0000000001303482

AUTHOR

Yangguang Li

showing 3 related works from this author

3D-transition metal mono-substituted Keggin polyoxotungstate with an antenna molecule: synthesis, structure and characterization

2008

Three new organic-inorganic hybrid complexes based on 3d-transition metal monosubstituted Keggin polyoxometalates (POMs) with imidazole (Im) as pendant ligands, formulated as (HIm)(6-)[SiW11O39NiIm]0.8[SiW11O39Ni(H2O)]0.2.7H2O (1), (Im)4Na6[SiW11O39MnIm]0.69[SiW11O39Mn(H2O)]0.31.7.5H2O (2) and (HIm)6[SiW11O39CoIm]0.63[SiW11O39Co(H2O)]0.37.7H2O (3), have been synthesized and characterized by IR spectroscopy, UV-visible spectroscopy, elemental analysis, TG analysis, cyclic voltammetry, magnetic properties, EPR and single-crystal/powder X-ray diffraction. The structural analyses indicate that the 3d metal atoms are incorporated into the vacancy of the alpha-[SiW11O39](8-) (SiW11). Complexes 1-…

ChemistryLigandInorganic chemistryInfrared spectroscopylaw.inventionInorganic ChemistryMetalCrystallographychemistry.chemical_compoundTransition metallawvisual_artvisual_art.visual_art_mediumMoleculeImidazoleCyclic voltammetryElectron paramagnetic resonanceDalton Transactions
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CCDC 606861: Experimental Crystal Structure Determination

2009

Related Article: Hongsheng Liu, C.J.Gomez-Garcia, Jun Peng, Jingquan Sha, Lixia Wang, Yechao Yan|2009|Inorg.Chim.Acta|362|1957|doi:10.1016/j.ica.2008.09.014

Space GroupCrystallographyhexakis(1H-Imidazol-3-ium) (mu12-silicato)-tetracosakis(mu2-oxo)-(1H-imidazole)-undecaoxo-nickel-undeca-tungsten heptahydrateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 606862: Experimental Crystal Structure Determination

2009

Related Article: Hongsheng Liu, C.J.Gomez-Garcia, Jun Peng, Jingquan Sha, Lixia Wang, Yechao Yan|2009|Inorg.Chim.Acta|362|1957|doi:10.1016/j.ica.2008.09.014

Hexa-sodium (mu~12~-silicato)-tetracosakis(mu~2~-oxo)-(1H-imidazole)-undecaoxo-manganese-undeca-tungsten 1H-imidazole solvate hydrateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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