0000000001303205
AUTHOR
A. Soriano-portillo
Synthesis and characterization of [Fe(III)(qsal)2][M(III)(pds)2] (M=Cu, Au)
Abstract Salts of the Fe(III) spin crossover cation [FeIII(qsal)2]+ (qsalH = N-(8-quinolyl)salicylaldimine) and monoanions [MIII(pds)2]− (M = Cu, Au; pds = pirazine-2,3-diselenolate) with formula [FeIII(qsal)2][MIII(pds)2] were prepared and characterized by single crystal X-ray diffraction and magnetic measurements. These two salts present magnetic properties essentially due to the FeIII centres in the high-spin state (S = 5/2), and do not have any spin transition.
CCDC 270162: Experimental Crystal Structure Determination
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CCDC 629475: Experimental Crystal Structure Determination
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CCDC 629474: Experimental Crystal Structure Determination
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CCDC 609521: Experimental Crystal Structure Determination
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CCDC 270163: Experimental Crystal Structure Determination
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CCDC 749069: Experimental Crystal Structure Determination
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CCDC 749068: Experimental Crystal Structure Determination
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CCDC 749070: Experimental Crystal Structure Determination
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CCDC 749071: Experimental Crystal Structure Determination
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CCDC 609520: Experimental Crystal Structure Determination
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CCDC 698389: Experimental Crystal Structure Determination
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