0000000001303251
AUTHOR
Volodymyr Bon
Indefinitely stable iron(IV) cage complexes formed in water by air oxidation
In nature, iron, the fourth most abundant element of the Earth's crust, occurs in its stable forms either as the native metal or in its compounds in the +2 or +3 (low-valent) oxidation states. High-valent iron (+4, +5, +6) compounds are not formed spontaneously at ambient conditions, and the ones obtained synthetically appear to be unstable in polar organic solvents, especially aqueous solutions, and this is what limits their studies and use. Here we describe unprecedented iron(IV) hexahydrazide clathrochelate complexes that are assembled in alkaline aqueous media from iron(III) salts, oxalodihydrazide and formaldehyde in the course of a metal-templated reaction accompanied by air oxidation…
CCDC 1400635: Experimental Crystal Structure Determination
Related Article: Stefania Tomyn, Sergii I. Shylin, Dmytro Bykov, Vadim Ksenofontov, Elzbieta Gumienna-Kontecka, Volodymyr Bon, Igor O. Fritsky|2017|Nat.Commun.|8|14099|doi:10.1038/ncomms14099
CCDC 1400636: Experimental Crystal Structure Determination
Related Article: Stefania Tomyn, Sergii I. Shylin, Dmytro Bykov, Vadim Ksenofontov, Elzbieta Gumienna-Kontecka, Volodymyr Bon, Igor O. Fritsky|2017|Nat.Commun.|8|14099|doi:10.1038/ncomms14099
CCDC 1458636: Experimental Crystal Structure Determination
Related Article: Stefania Tomyn, Sergii I. Shylin, Dmytro Bykov, Vadim Ksenofontov, Elzbieta Gumienna-Kontecka, Volodymyr Bon, Igor O. Fritsky|2017|Nat.Commun.|8|14099|doi:10.1038/ncomms14099