0000000001301732
AUTHOR
M.-c. Dul
A robust viologen and Mn-based porous coordination polymer with two types of Lewis acid sites providing high affinity for H 2 O, CO 2 and NH 3
A novel porous coordination polymer [Mn(pc3)(H2O)2]·xH2O (3 < x < 4) is synthesized in water at pH = 7 using the anionic viologen-carboxylate ligand 4,4′-bipyridinium,1,1′-bis-(2,4-dicarboxyphenyl) (pc32−). Dehydration of the material results in the formation of open pores containing two types of accessible Lewis acid sites: exposed Mn2+ cations and N+ atoms of viologen units. Due to this property the PCP shows high affinity and capacity in the adsorption of H2O, CO2 and NH3. Despite the presence of strong adsorption sites this material is stable in liquid water and in gaseous NH3.
CCDC 777548: Experimental Crystal Structure Determination
Related Article: E.Pardo, J.Ferrando-Soria, M.-C.Dul, R.Lescouezec, Y.Journaux, R.Ruiz-Garcia, J.Cano, M.Julve, F.Lloret, L.Canadillas-Delgado, J.Pasan, C.Ruiz-Perez|2010|Chem.-Eur.J.|16|12838|doi:10.1002/chem.201001737
CCDC 674871: Experimental Crystal Structure Determination
Related Article: D.Cangussu, E.Pardo, M.-C.Dul, R.Lescouezec, P.Herson, Y.Journaux, E.F.Pedroso, C.L.M.Pereira, H.O.Stumpf, M.C.Munoz, R.Ruiz-Garcia, J.Cano, M.Julve, F.Lloret|2008|Inorg.Chim.Acta|361|3394|doi:10.1016/j.ica.2008.02.042
CCDC 844822: Experimental Crystal Structure Determination
Related Article: M.-C.Dul, R.Lescouezec, L.-M.Chamoreau, Y.Journaux, R.Carrasco, M.Castellano, R.Ruiz-Garcia, J.Cano, F.Lloret, M.Julve, C.Ruiz-Perez, O.Fabelo, E.Pardo|2012|CrystEngComm|14|5639|doi:10.1039/c2ce25434d
CCDC 777549: Experimental Crystal Structure Determination
Related Article: E.Pardo, J.Ferrando-Soria, M.-C.Dul, R.Lescouezec, Y.Journaux, R.Ruiz-Garcia, J.Cano, M.Julve, F.Lloret, L.Canadillas-Delgado, J.Pasan, C.Ruiz-Perez|2010|Chem.-Eur.J.|16|12838|doi:10.1002/chem.201001737
CCDC 758079: Experimental Crystal Structure Determination
Related Article: E.Pardo, M.-C.Dul, R.Lescouezec, L.-M.Chamoreau, Y.Journaux, J.Pasan, C.Ruiz-Perez, M.Julve, F.Lloret, R.Ruiz-Garcia, J.Cano|2010|Dalton Trans.|39|4786|doi:10.1039/b926709c
CCDC 791634: Experimental Crystal Structure Determination
Related Article: M.-C.Dul, J.Ferrando-Soria, E.Pardo, R.Lescouezec, Y.Journaux, R.Ruiz-Garcia, J.Cano, M.Julve, F.Lloret, O.Fabelo, J.Pasan, C.Ruiz-Perez|2010|Inorg.Chem.|49|11264|doi:10.1021/ic102037m
CCDC 777550: Experimental Crystal Structure Determination
Related Article: E.Pardo, J.Ferrando-Soria, M.-C.Dul, R.Lescouezec, Y.Journaux, R.Ruiz-Garcia, J.Cano, M.Julve, F.Lloret, L.Canadillas-Delgado, J.Pasan, C.Ruiz-Perez|2010|Chem.-Eur.J.|16|12838|doi:10.1002/chem.201001737
CCDC 844823: Experimental Crystal Structure Determination
Related Article: M.-C.Dul, R.Lescouezec, L.-M.Chamoreau, Y.Journaux, R.Carrasco, M.Castellano, R.Ruiz-Garcia, J.Cano, F.Lloret, M.Julve, C.Ruiz-Perez, O.Fabelo, E.Pardo|2012|CrystEngComm|14|5639|doi:10.1039/c2ce25434d
CCDC 669577: Experimental Crystal Structure Determination
Related Article: D.Cangussu, E.Pardo, M.-C.Dul, R.Lescouezec, P.Herson, Y.Journaux, E.F.Pedroso, C.L.M.Pereira, H.O.Stumpf, M.C.Munoz, R.Ruiz-Garcia, J.Cano, M.Julve, F.Lloret|2008|Inorg.Chim.Acta|361|3394|doi:10.1016/j.ica.2008.02.042