0000000001303251

AUTHOR

Volodymyr Bon

showing 4 related works from this author

Indefinitely stable iron(IV) cage complexes formed in water by air oxidation

2017

In nature, iron, the fourth most abundant element of the Earth's crust, occurs in its stable forms either as the native metal or in its compounds in the +2 or +3 (low-valent) oxidation states. High-valent iron (+4, +5, +6) compounds are not formed spontaneously at ambient conditions, and the ones obtained synthetically appear to be unstable in polar organic solvents, especially aqueous solutions, and this is what limits their studies and use. Here we describe unprecedented iron(IV) hexahydrazide clathrochelate complexes that are assembled in alkaline aqueous media from iron(III) salts, oxalodihydrazide and formaldehyde in the course of a metal-templated reaction accompanied by air oxidation…

ClathrochelateScienceInorganic chemistryFormaldehydeSolid-stateGeneral Physics and Astronomy010402 general chemistryDFT01 natural sciencesArticleGeneral Biochemistry Genetics and Molecular BiologyInorganic Chemistrychemistry.chemical_compoundhigh-valent ironNative metalOorganisk kemiMultidisciplinaryAqueous solution010405 organic chemistryQGeneral ChemistryDecompositionCoordination chemistry3. Good health0104 chemical scienceschemistryCageEarth (classical element)Nature Communications
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CCDC 1400635: Experimental Crystal Structure Determination

2017

Related Article: Stefania Tomyn, Sergii I. Shylin, Dmytro Bykov, Vadim Ksenofontov, Elzbieta Gumienna-Kontecka, Volodymyr Bon, Igor O. Fritsky|2017|Nat.Commun.|8|14099|doi:10.1038/ncomms14099

Space GroupCrystallographybis(tetra-n-butylammonium) (1347810121316171922-dodeca-azatetracyclo[8.8.4.1317.1812]tetracosane-5614152021-hexonato)-iron(iv) chloroform solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1400636: Experimental Crystal Structure Determination

2017

Related Article: Stefania Tomyn, Sergii I. Shylin, Dmytro Bykov, Vadim Ksenofontov, Elzbieta Gumienna-Kontecka, Volodymyr Bon, Igor O. Fritsky|2017|Nat.Commun.|8|14099|doi:10.1038/ncomms14099

Space GroupCrystallographyCrystal Systembis(tetraphenylarsonium) (1347810121316171922-dodeca-azatetracyclo[8.8.4.1317.1812]tetracosane-5614152021-hexonato)-iron(iv) hydrateCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1458636: Experimental Crystal Structure Determination

2017

Related Article: Stefania Tomyn, Sergii I. Shylin, Dmytro Bykov, Vadim Ksenofontov, Elzbieta Gumienna-Kontecka, Volodymyr Bon, Igor O. Fritsky|2017|Nat.Commun.|8|14099|doi:10.1038/ncomms14099

Space GroupCrystallographycatena-((mu-1347810121316171922-dodeca-azatetracyclo[8.8.4.1317.1812]tetracosane-5614152021-hexone)-diaqua-calcium-iron isopropanol solvate tetrahydrate)Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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