-iron(ii) bis(perchlorate) acetone diethyl ether solvateExperimental 3D Coordinates
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catena-[(mu-11'-(pyridine-26-diyl)bis(1H-pyrazole-4-carboxylato))-bis(11'-(pyridine-26-diyl)bis(1H-pyrazole-4-carboxylic acid))-perchlorato-di-iron bis(perchlorate) acetone solvate monohydrate]Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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{26-bis[5-([11'-biphenyl]-4-yl)-1H-pyrazol-3-yl]pyridine}-[26-bis(1H-pyrazol-1-yl)pyridine-4-carboxylic acid]-iron bis(perchlorate) acetone solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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